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(S)-VANOL

Reaction
Product Name
(S)-VANOL
CAS No.
147702-13-4
Chemical Name
(S)-VANOL
Synonyms
(R)-VANOL;(S)-VANOL;(R)-VANOL 97%;(R)-VANOL,99%e.e.;(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL;(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL);3,3'-diphenyl--1,1'-diol;(2R)-3,3’-Diphenyl[2,2’-binaphthalene]-1,1’-diol;(2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol;2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-, (2R)-
CBNumber
CB2188801
Molecular Formula
C32H22O2
Formula Weight
438.52
MOL File
147702-13-4.mol
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(S)-VANOL Property

Melting point:
200-204 °C
alpha 
+362° (c 1.0, THF)
Boiling point:
580.1±50.0 °C(Predicted)
Density 
1.251±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
7.71±0.50(Predicted)
form 
Powder
color 
white to pale yellow
optical activity
[α]20/D +310°, c = 1 in chloroform
CAS DataBase Reference
147702-13-4
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Safety

Hazard Codes 
Xi
Risk Statements 
37/38-41
Safety Statements 
26-39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
675156
Product name
(R)-VANOL
Purity
97%
Packaging
250mg
Price
$178
Updated
2024/03/01
Strem Chemicals
Product number
08-1700
Product name
(2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL
Packaging
100mg
Price
$212
Updated
2024/03/01
Strem Chemicals
Product number
08-1700
Product name
(2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL
Packaging
500mg
Price
$838
Updated
2024/03/01
Ambeed
Product number
A466556
Product name
(2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol
Purity
98%99%ee
Packaging
100mg
Price
$68
Updated
2021/12/16
Ambeed
Product number
A466556
Product name
(2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol
Purity
98%99%ee
Packaging
1g
Price
$458
Updated
2021/12/16
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(S)-VANOL Chemical Properties,Usage,Production

Reaction

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes. 

Uses

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(S)-VANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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147702-13-4, (S)-VANOLRelated Search:


  • (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL
  • (2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL
  • (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol
  • (S)-VANOL
  • (R)-VANOL
  • (S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL)
  • (R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL
  • (2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
  • (2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
  • (R)-VANOL 97%
  • (R)-VANOL,99%e.e.
  • 3,3'-diphenyl-<2,2'-binaphthalene>-1,1'-diol
  • 2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-, (2R)-
  • (2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol
  • (2R)-(+)-3,3''-Diphenyl-[2,2''-binaphthalene]-1,1''-diol
  • (2R)-3,3’-Diphenyl[2,2’-binaphthalene]-1,1’-diol
  • 147702-13-4
  • BINOL Series
  • Chiral Oxygen