(S)-VANOL

Reaction

Product Name: (S)-VANOL
CAS No.: 147702-13-4
Chemical Name: (S)-VANOL
Synonyms: (R)-VANOL;(S)-VANOL;(R)-VANOL 97%;(R)-VANOL,99%e.e.;(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL;(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL);3,3'-diphenyl--1,1'-diol;(2R)-3,3’-Diphenyl[2,2’-binaphthalene]-1,1’-diol;(2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol;(2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol
CBNumber: CB2188801
Molecular Formula: C32H22O2
Formula Weight: 438.52
MOL File: 147702-13-4.mol

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(S)-VANOL Property

Melting point:: 200-204 °C
alpha: +362° (c 1.0, THF)
Boiling point:: 580.1±50.0 °C(Predicted)
Density: 1.251±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 7.71±0.50(Predicted)
form: Powder
color: white to pale yellow
optical activity: [α]20/D +310°, c = 1 in chloroform
CAS DataBase Reference: 147702-13-4

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Safety

Hazard Codes: Xi
Risk Statements: 37/38-41
Safety Statements: 26-39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 675156
Product name: (R)-VANOL
Purity: 97%
Packaging: 250mg
Price: $178
Updated: 2024/03/01

Strem Chemicals

Product number: 08-1700
Product name: (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL
Packaging: 100mg
Price: $212
Updated: 2024/03/01

Strem Chemicals

Product number: 08-1700
Product name: (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL
Packaging: 500mg
Price: $838
Updated: 2024/03/01

Ambeed

Product number: A466556
Product name: (2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol
Purity: 98%99%ee
Packaging: 100mg
Price: $68
Updated: 2021/12/16

Ambeed

Product number: A466556
Product name: (2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol
Purity: 98%99%ee
Packaging: 1g
Price: $458
Updated: 2021/12/16

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(S)-VANOL Chemical Properties,Usage,Production

Reaction

Chiral ligand used in catalytic asymmetric aziridination.
Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes.

Uses

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(S)-VANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-VANOL Suppliers

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147702-13-4, (S)-VANOLRelated Search:

(R)-VANOL,(S)-VANOL,(2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(S)-VANOL,(2S)-(-)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (S)-VANOL 2,2'-binaphthalene o-Terphenyl (R)-VAPOL o-Quaterphenyl (S)-VANOL (S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide

(2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL

(2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL

(R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol

(S)-VANOL

(R)-VANOL

(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL)

(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL

(2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL

(2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL

(R)-VANOL 97%

(R)-VANOL,99%e.e.

3,3'-diphenyl-<2,2'-binaphthalene>-1,1'-diol

2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-, (2R)-

(2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol

(2R)-(+)-3,3''-Diphenyl-[2,2''-binaphthalene]-1,1''-diol

(2R)-3,3’-Diphenyl[2,2’-binaphthalene]-1,1’-diol

(2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol

147702-13-4

BINOL Series

Chiral Oxygen