9-BBN TRIFLATE

Product Name: 9-BBN TRIFLATE
CAS No.: 62731-43-5
Chemical Name: 9-BBN TRIFLATE
Synonyms: 9-BBN·CF3SO3;9-BBN TRIFLATE;9-bbn triflate solution;9-BBN Triflate solution 0.5 M in hexanes;9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES;9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E;9-Borabicyclononyl Trifluoromethanesulfonate;9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE;9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate;9-Borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
CBNumber: CB2303895
Molecular Formula: C9H14BF3O3S
Formula Weight: 270.07
MOL File: 62731-43-5.mol

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9-BBN TRIFLATE Property

Boiling point:: 265.7±50.0 °C(Predicted)
Density: 0.733 g/mL at 25 °C
Flash point:: -22 °C
solubility: sol common inert organic solvents such as Et2O, CH2Cl2, and hexane.
form: liquid
BRN: 995656

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Safety

Hazard Codes: F,C,N,Xn
Risk Statements: 11-34-48/20-51/53-62-65-67-38
Safety Statements: 16-26-36/37/39-45-61-62-36/37
RIDADR: UN 2924 3/PG 2
WGK Germany: 3
F: 1-10
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P308+P313IF exposed or concerned: Get medical advice/attention.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 253138
Product name: 9-BBN triflate solution
Purity: 0.5 M in hexanes
Packaging: 100ml
Price: $277
Updated: 2023/01/07

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9-BBN TRIFLATE Chemical Properties,Usage,Production

Uses

Reactant for:

Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
Mukaiyama aldol addition
Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
Preparation of palladium porphyrin complexes
Boron-mediated β-alkoxy Me ketone aldol addition reactions

Enolization agent

Application

9-Bbn triflate can be used to prepare Lewis acids of vinyloxyboranes and boryl nitrify salts; a catalyst for the coupling of silyl enol ethers and acetals; and a catalyst for the isomerization of epoxides to allyl alcohols.

Preparation

Equimolar amounts of 9-Borabicyclo[3.3.1]nonane and Trifluoromethanesulfonic Acid are mixed in hexane and stirred at 20 °C for 24 h after which time 9-BBN TRIFLATE is isolated by vacuum distillation.

reaction suitability

reagent type: reductant

storage

Use in a fume hood; the neat liquid as well as solutions are moisture and air sensitive; therefore the material should be stored and transferred under a dry inert atmosphere.

9-BBN TRIFLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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9-BBN TRIFLATE Suppliers

China 39 Switzerland 1 United States 3 Global 43

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Shanghai Scientia Pharmaceutical Technology Co., Ltd.

Tel: 21-21-54301573 13917723525
Fax: (86)21-51861981
Email: sales@scientiapharm.com
Country: China
ProdList: 263
Advantage: 62

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Hangzhou Yuhao Chemical Technology Co., Ltd

Tel: 0571-82693216
Fax: +86-571-82880190
Email: info@yuhaochemical.com
Country: China
ProdList: 9387
Advantage: 52

Shanghai Sphchem Co., Ltd.

Tel: 021-56491756 13512199871
Fax: 021-5649-1756
Email: 2819742715@qq.com
Country: China
ProdList: 4001
Advantage: 55

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

TIANJIN SPRING PHARMA SCIENCE CO., LTD.

Tel: 0086-22-60330256
Fax: 0086-22-60330256
Country: China
ProdList: 83
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

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View Lastest Price from 9-BBN TRIFLATE manufacturers

Career Henan Chemical Co

Product: 9-BBN TRIFLATE 62731-43-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 25kg
Release date: 2019-07-09

62731-43-5, 9-BBN TRIFLATERelated Search:

Potassium 9-(2,3-dimethyl-2-butoxy)-9-boratabicyclo[3.3.l]nonane LITHIUM 9-BBN HYDRIDE 9-(1,1,2-Trimethylpropoxy)-9-borabicyclo[3.3.1]nonane BETA-BENZYL-9-BBN 9-BROMO-9-BORABICYCLO[3.3.1]NONANE 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE 9-Borabicyclo[3.3.1]nonane 9-BBN TRIFLATE Trifluoromethanesulfonic acid DIBUTYLBORON TRIFLUOROMETHANESULFONATE

9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE

9-BBN TRIFLATE

9-bbn triflate solution

9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate

9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution

9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES

9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E

9-BBN triflate solution, 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution

9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in diethyl ether, AcroSeal

9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in hexanes, AcroSeal

9-BBN Triflate solution 0.5 M in hexanes

9-BBN·CF3SO3

9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane

9-Borabicyclononyl Trifluoromethanesulfonate

Methanesulfonic acid, 1,1,1-trifluoro-, anhydride with 9-hydroxy-9-borabicyclo[3.3.1]nonane

9-Borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate

62731-43-5

C9H14BF3O3S

Boranes

Synthetic Reagents

Reduction