ChemicalBook > CAS DataBase List > 3-Hydroxybenzoic acid

3-Hydroxybenzoic acid

Product Name
3-Hydroxybenzoic acid
CAS No.
99-06-9
Chemical Name
3-Hydroxybenzoic acid
Synonyms
m-Hba;m-salicylicacid;m-Salicylic Aci;3-Carboxyphenol;m-Hydroxybenzoic;m-Salicylic acid;m-Oxybenzoic acid;3-hydroxybenzoate;RARECHEM AL BO 0049;meta-salicylic acid
CBNumber
CB4854760
Molecular Formula
C7H6O3
Formula Weight
138.12
MOL File
99-06-9.mol
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3-Hydroxybenzoic acid Property

Melting point:
200-203 °C (lit.)
Boiling point:
213.5°C (rough estimate)
Density 
1.4850
FEMA 
4431 | 3-HYDROXYBENZOIC ACID
refractive index 
1.4600 (estimate)
Flash point:
220 °C
storage temp. 
Store below +30°C.
pka
4.06(at 19℃)
form 
Powder
color 
White to off-white
PH
3 (H2O)Aqueous solution
Water Solubility 
slightly soluble
BRN 
508160
InChIKey
IJFXRHURBJZNAO-UHFFFAOYSA-N
CAS DataBase Reference
99-06-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 3-hydroxy-(99-06-9)
EPA Substance Registry System
m-Hydroxybenzoic acid (99-06-9)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
DH1924980
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29182990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
H20008
Product name
3-Hydroxybenzoic acid
Purity
ReagentPlus , 99%
Packaging
5g
Price
$28.1
Updated
2021/12/16
Sigma-Aldrich
Product number
36333
Product name
3-Hydroxybenzoic acid
Purity
analytical standard
Packaging
100mg
Price
$57.9
Updated
2021/12/16
Sigma-Aldrich
Product number
H20008
Product name
3-Hydroxybenzoic acid
Purity
ReagentPlus , 99%
Packaging
100g
Price
$51.8
Updated
2021/03/22
Sigma-Aldrich
Product number
H20008
Product name
3-Hydroxybenzoic acid
Purity
ReagentPlus , 99%
Packaging
500g
Price
$187
Updated
2021/03/22
Sigma-Aldrich
Product number
8.04537
Product name
3-Hydroxybenzoic acid for synthesis. CAS No. 99-06-9, EC Number 202-726-5., for synthesis
Packaging
8045370250
Price
$76.2
Updated
2020/08/18
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3-Hydroxybenzoic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

Intermediate for plasticizers, resins, light stabiliziers, petroleum additives, pharmaceuticals.

Uses

m- Hydroxybenzoic acid is reported as an intermediate in the manufacture of germicides, preservatives, pharmaceuticals, and plasticizer.

Uses

3-Hydroxybenzoic acid is used in perfumery. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals agrochemicals and dyestuff fields.

Definition

ChEBI: A monohydroxybenzoic acid that is benzoic acid substituted by a hydroxy group at position 3. It has been isolated from Taxus baccata.

Reactions

m-Hydroxybenzoic Acid, of the three hydroxybenzoic acids, the metaisomer is of least commercial importance. Unlike salicylic acid, m-hydroxybenzoic acid does not undergo the Friedel-Crafts reaction. It can be converted in 80% yield to m-aminophenol by the Schmidt reaction, which involves treating the acid with hydrazoic acid in trichloroethylene in the presence of sulfuric acid at 40 °C.

Synthesis Reference(s)

Tetrahedron Letters, 9, p. 3845, 1968 DOI: 10.1016/S0040-4039(01)99116-6

Purification Methods

Crystallise the hydroxyacid from absolute EtOH. [Beilstein 10 IV 315.]

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3-Hydroxybenzoic acid Suppliers

TAIZHOU HAIYING PHARMTECH CO.,LTD
Tel
0523-86222516
Email
sales@haiyingchem.com
Country
China
ProdList
60
Advantage
58
Shanghai Kaisai Chemical Co., Ltd
Tel
021-33516711;021-33516722
Fax
021-33516776
Email
kaisaichem1@163.com;kaisaichem1@163.com
Country
China
ProdList
4719
Advantage
58
shanghai science Bio-Pharmceutical.co,ltd.
Tel
0215-7872719
Fax
02157872719
Email
245662540@qq.com
Country
China
ProdList
310
Advantage
60
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
+86-021-61259100
Fax
86-21-61259102
Email
int02@meryer.com
Country
China
ProdList
40264
Advantage
62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30159
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2346
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1401
Advantage
62
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057- ;021-51691807
Fax
0757-86311057
Email
sales.gd@hwrkchemical.com;peter.shi@hwrkchemical.com
Country
China
ProdList
17295
Advantage
55
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View Lastest Price from 3-Hydroxybenzoic acid manufacturers

Shanxi Lianxu New Material Co., LTD
Product
3-Hydroxybenzoic acid 99-06-9
Price
US $30.00/KG
Min. Order
1KG
Purity
99.9%
Supply Ability
1000kg/month
Release date
2021-11-29
Xingtai Haoxun Import and Export Trade Co., Ltd.
Product
3-Hydroxybenzoic acid joyce 99-06-9
Price
US $20.00/KG
Min. Order
500g
Purity
99
Supply Ability
10tons
Release date
2020-07-14
Jinan Finer Chemical Co., Ltd
Product
3-Hydroxybenzoic acid 99-06-9
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
300mt/year
Release date
2021-07-28

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