ChemicalBook > CAS DataBase List > 6-Methyl-3piperidinecarboxylic acid Methyl ester

6-Methyl-3piperidinecarboxylic acid Methyl ester

Product Name
6-Methyl-3piperidinecarboxylic acid Methyl ester
CAS No.
908245-03-4
Chemical Name
6-Methyl-3piperidinecarboxylic acid Methyl ester
Synonyms
ethyl 6-Methylpiperidine-3-carboxylate;Methyl 6-Methylpiperidine-3-carboxylate;6-Methyl-piperidinecarboxylic acid Methyl ester;6-Methyl-3piperidinecarboxylic acid Methyl ester;Methyl 6-methylpiperidine-3-carboxylate - [M9067];3-Piperidinecarboxylic acid, 6-methyl-, methyl ester
CBNumber
CB22593618
Molecular Formula
C8H15NO2
Formula Weight
157.21
MOL File
908245-03-4.mol
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6-Methyl-3piperidinecarboxylic acid Methyl ester Property

Boiling point:
205.9±33.0 °C(Predicted)
Density 
0.982±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka
9.47±0.10(Predicted)
Appearance
Colorless to light yellow Liquid
optical activity
0.40°(C=0.01g/ml CHCL3)
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M356100
Product name
Methyl6-methylpiperidine-3-carboxylate
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
Z5322
Product name
Methyl6-methylpiperidine-3-carboxylate
Packaging
5g
Price
$911
Updated
2021/12/16
Matrix Scientific
Product number
071308
Product name
Methyl 6-methylpiperidine-3-carboxylate
Purity
97%
Packaging
5g
Price
$1015
Updated
2021/12/16
SynQuest Laboratories
Product number
4H23-1-8J
Product name
6-Methyl-3-piperidinecarboxylic acid methyl ester
Packaging
1g
Price
$1402
Updated
2021/12/16
J&W Pharmlab
Product number
60R0880
Product name
6-Methyl-piperidine-3-carboxylicacidmethylester
Purity
98%
Packaging
25g
Price
$2770
Updated
2021/12/16
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6-Methyl-3piperidinecarboxylic acid Methyl ester Chemical Properties,Usage,Production

Synthesis

5470-70-2

908245-03-4

The general procedure for the synthesis of methyl 6-methyl-3-piperidinecarboxylate from methyl 6-methylnicotinate was as follows: methanol (300 mL), concentrated hydrochloric acid (13.0 g), 10% Pd/C catalyst (4.0 g), and methyl 6-methylnicotinate (20.0 g, 132 mmol) were added to a 400 mL Fisher-Porter reactor. The mixture was heated to 80 °C and stirred at 60 psi hydrogen pressure for 21 hours. Upon completion of the reaction, the mixture was cooled and filtered to remove the catalyst. The filtrate was evaporated under reduced pressure to afford methyl 6-methyl-3-piperidinecarboxylate (27.0 g, quantitative yield). The structure of the product was confirmed by 1H NMR to be consistent with the target compound.

References

[1] Patent: US2010/93706, 2010, A1. Location in patent: Page/Page column 34
[2] Patent: EP3248980, 2017, A1. Location in patent: Paragraph 0163; 0164; 0165
[3] Patent: WO2010/124055, 2010, A1. Location in patent: Page/Page column 39-40
[4] Patent: WO2011/26917, 2011, A1. Location in patent: Page/Page column 93
[5] Patent: WO2011/26904, 2011, A1. Location in patent: Page/Page column 93

6-Methyl-3piperidinecarboxylic acid Methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Methyl-3piperidinecarboxylic acid Methyl ester Suppliers

Shanghai Sphchem Co., Ltd.
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NovoChemy Ltd.
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JW & Y Pharmlab Co., Ltd.
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View Lastest Price from 6-Methyl-3piperidinecarboxylic acid Methyl ester manufacturers

Anhui Dexinjia Biopharm Co., Ltd
Product
6-Methyl-3piperidinecarboxylic acid Methyl ester 908245-03-4
Price
US $200.00-150.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
20 tons
Release date
2024-05-20

908245-03-4, 6-Methyl-3piperidinecarboxylic acid Methyl esterRelated Search:


  • 6-Methyl-3piperidinecarboxylic acid Methyl ester
  • ethyl 6-Methylpiperidine-3-carboxylate
  • Methyl 6-Methylpiperidine-3-carboxylate
  • 3-Piperidinecarboxylic acid, 6-methyl-, methyl ester
  • 6-Methyl-piperidinecarboxylic acid Methyl ester
  • Methyl 6-methylpiperidine-3-carboxylate - [M9067]
  • 908245-03-4