Methyl 7-quinolinecarboxylate
- Product Name
- Methyl 7-quinolinecarboxylate
- CAS No.
- 51552-68-2
- Chemical Name
- Methyl 7-quinolinecarboxylate
- Synonyms
- Valine Impurity 5;Methyl 7-quinolinecarboxylate;Methyl quinoline-7-carboxylate;7-Quinolinecarboxylic acid, methyl ester;Quinoline-7-carboxylic acid methyl ester
- CBNumber
- CB22652830
- Molecular Formula
- C11H9NO2
- Formula Weight
- 187.19
- MOL File
- 51552-68-2.mol
Methyl 7-quinolinecarboxylate Property
- Boiling point:
- 315.1±15.0 °C(Predicted)
- Density
- 1.210±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 2.95±0.14(Predicted)
- Appearance
- Off-white to light yellow Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- CHM0393420
- Product name
- METHYL QUINOLINE-7-CARBOXYLATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $505.44
- Updated
- 2021/12/16
- Product number
- A521517
- Product name
- Methylquinoline-7-carboxylate
- Purity
- 95+%
- Packaging
- 100mg
- Price
- $41
- Updated
- 2021/12/16
- Product number
- A521517
- Product name
- Methylquinoline-7-carboxylate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $68
- Updated
- 2021/12/16
- Product number
- A521517
- Product name
- Methylquinoline-7-carboxylate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $152
- Updated
- 2021/12/16
- Product number
- 51552682
- Product name
- Methylquinoline-7-carboxylate
- Packaging
- 250mg
- Price
- $194.02
- Updated
- 2021/12/16
Methyl 7-quinolinecarboxylate Chemical Properties,Usage,Production
Synthesis
67-56-1
325-14-4
51552-68-2
General procedure for the synthesis of methyl 7-quinolinecarboxylate from methanol and 7-(trifluoromethyl)quinoline: a mixture of 7-(trifluoromethyl)quinoline (8.9 g, 1 eq.) and 35.6 mL of 10% fuming sulfuric acid was heated at 150 °C for 3 hours, and subsequently cooled to room temperature. To the reaction mixture was added 90 mL of methanol and heated at 80 °C overnight. Upon completion of the reaction, the methanol was removed by distillation. The residue was dissolved in 200 mL of water, neutralized with sodium carbonate solution and subsequently extracted three times with ethyl acetate. The organic phases were combined, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The crude product was washed with petroleum ether to afford methyl 7-quinolinecarboxylate (7.4 g, 88% yield) as a white solid.
References
[1] Patent: US2010/234340, 2010, A1. Location in patent: Page/Page column 21
[2] Bioorganic and Medicinal Chemistry, 2005, vol. 13, # 1, p. 59 - 68
[3] Patent: US2004/204455, 2004, A1. Location in patent: Page/Page column 21
[4] Bioorganic and Medicinal Chemistry Letters, 1999, vol. 9, # 10, p. 1403 - 1408
[5] Patent: US2008/275037, 2008, A1. Location in patent: Page/Page column 33
Methyl 7-quinolinecarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 7-quinolinecarboxylate manufacturers
- Product
- methylquinoline-7-carboxylate 51552-68-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 97.3%
- Supply Ability
- 100 tons
- Release date
- 2022-01-14