ChemicalBook > CAS DataBase List > 9-BBN TRIFLATE

9-BBN TRIFLATE

Product Name
9-BBN TRIFLATE
CAS No.
62731-43-5
Chemical Name
9-BBN TRIFLATE
Synonyms
9-BBN·CF3SO3;9-BBN TRIFLATE;9-bbn triflate solution;9-BBN triflate solution 0.5M in THF;9-BBN Triflate solution 0.5 M in hexanes;9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES;9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E;9-Borabicyclononyl Trifluoromethanesulfonate;9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE;9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate
CBNumber
CB2303895
Molecular Formula
C9H14BF3O3S
Formula Weight
270.07
MOL File
62731-43-5.mol
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9-BBN TRIFLATE Property

Boiling point:
265.7±50.0 °C(Predicted)
Density 
0.733 g/mL at 25 °C
Flash point:
-22 °C
solubility 
sol common inert organic solvents such as Et2O, CH2Cl2, and hexane.
form 
liquid
BRN 
995656
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Safety

Hazard Codes 
F,C,N,Xn
Risk Statements 
11-34-48/20-51/53-62-65-67-38
Safety Statements 
16-26-36/37/39-45-61-62-36/37
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
1-10
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P308+P313IF exposed or concerned: Get medical advice/attention.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
253138
Product name
9-BBN triflate solution
Purity
0.5 M in hexanes
Packaging
100ml
Price
$277
Updated
2023/01/07
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9-BBN TRIFLATE Chemical Properties,Usage,Production

Uses

Reactant for:

  • Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
  • Mukaiyama aldol addition
  • Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
  • Preparation of palladium porphyrin complexes
  • Boron-mediated β-alkoxy Me ketone aldol addition reactions

  • Enolization agent

Application

9-Bbn triflate can be used to prepare Lewis acids of vinyloxyboranes and boryl nitrify salts; a catalyst for the coupling of silyl enol ethers and acetals; and a catalyst for the isomerization of epoxides to allyl alcohols.

Preparation

Equimolar amounts of 9-Borabicyclo[3.3.1]nonane and Trifluoromethanesulfonic Acid are mixed in hexane and stirred at 20 °C for 24 h after which time 9-BBN TRIFLATE is isolated by vacuum distillation.

reaction suitability

reagent type: reductant

storage

Use in a fume hood; the neat liquid as well as solutions are moisture and air  sensitive; therefore the material should be stored and transferred under a dry inert atmosphere.

9-BBN TRIFLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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9-BBN TRIFLATE Suppliers

J & K SCIENTIFIC LTD.
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View Lastest Price from 9-BBN TRIFLATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
9-bbn triflate 62731-43-5
Price
US $1.10-9.90/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kg
Release date
2025-08-18
Career Henan Chemical Co
Product
9-BBN TRIFLATE 62731-43-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
25kg
Release date
2019-07-09

62731-43-5, 9-BBN TRIFLATERelated Search:


  • 9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE
  • 9-BBN TRIFLATE
  • 9-bbn triflate solution
  • 9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate
  • 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution
  • 9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES
  • 9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E
  • 9-BBN triflate solution, 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution
  • 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in diethyl ether, AcroSeal
  • 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in hexanes, AcroSeal
  • 9-BBN Triflate solution 0.5 M in hexanes
  • 9-BBN·CF3SO3
  • 9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane
  • 9-Borabicyclononyl Trifluoromethanesulfonate
  • Methanesulfonic acid, 1,1,1-trifluoro-, anhydride with 9-hydroxy-9-borabicyclo[3.3.1]nonane
  • 9-Borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
  • 9-BBN triflate solution 0.5M in THF
  • 62731-43-5
  • C9H14BF3O3S
  • Boranes
  • Synthetic Reagents
  • Reduction