Silane Coupling Agents KH-560 Physicochemical Properties Molecular Structure Uses Application Handling and Storage Fire-fighting measures Toxicological Information
ChemicalBook > CAS DataBase List > 3-Glycidoxypropyltrimethoxysilane

3-Glycidoxypropyltrimethoxysilane

Silane Coupling Agents KH-560 Physicochemical Properties Molecular Structure Uses Application Handling and Storage Fire-fighting measures Toxicological Information
Product Name
3-Glycidoxypropyltrimethoxysilane
CAS No.
2530-83-8
Chemical Name
3-Glycidoxypropyltrimethoxysilane
Synonyms
GLYMO;3-GLYCIDYLOXYPROPYLTRIMETHOXYSILANE;Glycidyloxypropyltrimethoxysilane;3-(2,3-EPOXYPROPOXY)PROPYLTRIMETHOXYSILANE;Silane coupling agent KH-560;γ-Glycidoxypropyltrimethoxysilane;GOPTS;A 187;Silane coupler KH-560;(GLYCIDOXYPROPYL)TRIMETHOXYSILANE
CBNumber
CB2194134
Molecular Formula
C9H20O5Si
Formula Weight
236.34
MOL File
2530-83-8.mol
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3-Glycidoxypropyltrimethoxysilane Property

Melting point:
-50°C
Boiling point:
120 °C2 mm Hg(lit.)
Density 
1.070 g/mL at 20 °C
vapor pressure 
0-12790Pa at 20-25℃
refractive index 
n20/D 1.429(lit.)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
Acetonitrile (Slightly), Chloroform
form 
Liquid
color 
Clear
Specific Gravity
1.07
Water Solubility 
Miscible with alcohols, ketones and aliphatic or aromatic hydrocarbons. Immiscible with water.
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
BRN 
4308125
Stability:
Moisture Sensitive
InChIKey
BPSIOYPQMFLKFR-UHFFFAOYSA-N
LogP
-2.6-0.5 at 20℃
CAS DataBase Reference
2530-83-8(CAS DataBase Reference)
NIST Chemistry Reference
3-Glycidoxypropyltrimethoxysilane(2530-83-8)
EPA Substance Registry System
3-(Trimethoxysilyl)propyl glycidyl ether (2530-83-8)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/38-21-52-41
Safety Statements 
28A-26-36/37/39-24/25
WGK Germany 
2
RTECS 
VV4025000
10-21
TSCA 
Yes
PackingGroup 
III
HS Code 
29310095
Toxicity
LD50 oral in rat: 22600uL/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
440167
Product name
(3-Glycidyloxypropyl)trimethoxysilane
Purity
≥98%
Packaging
100ml
Price
$66
Updated
2024/03/01
Sigma-Aldrich
Product number
440167
Product name
(3-Glycidyloxypropyl)trimethoxysilane
Purity
≥98%
Packaging
1l
Price
$359
Updated
2024/03/01
TCI Chemical
Product number
G0210
Product name
3-Glycidyloxypropyltrimethoxysilane
Purity
>97.0%(GC)
Packaging
25g
Price
$18
Updated
2024/03/01
TCI Chemical
Product number
G0210
Product name
3-Glycidyloxypropyltrimethoxysilane
Purity
>97.0%(GC)
Packaging
100g
Price
$43
Updated
2024/03/01
Alfa Aesar
Product number
A18431
Product name
(3-Glycidoxypropyl)trimethoxysilane, 97%
Packaging
25g
Price
$35.9
Updated
2024/03/01
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3-Glycidoxypropyltrimethoxysilane Chemical Properties,Usage,Production

Silane Coupling Agents KH-560

KH-560 is the first widely used coupling agent and has been used for 40 years. One end of its structure with reactive groups such as amino and vinyl, can react with epoxy, phenolic, polyester and other synthetic resin molecules. The other end is alkoxy (such as methoxy, ethoxy etc.) or chlorine atoms which is connected with silicon. These groups can be transformed into silanol in the hydrolysis in water solution or damp air. And the formed silanol is able to react with surface hydroxyl of glass, minerals and inorganic filler. Therefore, silane coupling agent is commonly used in silicate-filled epoxy, phenolic, polyester resin and other systems. In addition, it can also be used for FRP production, in order to improve its mechanical strength and resistance to wet environment. The organic groups of the silane coupling agent are selective about the reaction of the synthetic resin. Generally, these organic groups lack sufficient reactivity with synthetic resins such as polyethylene, polypropylene and polystyrene, and thus the coupling effect for them is poor. In recent years, new varieties of silane coupling agents with better coupling for polyolefins have been developed, but are limited in cost and other properties and are not yet widely used.
Silane coupling agent is also known as silane treatment agent. Its general formula is Y (CH2) nSiX3. Wherein n is an integer of 0 to 3; X is a hydrolyzable group such as chlorine, methoxy, ethoxy and acetoxy; Y is an organic functional group such as a vinyl, an amino, an epoxy group, a methacryloyloxy group and sulfydryl.

Physicochemical Properties

Colorless transparent liquid;
Soluble in a variety of organic solvents;
Easy to hydrolysis;
Able for condensation to form polysiloxanes;
Easy to polymerize in the presence of overheating, light and peroxide.

Molecular Structure


Fig: Molecular structure

Uses

3-Glycidoxypropyltrimethoxysilane is an epoxy-functional silane, it is a clear, light straw liquid. 3-Glycidoxypropyltrimethoxysilane may be used as a coupling agent in polysulfide and polyurethane caulks and sealants, in mineral-filled or glass-reinforced thermosets and thermoplastics, and in glass roving size-binders. It is particularly employed as an adhesion-promoting additive in waterborne systems, e.g. improving the adhesion of acrylic latex sealants.
Applications:

  • 3-Glycidoxypropyltrimethoxysilane may improve dry and wet strength in cured composites reinforced with glass fiber rovings
  • Enhance wet electrical properties of epoxy-based encapsulate and packaging materials.
  • Eliminate the need for a separate primer in polysulfide and urethane sealants.
  • Improve adhesion in waterborne acrylic sealants and in urethane and epoxy coatings.

Application

  • It is mainly used in unsaturated polyester composites to improve the mechanical properties, electrical properties and light transmission properties of the composites, especially to improve their performance in wet environment.
  • In wire and cable industry, when used to treat EPDM system stuffed by pottery clay and crosslinked by peroxide, it can improve consumption factor and specific inductance captance.
  • Used for its copolymerization with monomers like vinyl acetate and acrylic acid or methacrylic, to form the polymers widely used in coatings, adhesives and sealants, providing excellent adhesion and durability.

Handling and Storage

  • Handling
Normal measures for preventive fire protection.
  • Storage
Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2-8 °C.

Fire-fighting measures

Flammable properties
Flash point: 135 °C (275 °F)-closed cup
Ignition temperature: 400 °C (752 °F)
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus for fire-fighting if necessary.

Toxicological Information

Acute toxicity: LD50 Oral-rat-8,030 mg/kg
                         LD50 Dermal-rabbit-4,248 mg/kg
Irritation and corrosion:
Eyes-rabbit-Mild eye irritation

Chemical Properties

Colorless transparent liquid

Uses

Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimet?hoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating

Uses

(3-Glycidoxypropyl)trimethoxysilane is used in the production of carbon steel and its pre treatment favors the dry and wet adhesion of epoxy coating. It is also used to prepare epoxy-functionalized silica nanoparticles, which gives a reactive surface for one-step and high-density protein immobilization. It serves as a coupling agent and adhesion promoter.

General Description

(3-Glycidyloxypropyl)trimethoxysilane (GPTMS) is a bifunctional organosilane with three methoxy groups on one side and an epoxy ring on the other. The methoxy groups bind well with glass substrates creating a 3D matrix. The epoxy group is reactive with amides, alcohols, thiols and acids. GPTMS is highly reactive in water and can be used as a linking agent between the surface of the silica and the polymeric matrix.

Flammability and Explosibility

Not classified

3-Glycidoxypropyltrimethoxysilane Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Glycidoxypropyltrimethoxysilane Suppliers

Chembridge International Corp.(Taipei/Dongguan/Nanjing)
Tel
025-84712192
Fax
025-84712052
Email
china@chembridge.net
Country
China
ProdList
192
Advantage
62
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
HUANSHAN KBR CHEMICAL CO., LTD
Tel
0559-2335676-658 18155919527
Fax
18155919527
Email
johnxu@kbrchem.com
Country
China
ProdList
121
Advantage
55
Chongqing Yuanyuanxiang Technology Development Co. LTD
Tel
023-55703781 15320534687
Fax
023-55703781
Email
2022434087@qq.com
Country
China
ProdList
4100
Advantage
58
Wuhan Xinyang Ruihe Chemical Technology Co., Ltd.
Tel
13720181483 13720181483
Email
366443693@QQ.COM
Country
China
ProdList
5032
Advantage
58
HUANGSHANJIAHUASILICONE CO,LTD
Tel
15212785412; 15212785412
Email
hsuzihang@163.com
Country
China
ProdList
71
Advantage
58
Nanjing Runiver Technology Co.,Ltd.
Tel
18014470519
Fax
025-52215598
Email
info@runivertech.com
Country
China
ProdList
18
Advantage
55
Shandong Bosheng Chemical Co., Ltd
Tel
0531-84444404 15288855587
Email
1076821571@qq.com
Country
China
ProdList
34
Advantage
58
Shanghai Boyle Chemical Co., Ltd.
Tel
021-50182298 021-50180596
Fax
+86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2208
Advantage
55
Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
Advantage
60
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View Lastest Price from 3-Glycidoxypropyltrimethoxysilane manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
3-Glycidoxypropyltrimethoxysilane 2530-83-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-11
Hebei Andu Technology Com.,Ltd
Product
3-Glycidoxypropyltrimethoxysilane 2530-83-8
Price
US $3.50/kg
Min. Order
1kg
Purity
≥99%
Supply Ability
3000tons/month
Release date
2024-08-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
3-Glycidoxypropyltrimethoxysilane 2530-83-8
Price
US $100.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-30

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