6,6'-Dichloro-2,2'-bipyridine
- Product Name
- 6,6'-Dichloro-2,2'-bipyridine
- CAS No.
- 53344-72-2
- Chemical Name
- 6,6'-Dichloro-2,2'-bipyridine
- Synonyms
- 2,2'-Bi(6-chloropyridine);6,6'-Dichloro-2,2'-bipyridine;2,2'-Bipyridine, 6,6'-dichloro-;2-chloro-6-(6-chloropyridin-2-yl)pyridine
- CBNumber
- CB22160430
- Molecular Formula
- C10H6Cl2N2
- Formula Weight
- 225.07
- MOL File
- 53344-72-2.mol
6,6'-Dichloro-2,2'-bipyridine Property
- Melting point:
- 220℃ (benzene )
- Boiling point:
- 354.7±37.0 °C(Predicted)
- Density
- 1.363±0.06 g/cm3 (20 ºC 760 Torr)
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- -0.40±0.10(Predicted)
- Appearance
- Off-white to pink Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- HCH0361427
- Product name
- 6,6'-DICHLORO-2,2'-BIPYRIDINE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $495.77
- Updated
- 2021/12/16
- Product number
- 2741CS
- Product name
- 6,6'-Dichloro-2,2'-bipyridine
- Packaging
- 1g
- Price
- $579
- Updated
- 2021/12/16
- Product number
- CM133591
- Product name
- 6,6''-dichloro-2,2''-bipyridine
- Purity
- 95%
- Packaging
- 5g
- Price
- $898
- Updated
- 2021/12/16
- Product number
- 53344722
- Product name
- 6,6'-Dichloro-2,2'-bipyridine
- Packaging
- 5g
- Price
- $940.8
- Updated
- 2021/12/16
- Product number
- CD51000830
- Product name
- 6,6'-Dichloro-2,2'-bipyridine
- Purity
- 95+%
- Packaging
- 5g
- Price
- $952
- Updated
- 2021/12/16
6,6'-Dichloro-2,2'-bipyridine Chemical Properties,Usage,Production
Synthesis
109-09-1
53344-72-2
The synthesis of 6,6'-dichloro-2,2'-bipyridine (52a) was achieved by reacting a mixture of BuLi/Me2N(CH2)2OLi with 2-chloropyridine as starting material. This mixture served as a base for selective lithiation of the C-6 region (Scheme 23). The 6-lithium-2-chloropyridine generated during the reaction was further reacted with the starting material 2-chloropyridine to produce the target coupling product 52a in 47% yield.
References
[1] Organic Letters, 2000, vol. 2, # 6, p. 803 - 805
[2] Patent: US2010/298562, 2010, A1. Location in patent: Page/Page column 34
[3] Organic Letters, 2000, vol. 2, # 6, p. 803 - 805
[4] Phosphorus and Sulfur and the Related Elements, 1987, vol. 34, p. 123 - 132
[5] Patent: CN107935919, 2018, A. Location in patent: Paragraph 0049; 0051
6,6'-Dichloro-2,2'-bipyridine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6,6'-Dichloro-2,2'-bipyridine manufacturers
- Product
- 2-cyano-1,10-phenanthroline 53344-72-2
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 95%-99%
- Supply Ability
- 100kg
- Release date
- 2018-12-24