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4-phenylnaphthalen-1-ylboronic acid

Product Name
4-phenylnaphthalen-1-ylboronic acid
CAS No.
372521-91-0
Chemical Name
4-phenylnaphthalen-1-ylboronic acid
Synonyms
(4-Phenylnaphthalen-1-yl);4-Phenylnaphthalene-1-boronic acid;1-(4-phenylnaphthalene)boronic acid;4-phenylnaphthalen-1-ylboronic acid;4-Phenylnaphthalene-1-boronic acid97;(1-Phenylnaphthalen-4-yl)boronic acid;4-phenyl(napthalene-1-yl)boronic acid;4-Phenylnaphthalene-1-boronicacid,98%;(1-phenylnaphthalene-4-yl) boric acid;B-(4-phenyl-1-naphthalenyl)boronic acid
CBNumber
CB22609935
Molecular Formula
C16H13BO2
Formula Weight
248.08
MOL File
372521-91-0.mol
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4-phenylnaphthalen-1-ylboronic acid Property

Boiling point:
449.4±48.0 °C(Predicted)
Density 
1.23
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Solid
pka
8.54±0.30(Predicted)
color 
White to Almost white
InChI
InChI=1S/C16H13BO2/c18-17(19)16-11-10-13(12-6-2-1-3-7-12)14-8-4-5-9-15(14)16/h1-11,18-19H
InChIKey
BSKLSKWOKGVQHF-UHFFFAOYSA-N
SMILES
B(C1=C2C(C=CC=C2)=C(C2=CC=CC=C2)C=C1)(O)O
CAS DataBase Reference
372521-91-0
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Safety

Hazard Codes 
Xi
Risk Statements 
41
Safety Statements 
26-39
WGK Germany 
WGK 3
HS Code 
2931.90.9051
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Dam. 1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
BML00310
Product name
4-Phenyl(napthalene-1-yl)boronic acid
Purity
Aldrich
Packaging
1g
Price
$114
Updated
2026/03/19
TCI Chemical
Product number
P2290
Product name
4-Phenylnaphthalene-1-boronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$74
Updated
2026/03/19
TCI Chemical
Product number
P2290
Product name
4-Phenylnaphthalene-1-boronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$256
Updated
2021/12/16
TRC
Product number
P399665
Product name
(4-Phenylnaphthalen-1-yl)boronicAcid
Packaging
10mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
X0073
Product name
4-Phenyl(naphthalene-1-yl)boronicacid
Packaging
25g
Price
$463
Updated
2021/12/16
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4-phenylnaphthalen-1-ylboronic acid Chemical Properties,Usage,Production

Synthesis

5419-55-6

59951-65-4

372521-91-0

Example 1: Preparation of compound C-12 Preparation of Compound 2 [(4-phenylnaphthalen-1-yl)boronic acid] [1081] 1-bromo-4-phenylnaphthalene (Compound 1) (50 g, 176 mmol) was dissolved in anhydrous tetrahydrofuran (THF) (1 L) in a flask. The mixture was stirred at -78°C and n-butyllithium (n-BuLi) (2.5 M in hexane, 132 mL) was added slowly and dropwise. The reaction mixture was stirred at room temperature for 1 hour. Subsequently, the reaction mixture was cooled to -78°C and triisopropyl borate (61 mL, 264 mmol) was added slowly and dropwise. The reaction mixture was then stirred at room temperature for 3 hours. After completion of the reaction, extraction was carried out with ethyl acetate. The organic layer obtained from the extraction was dried with magnesium sulfate (MgSO) and solidified by hexane to give compound 2 (30 g, 68% yield).

References

[1] Patent: WO2014/88290, 2014, A1. Location in patent: Paragraph 105; 106; 107; 108

4-phenylnaphthalen-1-ylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-phenylnaphthalen-1-ylboronic acid Suppliers

Shijiazhuang Jia Teng New Material Technology Co., Ltd.
Tel
13932181200; 13932181200
Fax
0311-66571551
Email
hou@sjzjtchem.com
Country
China
ProdList
287
Advantage
60
Qinyang Chuang'an Chemical Technology Co., Ltd
Tel
0371-61280670 15617977826
Fax
0371-61280670
Email
3007367019@qq.com
Country
China
ProdList
303
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58
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
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Adamas Reagent, Ltd.
Tel
400-6009262 15618770481
Fax
021-64823266
Email
yhx@titansci.com
Country
China
ProdList
14101
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Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070 13770331960
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16027
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Springchem New Material Technology Co.,Limited
Tel
+86-021-62885108 +8613917661608
Email
info@spring-chem.com
Country
China
ProdList
2068
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57
ZhengZhou HuaWen Chemical Co.Ltd
Tel
0370-2785118 17550508557
Fax
QQ:3470079902
Email
675141927@qq.com
Country
China
ProdList
3199
Advantage
55
Anhui Sholon New Material Technology Co., Ltd.
Tel
0550-5261666 19901505185
Fax
0550-5261919
Email
sales@sholonchem.com
Country
China
ProdList
262
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58
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View Lastest Price from 4-phenylnaphthalen-1-ylboronic acid manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-phenylnaphthalen-1-ylboronic acid 372521-91-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-02
Henan Aochuang Chemical Co.,Ltd.
Product
4-phenylnaphthalen-1-ylboronic acid 372521-91-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-27
Henan Fengda Chemical Co., Ltd
Product
4-phenylnaphthalen-1-ylboronic acid 372521-91-0
Price
US $32.00-1.50/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-22

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