Tralkoxydim

ChemicalBook > CAS DataBase List > Tralkoxydim

Physical and Chemical Properties InChI Code Toxicity Application Synthesis

Product Name: Tralkoxydim
CAS No.: 87820-88-0
Chemical Name: Tralkoxydim
Synonyms: TRALKOXIDYM;GRASP;pp604;ACHIEVE;Fd 4026;Achiveve;splendor;Ici-A 604;Hsdb 7016;Grasp 604
CBNumber: CB2299916
Molecular Formula: C20H27NO3
Formula Weight: 329.43
MOL File: 87820-88-0.mol

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Tralkoxydim Property

Melting point:: 106°
Boiling point:: 467.02°C (rough estimate)
Density: 1.1213 (rough estimate)
refractive index: 1.5614 (estimate)
Flash point:: >100 °C
storage temp.: 0-6°C
solubility: soluble in dichloromethane,Toluene,Acetone
pka: 4.20±0.25(Predicted)
color: Light yellow to Yellow to Orange
Merck: 14,9564
BRN: 8577523
LogP: 4.460
CAS DataBase Reference: 87820-88-0(CAS DataBase Reference)
EPA Substance Registry System: Tralkoxydim (87820-88-0)

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Safety

Hazard Codes: Xn
Risk Statements: 22
RIDADR: UN 3077 9 / PGIII
WGK Germany: 3
RTECS: GW7191600
HazardClass: 9
PackingGroup: III
HS Code: 29280000
Hazardous Substances Data: 87820-88-0(Hazardous Substances Data)
Toxicity: LD50 orally in male and female rats, male and female mice, male rabbit (mg/kg): 1324, 934, 1231, 1100, 519; dermally in male and female rats: >2000, >2000 mg/kg (Warner 1987)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 36536
Product name: Tralkoxidym
Purity: PESTANAL
Packaging: 250mg
Price: $74.7
Updated: 2022/05/15

TCI Chemical

Product number: T2916
Product name: Tralkoxydim
Packaging: 200MG
Price: $27
Updated: 2024/03/01

TCI Chemical

Product number: T2916
Product name: Tralkoxydim
Packaging: 1G
Price: $87
Updated: 2024/03/01

TRC

Product number: T712403
Product name: Tralkoxidym
Packaging: 250mg
Price: $50
Updated: 2021/12/16

Chem-Impex

Product number: 39336
Product name: Tralkoxydim,95%(HPLC)
Purity: 95%(HPLC)
Packaging: 200MG
Price: $61.6
Updated: 2021/12/16

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Tralkoxydim Chemical Properties,Usage,Production

Physical and Chemical Properties

Appearance: White tasteless crystalline solid
Melting Point: 106℃
Saturated Vapor Pressure: 4×10-7Pa (<0.013×10-3Pa 20℃)
Solubility: 4×10-7Pa (<0.013×10-3Pa 20℃) in dichloromethane at 24℃, 213g/L in methylbenzene at 24℃, 110g/L in ethyl acetate at 24℃, 89g/L in acetone at 24℃, 25g/L in methanol at 24℃, 18g/L in hexane at 24℃.
6mg/L (pH=6.5) and 5mg/L (pH=5.0) in water at 20℃

InChI Code

1S/C20H27NO3/c1-6-16(21-24-7-2)20-17(22)10-15(11-18(20)23)19-13(4)8-12(3)9-14(19)5/h8-9,15,22H,6-7,10-11H2,1-5H3

Toxicity

P.O. acute toxicity： LD50=1324mg/kg for male rats, LD50=934mg/kg for female rats, LD50=1321mg/kg for male mice, LD50=1100mg/kg for female mice, LD50>519mg/kg for rabbits.
Non-effect dose for rats in three-month feed test is 12.5mg/kg. LD50=3020mg/kg for mallard, LD50=4430mg/kg for partridge.
Acute percutaneous toxicity: LD50>2000mg/kg for male and female rats.
Acute inhalation toxicity: LC50>3467mg/m3 for male and female rats.
It has mild irritation on eyes and skin. No allergic effect on cavy.
No teratogenesis effect has been observed yet.
LC50>7.2mg/L (96h) for rainbow trout, LC50>8.2mg/L (96h) for Cyprinus carpio var.

Application

Tralkoxydim is a kind of highly selective herbicide with inward absorption and conduction ability. It’s used on a variety of graminaceous weeds in barley and wheat fields. It is rapidly absorbed and transferred throughout all parts of the weeds after foliar spray. The weeds will soon turn pale and wither. The general dosage is 150～350g effective constituent/hm2 . 200～350g effective constituent /hm2 of tralkoxydim applied from early growth period to elongation stage will be effective on the prevention and control of wild oat weeds.

Synthesis

The product of the reaction between 2,4,6-Trimethylbenzaldehyde and acetone react with diethyl malonate to generate an intermediate. The intermediate is transformed into 3-hydroxy-5-（2',4',6'-trimethylphenyl）-cyclohexyl-2-alkenyl-1-ketone after hydrolysis, cyclization and decarboxylation. Then it reacts with propionic anhydride in the presence of sodium methanol. The product reacts with ethoxyamine hydrochloride to generate methoxyphenone.

Uses

Post-emergent herbicide.

Definition

ChEBI: Tralkoxydim is a mixture.

Agricultural Uses

Herbicide: Tralkoxydim is a post-emergent herbicide applied to actively growing weeds in wheat, barley, triticale and cereal rye to control wild oats, green foxtail, yellow foxtail, annual ryegrass and Persian darnel. Registered for use in EU countries. Registered for use in the U.S.

Trade name

ACHIEVE®; ACHIEVE®-40DG; ALPHA GRASP®; ICI-A 604®; PP 604®; SPLENDOR®

Tralkoxydim Preparation Products And Raw materials

Raw materials

Ethoxyamine hydrochloride Mesitaldehyde Propionic anhydride 2-Cyclohexen-1-one METHOXYPHENONE

Preparation Products

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View Lastest Price from Tralkoxydim manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Tralkoxydim 87820-88-0
Price: US $99.00-45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-11-12

Hebei Mujin Biotechnology Co.,Ltd

Product: Tralkoxydim 87820-88-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-16

Hebei Weibang Biotechnology Co., Ltd

Product: Tralkoxydim 87820-88-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-04

87820-88-0, TralkoxydimRelated Search:

3-Fluorobenzotrifluoride 2-Ethoxyphenol DIETHOXYMETHANE Propyl gallate acetic acid, triethoxy-, ethyl ester 3-Aminobenzotrifluoride Tricresyl Phosphate 1,2,4-Trimethylbenzene Benzotrifluoride 4-Ethoxyphenol CHLOROPHOSPHONAZO III Propyl butyrate Toltrazuril Ethoxyquin Mesitylene BUTROXYDIM TRITON 5-O-TOLYL-2-PENTENE 98

2-[1-（ethoxyimino) propyl]-3-hydroxy-5-mestiylcyclohexen-2-one

Fd 4026

Hsdb 7016

Ici-A 604

Tralkoxydim 500mg [87820-88-0]

GRASP

Achiveve

Grasp 604

ICI AO 604

2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethylphenyl)cyclohex-2-enone

ACHIEVE

TRALKOXIDYM

TRALOXYDIM

DQFPEYARZIQXRM-UHFFFAOYSA-N

Tralkoxydim Solution, 100ppm

(Z)-4-(1-(ethoxyimino)propyl)-5-hydroxy-2',4',6'-trimethyl-1,6-dihydro-[1,1'-biphenyl]-3(2H)-one

TRALKOXYDIM

TRALKOXYDIME

2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,6-trimethylphenyl)-2-cyclohexen-1

2-(1-(ethoxyimino)propyl)-3-hydroxy-5-mesitylcyclohex-2-enone

2-cyclohexen-1-one,2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,6-trimethylpheny

pp604

splendor

2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,,6-trimethylphenyl-2-cyclohexen-1-one

2-(1-(ethoxyimino)propyl)-3-hydroxy-5-mesi tylcyclohexen-2-one

TRALKOXIDYM PESTANAL, 250 MG

2-(1-[Ethoxyamino]propyl)-3-hydroxy-5-(2,4,6-trimethylphenyl)cyclohex-2-enone

2-Cyclohexen-1-one, 2-1-(ethoxyimino)propyl-3-hydroxy-5-(2,4,6-trimethylphenyl)-

tralkoxydim (bsi,iso)

(2S)-2-amino-3-(4-azido-3-iodophenyl)propanoic acid

Grasp(TM)

Tralkoxydim@1000 μg/mL in Methanol

Tralkoxydim Standard

Tralkoxydim @100 μg/mL in MeOH

4-(1-(Ethoxyimino)propyl)-5-hydroxy-2',4',6'-trimethyl-1,6-dihydro-[1,1'-biphenyl]-3(2H)-one

Tralkoxydim 100 μg/ml Acetonitrile

Fruquintinib Impurity 1

87820-88-0

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