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2-Amino-4,5-dichlorophenol

Product Name
2-Amino-4,5-dichlorophenol
CAS No.
28443-57-4
Chemical Name
2-Amino-4,5-dichlorophenol
Synonyms
Lenvatinib Impurity 87;2-AMINO-4,5-DICHLORPHENOL;2-Amino-4,5-dichlorophenol;Phenol, 2-amino-4,5-dichloro-;4,5-Dichloro-2-hydroxyaniline
CBNumber
CB22205764
Molecular Formula
C6H5Cl2NO
Formula Weight
178.02
MOL File
28443-57-4.mol
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2-Amino-4,5-dichlorophenol Property

Melting point:
174-175 °C
Boiling point:
309.1±42.0 °C(Predicted)
Density 
1.560±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
powder
pka
8.36±0.23(Predicted)
color 
Very dark beige to very dark brown
EPA Substance Registry System
Phenol, 2-amino-4,5-dichloro- (28443-57-4)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
29089990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A596850
Product name
2-Amino-4,5-dichlorophenol
Packaging
500mg
Price
$145
Updated
2021/12/16
AK Scientific
Product number
V4907
Product name
2-Amino-4,5-dichlorophenol
Packaging
250mg
Price
$120
Updated
2021/12/16
SynQuest Laboratories
Product number
4656-5-Y1
Product name
2-Amino-4,5-dichlorophenol
Packaging
1g
Price
$130
Updated
2021/12/16
Apolloscientific
Product number
OR16946
Product name
2-Amino-4,5-dichlorophenol
Packaging
250mg
Price
$51
Updated
2021/12/16
SynQuest Laboratories
Product number
4656-5-Y1
Product name
2-Amino-4,5-dichlorophenol
Packaging
250mg
Price
$61
Updated
2021/12/16
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2-Amino-4,5-dichlorophenol Chemical Properties,Usage,Production

Synthesis

39224-65-2

28443-57-4

The general procedure for the synthesis of 2-hydroxy-4,5-dichloroaniline from 4,5-dichloro-2-nitrophenol was as follows: to a stirred mixed solution of 4,5-dichloro-2-nitrophenol (15 g, 72 mmol) in acetic acid (150 mL) and water (450 mL) was added powdered iron (16 g, 285 mmol) in batches. The reaction mixture was stirred continuously at 50 °C for 2 hours. Upon completion of the reaction, the mixture was cooled to room temperature and subjected to filtration operation and the filter cake was washed with ethyl acetate. The filtrate was subsequently extracted with ethyl acetate. The combined organic layers were washed sequentially with water, NaHCO3 (aq.) and brine, dried over Na2SO4 and concentrated under vacuum to give the final target product 2-hydroxy-4,5-dichloroaniline (10 g, 78% yield).

References

[1] Journal of Organic Chemistry, 1996, vol. 61, # 10, p. 3289 - 3297
[2] Patent: US2014/288045, 2014, A1. Location in patent: Paragraph 0456
[3] European Journal of Medicinal Chemistry, 2012, vol. 56, p. 108 - 119
[4] Patent: WO2018/37223, 2018, A1. Location in patent: Page/Page column 81
[5] Journal of the Chemical Society, 1956, p. 4727,4730

2-Amino-4,5-dichlorophenol Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Amino-4,5-dichlorophenol Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Shanghai Sunway Pharmaceutical Technology Co., Ltd
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18270980682
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021 51613951
Email
mlcheng@sunwaypharm.cn
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China
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8669
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9ding chemical ( Shanghai) Limited
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4009209199
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86-021-52271987
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China
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Nanjing ShengSai Chemical Co., Ltd.
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025-85205967 13951876367
Fax
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shengsaichem@163.com
Country
China
ProdList
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Bide Pharmatech Ltd.
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China
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ChemStrong Scientific Co.,Ltd
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NovoChemy Ltd.
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Chengdu J&B Technology Co., Ltd.
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028-61186694 15608078506
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China
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55
SuZhou ShiYa Biopharmaceuticals, Inc.
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0512-0512-52358471 17715136450
Fax
05125235 6881
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sales@shiyabiopharm.com
Country
China
ProdList
12127
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View Lastest Price from 2-Amino-4,5-dichlorophenol manufacturers

Career Henan Chemical Co
Product
2-Amino-4,5-dichlorophenol 28443-57-4
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1000kgs
Release date
2019-12-18

28443-57-4, 2-Amino-4,5-dichlorophenolRelated Search:


  • 2-Amino-4,5-dichlorophenol
  • 4,5-Dichloro-2-hydroxyaniline
  • 2-AMINO-4,5-DICHLORPHENOL
  • Phenol, 2-amino-4,5-dichloro-
  • Lenvatinib Impurity 87
  • 28443-57-4