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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

Reaction
Product Name
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
CAS No.
27057-09-6
Chemical Name
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Synonyms
Bis(triphenylphosphino)(2-methylphenyl)chloronickel;Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II);BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99%;Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride;Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%;2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide
CBNumber
CB23151060
Molecular Formula
C43H39ClNiP2
Formula Weight
711.88
MOL File
27057-09-6.mol
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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Property

Melting point:
195-200°C
storage temp. 
2-8°C
form 
Powder
color 
yellow
CAS DataBase Reference
27057-09-6
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
794279
Product name
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Packaging
250mg
Price
$81.6
Updated
2024/03/01
Sigma-Aldrich
Product number
794279
Product name
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Packaging
1g
Price
$358
Updated
2024/03/01
Strem Chemicals
Product number
28-0096
Product name
Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%
Packaging
250mg
Price
$117
Updated
2024/03/01
Strem Chemicals
Product number
28-0096
Product name
Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%
Packaging
1g
Price
$352
Updated
2024/03/01
Arctom
Product number
AS591439
Product name
Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II)
Purity
98%
Packaging
1g
Price
$160
Updated
2021/12/16
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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Chemical Properties,Usage,Production

Reaction

  1. This complex is used as an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates.
  2. This nickel precatalyst is used for the polymerization of halothiophenes. 

Uses

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Suppliers

Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52925
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87

27057-09-6, Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)Related Search:


  • Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
  • BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99%
  • Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%
  • 2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide
  • Bis(triphenylphosphino)(2-methylphenyl)chloronickel
  • Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride
  • 27057-09-6
  • C43H37ClNiP2