4-Bromo-2,5-dimethoxybenzaldehyde
- Product Name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- CAS No.
- 31558-41-5
- Chemical Name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- Synonyms
- Benzaldehyde, 4-bromo-2,5-dimethoxy-;4-Bromo-2,5-dimethoxybenzaldehyde 98%;4-Bromo-2,5-dimethoxybenzaldehyde, 98+%;4-bromo-2,5-dimethoxybenzaldehyde(SALTDATA: FREE);4-Bromo-2,5-dimethoxybenzaldehyde ISO 9001：2015 REACH
- CBNumber
- CB8947073
- Molecular Formula
- C9H9BrO3
- Formula Weight
- 245.07
- MOL File
- 31558-41-5.mol
4-Bromo-2,5-dimethoxybenzaldehyde Property
- Melting point:
- 132-135°C
- Boiling point:
- 337.1±42.0 °C(Predicted)
- Density
- 1.482±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- solid
- color
- Faint yellow to yellow
- Water Solubility
- Insoluble in water.
- Stability:
- Hygroscopic
- InChI
- InChI=1S/C9H9BrO3/c1-12-8-4-7(10)9(13-2)3-6(8)5-11/h3-5H,1-2H3
- InChIKey
- BIFWGDWGCZLCHF-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC(OC)=C(Br)C=C1OC
Safety
- HS Code
- 2913000090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B683545
- Product name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- Packaging
- 2.5g
- Price
- $120
- Updated
- 2021/12/16
- Product number
- OR0915
- Product name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- Purity
- 98%
- Packaging
- 25g
- Price
- $148
- Updated
- 2021/12/16
- Product number
- OR0915
- Product name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- Purity
- 98%
- Packaging
- 5g
- Price
- $43
- Updated
- 2021/12/16
- Product number
- J54600
- Product name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- Packaging
- 5g
- Price
- $48
- Updated
- 2021/12/16
- Product number
- 2615-9-X4
- Product name
- 4-Bromo-2,5-dimethoxybenzaldehyde
- Packaging
- 5G
- Price
- $52
- Updated
- 2021/12/16
4-Bromo-2,5-dimethoxybenzaldehyde Chemical Properties,Usage,Production
Uses
4-Bromo-2,5-dimethoxybenzene is used as a pharmaceutical intermediate.
Synthesis
93-02-7
31558-41-5
At 0 °C, 2,5-dimethoxybenzaldehyde (1.0 g, 6.02 mmol) was dissolved in glacial acetic acid (7 mL) and a solution of bromine (0.34 mL, 6.62 mmol) in glacial acetic acid (3 mL) was slowly added. The reaction mixture was gradually warmed to room temperature and stirred continuously for 1 hour. Upon completion of the reaction, water (30 mL) was added to quench the reaction and the resulting white precipitate was collected by filtration. The precipitate was redissolved in water (30 mL) and dichloromethane (30 mL) for liquid-liquid separation. The aqueous phase was extracted with dichloromethane (3 x 25 mL), and all organic phases were combined, washed with brine (25 mL), dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography (eluent: 20% ethyl acetate/hexane) to afford 4-bromo-2,5-dimethoxybenzaldehyde as a light yellow solid (0.83 g, 3.37 mmol, 56% yield).
References
[1] Organic and Biomolecular Chemistry, 2013, vol. 11, # 35, p. 5782 - 5786
[2] Tetrahedron, 2011, vol. 67, # 21, p. 3904 - 3914
[3] Journal of the American Chemical Society, 2011, vol. 133, # 40, p. 15870 - 15873
[4] Synthetic Communications, 1998, vol. 28, # 24, p. 4629 - 4637
[5] Tetrahedron Letters, 2003, vol. 44, # 16, p. 3281 - 3284
4-Bromo-2,5-dimethoxybenzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Bromo-2,5-dimethoxybenzaldehyde manufacturers
- Product
- 4-Bromo-2,5-dimethoxybenzaldehyde 31558-41-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 95%
- Supply Ability
- 2000
- Release date
- 2025-09-04
- Product
- 4-Bromo-2,5-dimethoxybenzaldehyde 31558-41-5
- Price
- US $10.00/KG
- Min. Order
- 100KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-22
- Product
- 4-Bromo-2, 5-Dimethoxybenzaldehyde 31558-41-5
- Price
- US $10.70/kg
- Min. Order
- 10kg
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-20