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methyl morpholine-2-carboxylate hydrochloride

Product Name
methyl morpholine-2-carboxylate hydrochloride
CAS No.
937063-34-8
Chemical Name
methyl morpholine-2-carboxylate hydrochloride
Synonyms
Methyl morpholine-2-carboxylate, HCl;2-Morpholinecarboxylic acid methyl ester HCl;methyl morpholine-2-carboxylate hydrochloride;2-Morpholinecarboxylic acid methyl ester hydrochloride (1:1)
CBNumber
CB22538211
Molecular Formula
C6H12ClNO3
Formula Weight
181.62
MOL File
937063-34-8.mol
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methyl morpholine-2-carboxylate hydrochloride Property

storage temp. 
Inert atmosphere,Room Temperature
Appearance
White to off-white Solid
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Safety

RIDADR 
UN2811
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M218788
Product name
MethylMorpholine-2-carboxylateHydrochloride
Packaging
10mg
Price
$60
Updated
2021/12/16
Matrix Scientific
Product number
075797
Product name
Methyl morpholine-2-carboxylate hydrochloride
Purity
95+%
Packaging
1g
Price
$122
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-5-JH
Product name
Methyl morpholine-2-carboxylate hydrochloride
Packaging
1g
Price
$144
Updated
2021/12/16
AK Scientific
Product number
J90176
Product name
Methylmorpholine-2-carboxylatehydrochloride
Packaging
10g
Price
$180
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-5-JH
Product name
Methyl morpholine-2-carboxylate hydrochloride
Packaging
5G
Price
$424
Updated
2021/12/16
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methyl morpholine-2-carboxylate hydrochloride Chemical Properties,Usage,Production

Uses

Methyl Morpholine-2-carboxylate Hydrochloride is used as a preparation of chromen-4-one derivative for the treatment of hepatitis B virus infection.

Synthesis

500789-41-3

937063-34-8

The general procedure for the synthesis of methyl morpholine-2-carboxylate hydrochloride from methyl N-Boc-2-morpholinecarboxylate was as follows: to a solution of 1,4-dioxane (1.0 mL) containing methyl 4-(tert-butoxycarbonyl)-2-morpholinecarboxylate (232 mg, 0.95 mmol) was added a solution of 1,4-dioxane (1.18 mL) with 4 M hydrochloric acid. The reaction mixture was stirred at room temperature for 15 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure to afford methyl morpholine-2-carboxylate hydrochloride (232 mg, 0.95 mmol, quantitative yield). The structure of the product was confirmed by 1H NMR (CDCl3) with the following chemical shifts: δ 3.03-3.19 (2H, m), 3.26-3.45 (2H, m), 3.55-3.69 (1H, m), 3.82 (3H, s), 4.03-4.22 (2H, m), 4.58-4.69 (1H, m).

References

[1] Bioorganic and Medicinal Chemistry, 2012, vol. 20, # 9, p. 3072 - 3093

methyl morpholine-2-carboxylate hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl morpholine-2-carboxylate hydrochloride Suppliers

PharmaBlock Sciences (Nanjing),Inc.
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55
ForeChem (Nantong) Technology Co.,Ltd.
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Adamas Reagent, Ltd.
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Shandong Xiya Chemical Co., Ltd
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18729
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Shanghai Sunway Pharmaceutical Technology Co., Ltd
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021 51613951
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Shanghai Sheepchem Co., Ltd.
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Amatek Scientific Co. Ltd.
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Bide Pharmatech Ltd.
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+86-21-61629029
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Chengdu Firster Pharmaceutical Co., Ltd.
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028-87078428 028-87074958
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8772-8116
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chengzhenyong@cdfirster.com
Country
China
ProdList
2598
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View Lastest Price from methyl morpholine-2-carboxylate hydrochloride manufacturers

Career Henan Chemical Co
Product
methyl morpholine-2-carboxylate hydrochloride 937063-34-8
Price
US $5.00/KG
Min. Order
1KG
Purity
95%-98%
Supply Ability
100kg
Release date
2019-09-03