ChemicalBook > CAS DataBase List > 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
Reactions- Product Name
- 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
- CAS No.
- 1660153-91-2
- Chemical Name
- 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
- Synonyms
- 2;2-(t-ButyL;98% (t-Bu)PhCPhos;phosphino)-2',6'-dimethyL;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl;2-Tert-butyl(phenyl)phosphine-2',6'-dimethylamine-1,1'-biphenyl;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl,98%;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98%;2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, (t-Bu)PhCPhos
- CBNumber
- CB23140277
- Molecular Formula
- C26H33N2P
- Formula Weight
- 404.53
- MOL File
- 1660153-91-2.mol
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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Property
- Melting point:
- 112 °C
- Boiling point:
- 537.6±50.0 °C(Predicted)
- pka
- 5.00±0.28(Predicted)
- form
- Powder
- color
- white to off-white
- InChI
- InChI=1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3
- InChIKey
- HTHOMNNVAUPLKK-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2P(C(C)(C)C)C2=CC=CC=C2)=C(N(C)C)C=CC=C1N(C)C
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H413May cause long lasting harmful effects to aquatic life
- Precautionary statements
-
P273Avoid release to the environment.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 900275
- Product name
- (t-Bu)PhCPhos
- Purity
- 95%
- Packaging
- 250mg
- Price
- $203
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 900275
- Product name
- (t-Bu)PhCPhos
- Purity
- 95%
- Packaging
- 1g
- Price
- $573
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-3010
- Product name
- 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
- Packaging
- 250mg
- Price
- $108
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-3010
- Product name
- 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
- Packaging
- 1g
- Price
- $323
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-3010
- Product name
- 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
- Packaging
- 5g
- Price
- $1293
- Updated
- 2024/03/01
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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Chemical Properties,Usage,Production
Reactions
Ligand for the Palladium-catalyzed Buchwald-Hartwig cross-coupling of hindered primary amines and aryl halides.
Uses
(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Preparation Products And Raw materials
Raw materials
Preparation Products
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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Suppliers
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View Lastest Price from 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- (t-Bu)PhCPhos 1660153-91-2
- Price
- US $0.00-0.00/g
- Min. Order
- 100g
- Purity
- 98%
- Supply Ability
- 15KG
- Release date
- 2024-05-06