2-Methyl-3-nitroanisole

Product Name: 2-Methyl-3-nitroanisole
CAS No.: 4837-88-1
Chemical Name: 2-Methyl-3-nitroanisole
Synonyms: 2-Methyl-3-nit;BUTTPARK 52\11-31;2-METHYL-3-NITROANISOLE;3-nitro-2-methylanisole;2-Methy1-3-nitroanisole;2-METHOXY-6-NITROTOLUENE;6-METHOXY-2-NITROTOLUENE;Anisole, 2-methyl-3-nitro-;2-Methoxy-6-nitrotoluene>2-METHYL-3-NITROANISOLE, 98+%
CBNumber: CB2309796
Molecular Formula: C8H9NO3
Formula Weight: 167.16
MOL File: 4837-88-1.mol

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2-Methyl-3-nitroanisole Property

Melting point:: 54-56 °C (lit.)
Boiling point:: 94-96°C 0,5mm
Density: 1.180±0.06 g/cm3(Predicted)
Flash point:: >230 °F
storage temp.: Store at room temperature
solubility: soluble in Methanol
form: Powder or Crystalline Powder
color: Yellow to pale brown
BRN: 2328599
InChI: InChI=1S/C8H9NO3/c1-6-7(9(10)11)4-3-5-8(6)12-2/h3-5H,1-2H3
InChIKey: HQCZLEAGIOIIMC-UHFFFAOYSA-N
SMILES: C1(OC)=CC=CC([N+]([O-])=O)=C1C
CAS DataBase Reference: 4837-88-1(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-methoxy-2-methyl-3-nitro-(4837-88-1)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 22-36/37-36-26
RIDADR: 2811
WGK Germany: 3
Hazard Note: Harmful
PackingGroup: III
HS Code: 29093090
Storage Class: 11 - Combustible Solids
Hazard Classifications: Acute Tox. 4 Oral

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H301Toxic if swalloed

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P321Specific treatment (see … on this label).

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 115428
Product name: 2-Methyl-3-nitroanisole
Purity: 99%
Packaging: 10g
Price: $154.7
Updated: 2025/07/31

TCI Chemical

Product number: M1416
Product name: 2-Methoxy-6-nitrotoluene
Purity: >97.0%(GC)
Packaging: 5g
Price: $81
Updated: 2025/07/31

TCI Chemical

Product number: M1416
Product name: 2-Methoxy-6-nitrotoluene
Purity: >97.0%(GC)
Packaging: 25g
Price: $246
Updated: 2025/07/31

TRC

Product number: M339315
Product name: 2-Methyl-3-nitroanisole
Packaging: 100mg
Price: $75
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0021189
Product name: 2-METHYL-3-NITROANISOLE
Purity: 95.00%
Packaging: 1G
Price: $606.61
Updated: 2021/12/16

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2-Methyl-3-nitroanisole Chemical Properties,Usage,Production

Uses

2-Methyl-3-nitroanisole may be used in chemical synthesis studies.

Synthesis

A solution of dimethyl sulfoxide (80 mL) was added to a 500 mL three-necked vial at 25 ??. 29.7 g (0.32 mol) of methanol and 14 g (0.35 mol) of 60% sodium hydride were added slowly with stirring, the temperature was raised to 120 ??, and a solution of dimethyl sulfoxide containing 56.3 g (0.3 mol) of 2-methyl-3-nitrochlorobenzene was added dropwise. After dropwise reaction for 3 h. Decrease to 25 ??, add toluene (150 mL) and water (200 mL), partitioning, the aqueous layer was extracted with toluene (100 mL) twice, 50 mL each time, combined with the organic phase and washed with 5% aqueous sodium hydroxide (40 mL) once, partitioning. The organic layer was washed with water, the organic layer was dried with anhydrous sodium sulfate, filtered and evaporated. Get 2-methyl-3-nitro anisole.

Purification Methods

2-Methyl-5-nitroanisole crystallises from MeOH (yellow needles) and sublimes in vacuo. [Kuffner Monatsh Chem 91 1152 1960, Beilstein 6 I 178.]

2-Methyl-3-nitroanisole Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methyl-3-nitroanisole Suppliers

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View Lastest Price from 2-Methyl-3-nitroanisole manufacturers

PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD

Product: 2-Methyl-3-nitroanisole 4837-88-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 500 kgs
Release date: 2024-07-08

Henan Fengda Chemical Co., Ltd

Product: 2-methyl-3-nitroanisole 4837-88-1
Price: US $122.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-11

Henan Bao Enluo International TradeCo.，LTD

Product: 2-Methyl-3-nitroanisole 4837-88-1
Price: US $30.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 50000tons
Release date: 2023-08-15

4837-88-1, 2-Methyl-3-nitroanisoleRelated Search:

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BUTTPARK 52\11-31

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2-METHYL-3-NITROANISOLE, 98+%

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4837-88-1

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