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ChemicalBook > CAS DataBase List > 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine

2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine

Reactions
Product Name
2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
CAS No.
1660153-91-2
Chemical Name
2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
Synonyms
2;2-(t-ButyL;98% (t-Bu)PhCPhos;phosphino)-2',6'-dimethyL;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl;2-Tert-butyl(phenyl)phosphine-2',6'-dimethylamine-1,1'-biphenyl;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl,98%;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98%;2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl;2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, (t-Bu)PhCPhos
CBNumber
CB23140277
Molecular Formula
C26H33N2P
Formula Weight
404.53
MOL File
1660153-91-2.mol
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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Property

Melting point:
112 °C
Boiling point:
537.6±50.0 °C(Predicted)
pka
5.00±0.28(Predicted)
form 
Powder
color 
white to off-white
InChI
InChI=1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3
InChIKey
HTHOMNNVAUPLKK-UHFFFAOYSA-N
SMILES
C1(C2=CC=CC=C2P(C(C)(C)C)C2=CC=CC=C2)=C(N(C)C)C=CC=C1N(C)C
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
900275
Product name
(t-Bu)PhCPhos
Purity
95%
Packaging
250mg
Price
$203
Updated
2024/03/01
Sigma-Aldrich
Product number
900275
Product name
(t-Bu)PhCPhos
Purity
95%
Packaging
1g
Price
$573
Updated
2024/03/01
Strem Chemicals
Product number
15-3010
Product name
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
Packaging
250mg
Price
$108
Updated
2024/03/01
Strem Chemicals
Product number
15-3010
Product name
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
Packaging
1g
Price
$323
Updated
2024/03/01
Strem Chemicals
Product number
15-3010
Product name
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
Packaging
5g
Price
$1293
Updated
2024/03/01
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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Chemical Properties,Usage,Production

Reactions

Ligand for the Palladium-catalyzed Buchwald-Hartwig cross-coupling of hindered primary amines and aryl halides.

Uses

(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Preparation Products And Raw materials

Raw materials

Preparation Products

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2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
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View Lastest Price from 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
(t-Bu)PhCPhos 1660153-91-2
Price
US $0.00-0.00/g
Min. Order
100g
Purity
98%
Supply Ability
15KG
Release date
2024-05-06

1660153-91-2, 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamineRelated Search:


  • 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
  • 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
  • 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98%
  • 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, (t-Bu)PhCPhos
  • 2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl
  • 2-(t-ButyL
  • 98% (t-Bu)PhCPhos
  • phosphino)-2',6'-dimethyL
  • [1,1'-Biphenyl]-2,6-diamine, 2'-[(1,1-dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-
  • 2'-(tert-Butyl(phenyl)phosphino)-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
  • 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl,98%
  • 2-Tert-butyl(phenyl)phosphine-2',6'-dimethylamine-1,1'-biphenyl
  • 2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
  • 2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl
  • 2'-(tert-Butyl(phenyl)phosphino)-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine
  • 2
  • 1660153-91-2
  • C26H33N2P
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts