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ChemicalBook > CAS DataBase List > 3,4-Epoxytetrahydrofuran

3,4-Epoxytetrahydrofuran

Uses
Product Name
3,4-Epoxytetrahydrofuran
CAS No.
285-69-8
Chemical Name
3,4-Epoxytetrahydrofuran
Synonyms
3,6-DIOXABICYCLO[3.1.0]HEXANE;3,4-Epoxy-THF;4-Epoxytetrahydrofuran;3,4-EPOXYTETRAHYDROFURAN;3,4-Epoxytetrahydrofurane;3,4-Diepoxytetrahydrofuran;3,4-Epoxytetrahydrofuran>3,4-EPOXYTETRAHYDROFURAN 96%;3,4-Epoxytetrahydrofuran,96%;3,4-Epoxytetrahydrofuran, 98 %
CBNumber
CB2202349
Molecular Formula
C4H6O2
Formula Weight
86.09
MOL File
285-69-8.mol
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3,4-Epoxytetrahydrofuran Property

Boiling point:
44°C 10mm
Density 
1.237
refractive index 
1.445-1.449
Flash point:
>38℃
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Liquid
color 
Clear yellow
Water Solubility 
MODERATELY SOLUBLE
InChI
InChI=1S/C4H6O2/c1-3-4(6-3)2-5-1/h3-4H,1-2H2
InChIKey
AIUTZIYTEUMXGG-UHFFFAOYSA-N
SMILES
C12C(O1)COC2
CAS DataBase Reference
285-69-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-10
Safety Statements 
36/37/39-26-23-16-36/37/38
RIDADR 
1993
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
HS Code 
29321900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
PHB00276
Product name
3,4-Epoxytetrahydrofuran
Purity
AldrichCPR
Packaging
1 g
Price
$107
Updated
2025/07/31
TCI Chemical
Product number
E0795
Product name
3,4-Epoxytetrahydrofuran
Purity
>97.0%(GC)
Packaging
5g
Price
$87
Updated
2025/07/31
TCI Chemical
Product number
E0795
Product name
3,4-Epoxytetrahydrofuran
Purity
>97.0%(GC)
Packaging
25g
Price
$300
Updated
2025/07/31
TRC
Product number
D485245
Product name
3,6-Dioxabicyclo[3.1.0]hexane
Packaging
25g
Price
$150
Updated
2021/12/16
TRC
Product number
D485245
Product name
3,6-Dioxabicyclo[3.1.0]hexane
Packaging
1g
Price
$55
Updated
2021/12/16
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3,4-Epoxytetrahydrofuran Chemical Properties,Usage,Production

Uses

3,6-Dioxabicyclo[3.1.0]hexane was a reagent used in making various degradable polymers from epoxides using a versatile dinuclear chromium catalyst.

Chemical Properties

clear yellow liquid

Synthesis

1708-29-8

285-69-8

Step 1: 85% m-chloroperoxybenzoic acid (mCPBA) (18.86 g, 0.093 mol) was slowly added to 150 mL of dichloromethane solution containing 2,5-dihydrofuran (5.04 g, 0.072 mol) at 0°C in an ice-water bath. The reaction mixture was stirred at room temperature for 48 hours. After completion of the reaction, the precipitate was removed by filtration. The filtrate was washed sequentially with saturated aqueous sodium bicarbonate, water and brine. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to give a mixture of white solid and yellow oil (5.24 g, 84.6% yield).

References

[1] Patent: WO2008/33562, 2008, A2. Location in patent: Page/Page column 53
[2] Patent: US2009/76005, 2009, A1. Location in patent: Page/Page column 23
[3] Bioorganic and Medicinal Chemistry, 2006, vol. 14, # 24, p. 8467 - 8487
[4] Patent: US5374416, 1994, A
[5] Patent: US2009/30212, 2009, A1. Location in patent: Page/Page column 15-16

3,4-Epoxytetrahydrofuran Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3,4-Epoxytetrahydrofuran manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
3,4-Epoxytetrahydrofuran 285-69-8
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-21
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
3,4-Epoxytetrahydrofuran 285-69-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-31
Hebei Yanxi Chemical Co., Ltd.
Product
3,4-Epoxytetrahydrofuran 285-69-8
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-21

285-69-8, 3,4-EpoxytetrahydrofuranRelated Search:


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