COBALTOCENE HEXAFLUOROPHOSPHATE

Product Name: COBALTOCENE HEXAFLUOROPHOSPHATE
CAS No.: 12427-42-8
Chemical Name: COBALTOCENE HEXAFLUOROPHOSPHATE
Synonyms: COBALTOCENE HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT(III);COBALTOCENIUM HEXAFLUOROPHOSPHATE;COBALTICINIUM HEXAFLUOROPHOSPHATE;Cobalticiniumhexafluorophosphate,98%;Cobaltocenium hexafluorophosphate,98%;cobaltocenium hexafluorophosphate(1-);Dicyclopentadienylcobalt hexafluorophosphate;BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE;Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate
CBNumber: CB2314446
Molecular Formula: C10H10CoF6P10*
Formula Weight: 334.08
MOL File: 12427-42-8.mol

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COBALTOCENE HEXAFLUOROPHOSPHATE Property

solubility: slightly sol. in Dimethylformamide
form: crystal
color: yellow

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
HS Code: 2931.90.9051

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 279811
Product name: Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate
Purity: 98%
Packaging: 1g
Price: $67.3
Updated: 2024/03/01

TCI Chemical

Product number: C1589
Product name: Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate
Purity: >96.0%(T)
Packaging: 1g
Price: $207
Updated: 2024/03/01

Strem Chemicals

Product number: 27-0410
Product name: Cobalticinium hexafluorophosphate, 98%
Packaging: 1g
Price: $76
Updated: 2024/03/01

Strem Chemicals

Product number: 27-0410
Product name: Cobalticinium hexafluorophosphate, 98%
Packaging: 5g
Price: $303
Updated: 2024/03/01

TRC

Product number: B424105
Product name: Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate
Packaging: 1g
Price: $45
Updated: 2021/12/16

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COBALTOCENE HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Chemical Properties

yellow powder

Uses

Uses:

Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
Reactant for modification of organometallic electrodes surfaces through cathodic reduction
Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers

Synthesis Reference(s)

[1](a) Gmelin, Handbuch der Anorganischen Chemie, 8th ed; Verlag Chemie: Weinheim, 1973; Supplement, Vol. 5, part 1. (b) Sheats, J. E. JOM Libr. 1979, 7, 461.

reaction suitability

core: cobalt
reagent type: catalyst

Synthesis

Cobaltocene hexafluorophosphate is readily synthesized from cobalt(II) salts + CpNa, followed by air + HPF6 or NH4PF6. Salts with a wide range of other counterions may be obtained similarly. The cobaltocenium ion^[1] may be precipitated from aqueous solution by a variety of large anions. In addition to PF6 -, convenient counterions include Br3 - and I3 -. The simple halides are hygroscopic, but may be obtained in anhydrous form by removal of water under vacuum.

Precautions

COBALTOCENE HEXAFLUOROPHOSPHATE is very stable; irritant.

COBALTOCENE HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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COBALTOCENE HEXAFLUOROPHOSPHATE Suppliers

Americas 1 Belgium 1 China 45 Europe 1 Germany 3 India 1 Japan 2 Switzerland 1 United Kingdom 3 United States 12 Global 70

Alfa Chemistry

Tel: 1-516-6625404
Fax: 1-516-927-0118
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Aladdin Scientific

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Advanced Synthesis Technologies

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Ereztech LLC

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United States Biological

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Strem Chemicals, Inc.

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Riedel-de Haen AG

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TCI America

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Ereztech LLC

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Anvia Chemicals, LLC

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HONEST JOY HOLDINGS LIMITED

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Cardinal Industries

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12427-42-8, COBALTOCENE HEXAFLUOROPHOSPHATERelated Search:

Sodium hexafluorophosphate Nickel Dicyclopentadiene Gold(III) chloride 2-Azido-1,3-diMethyliMidazoliniuM Hexafluorophosphate BIS(ETHYLCYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE PHOSPHORUS TRIFLUORIDE BIS(PENTAMETHYLCYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE BIS(CYCLOPENTADIENYL)COBALT Hexafluorophosphoric acid PHOSPHORUS PENTAFLUORIDE COBALTOCENE HEXAFLUOROPHOSPHATE

BIS(CYCLOPENTADIENYL)COBALT(III)

Cobalticiniumhexafluorophosphate,98%

Bis(cyclopentadienyl)cobalt (II) hexafluorophosphate

Cobaltocenium hexafluorophosphate,98%

Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate

Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate(1-)

Dicyclopentadienylcobalt hexafluorophosphate

Dicyclopentadienylcobalt(1+) hexafluorophosphate(1-)

COBALTICINIUM HEXAFLUOROPHOSPHATE

COBALTOCENE HEXAFLUOROPHOSPHATE

COBALTOCENIUM HEXAFLUOROPHOSPHATE

BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE

BIS(CYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE

cobaltocenium hexafluorophosphate(1-)

Bis(cyclopentadienyl)cobalt(III)Hexafluorophosphate&gt

COBALTOCENE HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH

12427-42-8

C10H10CoF6P10

C5H52CoPF6

C10H10CoF6P

C10H10CoPF6

Classes of Metal Compounds

Titanocene, etc.

Transition Metal Compounds

Co (Cobalt) Compounds

Metallocenes

Catalysis and Inorganic Chemistry

halometallate salts

Classes of Metal Compounds

Co (Cobalt) Compounds

Metallocenes

Titanocene, etc.

Transition Metal Compounds

Catalysis and Inorganic Chemistry

Chemical Synthesis

Cobalt