3-(Benzyloxy)phenol
- Product Name
- 3-(Benzyloxy)phenol
- CAS No.
- 3769-41-3
- Chemical Name
- 3-(Benzyloxy)phenol
- Synonyms
- 3-Aenzyloxyphenol;3-(benzloxy)phenol;3-(BENZYLOXY)PHENOL;TIMTEC-BB SBB008506;M-(BENZYLOXY)PHENOL;3-(Benzyloxy)phenol>MONOBENZYL RESOURCINOL;3-(phenylmethoxy)phenol;3-(Benzyloxy)phenol ,95%;Phenol, 3-(phenylmethoxy)-
- CBNumber
- CB2209878
- Molecular Formula
- C13H12O2
- Formula Weight
- 200.23
- MOL File
- 3769-41-3.mol
3-(Benzyloxy)phenol Property
- Melting point:
- 50°C
- Boiling point:
- 200 °C / 5mmHg
- Density
- 1.0907 (rough estimate)
- refractive index
- 1.5906 (estimate)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- powder to crystal
- pka
- 9.59±0.10(Predicted)
- color
- White to Almost white
- CAS DataBase Reference
- 3769-41-3
- NIST Chemistry Reference
- Benzyl 3-hydroxyphenyl ether(3769-41-3)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-41
- Safety Statements
- 26-36/37/39-39
- HS Code
- 29095000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B2070
- Product name
- 3-(Benzyloxy)phenol
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $179
- Updated
- 2025/07/31
- Product number
- B2070
- Product name
- 3-(Benzyloxy)phenol
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $563
- Updated
- 2025/07/31
- Product number
- B521465
- Product name
- 3-(Benzyloxy)phenol
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- B521465
- Product name
- 3-(Benzyloxy)phenol
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB147402
- Product name
- 3-(Benzyloxy)phenol
- Packaging
- 2g
- Price
- $89
- Updated
- 2021/12/16
3-(Benzyloxy)phenol Chemical Properties,Usage,Production
Chemical Properties
White solid
Uses
3-(Benzyloxy)phenol is an isomer of benzyloxyphenol (BLP), which contains the structures 2-BLP, 3-BLP, and 4-BLP. 3-BLP is used for chromatographic identification or isomer extraction and separation studies.
Synthesis
100-39-0
108-46-3
3769-41-3
General procedure for the preparation of 3-benzyloxyphenol: Resorcinol (10.0 g, 90.9 mmol) was dissolved in acetone (50 mL) and cooled to 5-10 °C. With continuous stirring, anhydrous potassium carbonate (18.8 g, 136.3 mmol) was added. Maintaining this temperature, benzyl bromide (10.88 g, 63.6 mmol) was added slowly and the cooling bath was removed after 10 minutes. The reaction mixture was refluxed for 12 to 17 hours. After the temperature was reduced to 20 to 40°C, the solid potassium carbonate was removed by filtration. The filtrate was concentrated, poured into ice water, acidified with 6N hydrochloric acid and subsequently extracted with ethyl acetate (3 x 25 mL). The organic layers were combined, washed with water, dried over anhydrous sodium sulfate and evaporated to give a brown colloidal substance. Purification by column chromatography (230-400 mesh silica gel, eluent ethyl acetate:petroleum ether = 10:90), discarding the dibenzyloxyditerpene by-product, gave pure light brown colloidal target product 3-benzyloxyphenol. Yield: 13.5 g, 68% yield. Product characterization data: 1H NMR (CDCl3, 200MHz): δ 7.50-7.30 (m, 5H), 7.12 (t, J = 8.2Hz, 1H), 6.57 (dd, J = 1.8, 6.2Hz, 1H), 6.50-6.40 (m, 2H), 5.02 (s, 2H), 4.86 (bs, 1H, D2O exchangeable). Mass spectrum (CI): m/z 201 (M++1). IR (KBr, cm-1): 3406, 3032, 1595, 1490, 1454.
References
[1] Patent: US2014/256657, 2014, A1. Location in patent: Paragraph 0399
[2] Tetrahedron, 2007, vol. 63, # 43, p. 10698 - 10708
[3] Journal of Organic Chemistry, 1997, vol. 62, # 10, p. 3062 - 3075
[4] Journal of Medicinal Chemistry, 2004, vol. 47, # 17, p. 4155 - 4158
[5] Chemical Communications, 2018, vol. 54, # 39, p. 4935 - 4938
3-(Benzyloxy)phenol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-(Benzyloxy)phenol manufacturers
- Product
- 3-Benzyloxyphenol 3769-41-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20t
- Release date
- 2024-07-14
- Product
- 3-Benzyloxyphenol 3769-41-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2020-01-08