ChemicalBook > CAS DataBase List > 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE

Product Name: 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
CAS No.: 95740-49-1
Chemical Name: 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
Synonyms: 2-bromo-5-methylbenzyl ether;1-bromo-2-methoxy-4-methylbenzene;Benzene,1-broMo-2-Methoxy-4-Methyl-;4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
CBNumber: CB22130017
Molecular Formula: C8H9BrO
Formula Weight: 201.06
MOL File: 95740-49-1.mol

Less

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Property

Melting point:: 104-105℃
Boiling point:: 107-109℃ (11 Torr)
storage temp.: Sealed in dry,Room Temperature
Appearance: Colorless to light yellow Liquid

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

Less

N-Bromosuccinimide Price

TRC

Product number: B696720
Product name: 1-Bromo-2-methoxy-4-methylbenzene
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Oakwood

Product number: 038665
Product name: 2-Bromo-5-methylanisole
Purity: 99%
Packaging: 5g
Price: $73
Updated: 2021/12/16

AK Scientific

Product number: X8417
Product name: 2-Bromo-5-methylanisole
Packaging: 1g
Price: $81
Updated: 2021/12/16

AK Scientific

Product number: X8417
Product name: 2-Bromo-5-methylanisole
Packaging: 5g
Price: $148
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0103790
Product name: 2-BROMO-5-METHYLANISOLE
Purity: 95.00%
Packaging: 1G
Price: $166.95
Updated: 2021/12/16

Less

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Chemical Properties,Usage,Production

Synthesis

39538-68-6

95740-49-1

General procedure for the synthesis of 2-bromo-5-methylanisole from 2-methoxy-4-methylaniline: under nitrogen protection, copper bromide (4.88 g, 21.8 mmol) was dissolved in acetonitrile (20 ml), ethyl nitrite (2.13 ml, 17.9 mmol) was added, and the reaction system was subsequently slowly heated up to 65 °C and maintained. A solution of 2-methoxy-4-methylaniline (2.24 g, 16.3 mmol) in acetonitrile (20 ml) was slowly added to the above reaction mixture and stirring was continued for 15 minutes. After completion of the reaction, the solvent was removed by vacuum distillation, the residue was dissolved in cyclohexane, washed sequentially with 3 x 3 NH3 aqueous solution and water, and the organic phase was dried with anhydrous Na2SO4. The solvent was again removed by vacuum distillation, and the resulting crude product was purified by fast chromatography (with chloroform as eluent) to afford the target product 2-bromo-5-methylanisole (1.92 g, 59% yield).1H-NMR (CDCl3) δ: 2.32 (s, 3H), 3.86 (s, 3H), 6.64 (dd, J = 8.0,1.4 Hz, 1H) , 6.72 (d, J = 1.4Hz, 1H), 7.39 (d, J = 8.0Hz, 1H). 13C-NMR (CDCl3) δ: 21.4,56.1,108.3,113.1,122.5,132.9,138.7,155.6.

References

[1] Patent: WO2005/123676, 2005, A1. Location in patent: Page/Page column 36-37
[2] Patent: WO2011/15641, 2011, A1. Location in patent: Page/Page column 134
[3] Patent: US2012/316161, 2012, A1. Location in patent: Page/Page column 44
[4] Zhurnal Obshchei Khimii, 1932, vol. 2, p. 472,475
[5] Chem. Zentralbl., 1933, vol. 104, # I, p. 604

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Suppliers

China 87 India 3 Switzerland 1 United Kingdom 2 United States 5 Global 98

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Yangzhou Siyu Chemical Co.,Ltd.

Tel: 0514-87325867
Fax: 0086-514-87325867
Email: sales@siyuchem.com
Country: China
ProdList: 370
Advantage: 55

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Shanghai Harvest Chemical Industrial Co., Ltd.

Tel: 021-31038972,31038973 17321035817
Fax: +86-21-51385350
Email: sales@harvest-chem.com
Country: China
ProdList: 2816
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

Wuhan Arike Technology Co., Ltd.

Tel: 027- 51832457 94518350
Fax: E-Mail Inquiry
Country: China
ProdList: 746
Advantage: 62

Nanjing Vital Chemical Co., Ltd.

Tel: Please Send Email 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 4378
Advantage: 65

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66113011 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19913
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

ShangHai Zexin Chemical Technology Co., Ltd.

Tel: 021-60136491 15901897992
Fax: 021-60136492
Country: China
ProdList: 455
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Modachem Shanghai Co., Ltd

Tel: +86 (0)21 51320687 51371369 1744605818
Fax: +86 (0)21 51371369
Country: China
ProdList: 1578
Advantage: 58

Tianjin Anhao Biological Technology Co., Ltd.

Tel
Email: sales@ahpharmatech.com
Country: China
ProdList: 5734
Advantage: 55

Nanjing Chalf-Pharm Technology Co., Ltd.

Tel: 025-57018978 18251899859
Fax: 025-57018008
Email: sales@chalf-pharm.com
Country: China
ProdList: 5674
Advantage: 50

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66028182 18626450290
Email: yftan@aikonchem.com
Country: China
ProdList: 16679
Advantage: 50

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12346
Advantage: 58

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

Hubei Chuangliankangcheng Pharmaceutical Co., Ltd.

Tel: 027-65388397 18164111589
Fax: 027-65388397
Email: 3321478047@qq.com
Country: China
ProdList: 2007
Advantage: 55

Nanjing Vital Chemical Co., Ltd.

Tel: 025-87193546 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 9021
Advantage: 60

ShangHai Siyan Biological Technology Co., Ltd.

Tel: 021-50908862，442785678，326799392 18721037013
Fax: 021-50908862
Email: siyansales@126.com
Country: China
ProdList: 9627
Advantage: 58

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Shijiazhuang Yesheng Chemical Technology Co., Ltd

Tel: 18031147013 18031147013;
Fax: 0311-68030586
Email: yeshengchemical@163.com
Country: China
ProdList: 2607
Advantage: 58

Shanghai Kangman Biological Technology Co., Ltd.

Tel: 18800375331
Fax: 021-50908862
Email: kangmansales@163.com
Country: China
ProdList: 7570
Advantage: 55

Shanghai CR Corporation Limited

Tel: 13062833949; 4006653949 4006653949
Fax: QQ: 2136646215
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 9755
Advantage: 58

Hangzhou Molcore Biopharmatech Co.,Ltd

Tel: 400-711-5280 86-571-81025280
Fax: 86-571-85806285
Email: sales@molcore.com
Country: China
ProdList: 9967
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718; +8613336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29735
Advantage: 60

Bejing Famous Pharmaceutical Technology Co., Ltd.

Tel: 13331045123
Fax: 86-10-80339217
Email: 2559355526@qq.com
Country: China
ProdList: 14193
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25000
Advantage: 58

Suzhou Xiya Pharmaceutical Co., Ltd.

Tel: 0512-87819718 18912655635
Email: 2587879032@qq.com
Country: China
ProdList: 1403
Advantage: 58

Fluoropharm Co., Ltd.

Tel: 0571-85586753 13336034509
Fax: 0571 85586753
Email: sales@fluoropharm.com
Country: China
ProdList: 1289
Advantage: 58

Shanghai SPAR pharmaceutical technology co., LTD

Tel: 021-000000
Email: admin@jingshipharmatech.com
Country: China
ProdList: 9853
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Shanghai Scochem Technology Co., Ltd.

Tel: 021-33758897
Email: sales@scochem.com
Country: China
ProdList: 1596
Advantage: 58

Xinyi Kaiwu Chemical Technology Co., Ltd.

Tel: 0516-0516-88997009 18651776937
Email: 4164357@qq.com
Country: China
ProdList: 3204
Advantage: 58

Allfluoro pharmaceutical co. ltd.

Tel: +86-400-0216110 +86-15958047586
Fax: 0086-21-33275002
Email: sales@allfluoro.com
Country: China
ProdList: 11385
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Win-Win chemical CO., Limited

Tel: +86-0086-577-64498589 +86-15355981851
Fax: 0086-577-56994596
Email: sales@win-winchemical.com
Country: China
ProdList: 14359
Advantage: 58

Henan Weituxi Chemical Technology Co., Ltd.

Tel: 0371-63284658 18135795563
Fax: QQ:2885349392
Email: 2885349392@qq.com
Country: China
ProdList: 9992
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23912
Advantage: 58

Block Chemical Technology (Shanghai) Co., LTD

Tel: 021-20432219 13918097649
Fax: QQ79021576
Email: li_jinfei@acblock-lab.com
Country: China
ProdList: 9673
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 +8613203830695
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29798
Advantage: 58

Fuxin Pharmaceutical

Tel: +86-021-021-50872116 +8613122107989
Email: contact@fuxinpharm.com
Country: China
ProdList: 10000
Advantage: 58

Less

View Lastest Price from 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE manufacturers

Career Henan Chemical Co

Product: 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE 95740-49-1
Price: US $1.00/g
Min. Order: 1g
Purity: 98%
Supply Ability: 100KG
Release date: 2020-01-12

Career Henan Chemical Co

Product: 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE 95740-49-1
Price: US $9.80/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg -1000kg
Release date: 2020-01-03

95740-49-1, 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATERelated Search:

4-BROMO-2,5-DIMETHOXYPHENETHYLAMINE HCL 2,4-DIBROMO-5-METHOXYTOLUENE 4-Bromo-2,5-dimethoxybenzaldehyde 4-BROMO-3,5-DIMETHOXYBENZOIC ACID Brodimoprim 4-BROMO-3,5-DIMETHOXYBENZALDEHYDE METHYL 3,5-DIBROMO-2,4-DIMETHOXY-6-METHYLBENZOATE 4-BROMO-2,5-DIMETHOXYTOLUENE 5-BROMO-4-METHOXY-7-METHYLINDANE (+/-)-2,5-DIMETHOXY-4-BROMO-AMPHETAMINE HYDROBROMIDE 2-[(5-BROMO-7-METHYL-2,3-DIHYDRO-1H-INDEN-4-YL)OXY]ACETOHYDRAZIDE AKOS BBS-00001989 SPECS AB-131/40897143 (+/-)DOB, [PROPYL-1,2-3H]- 2,5-DIMETHOXY-4-BROMAMPHETAMIN 4-(4-BROMO-2,5-DIETHOXY-PHENYL)-THIAZOL-2-YLAMINE 2,4,6-tribromo-3,5-dimethylphenyl 4-chlorobenzenecarboxylate AKOS BBS-00001986

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE

1-bromo-2-methoxy-4-methylbenzene

Benzene,1-broMo-2-Methoxy-4-Methyl-

2-bromo-5-methylbenzyl ether

95740-49-1