ChemicalBook > CAS DataBase List > LITHIUM METHOXIDE

LITHIUM METHOXIDE

Preparation

Product Name: LITHIUM METHOXIDE
CAS No.: 865-34-9
Chemical Name: LITHIUM METHOXIDE
Synonyms: lithium methanolate;LITHIUMMETHOXID;LITHIUM METHYLATE;Methoxylithium;ithium methoxide;Lithium metoxide;LITHIUM METHOXIDE;methanol,lithiumsalt;0.1M Lithium methoxide;Lithiummethoxide;96.8%;
CBNumber: CB2315281
Molecular Formula: CH3LiO
Formula Weight: 37.97
MOL File: 865-34-9.mol

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LITHIUM METHOXIDE Property

Melting point:: 500°C
Boiling point:: 64.6 °C
Density: 0.85 g/mL at 20 °C
Flash point:: 52 °F
storage temp.: Flammables area
solubility: Soluble in methanol.
form: powder
color: White
Specific Gravity: 0.85
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Sensitive: Moisture Sensitive
BRN: 3552389
Stability:: Stable, but reacts violently with water. Highly flammable. Store under dry inert gas.
CAS DataBase Reference: 865-34-9(CAS DataBase Reference)
EPA Substance Registry System: Methanol, lithium salt (865-34-9)

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Safety

Hazard Codes: F,T,C
Risk Statements: 14-17-34-39/23/24/25-36/38-23/24/25-11
Safety Statements: 8-16-26-43-45-36/37/39-36/37
RIDADR: UN 3274 3/PG 2
WGK Germany: 3
F: 3-10-23
TSCA: Yes
HazardClass: 4.2
PackingGroup: II
HS Code: 29051990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H251Self-heating; may catch fire

H314Causes severe skin burns and eye damage

Precautionary statements

P235Keep cool.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 62562
Product name: Lithium methoxide solution
Purity: ~10% in methanol (T, ~2.2 M)
Packaging: 100mL
Price: $274
Updated: 2025/07/31

Sigma-Aldrich

Product number: 344370
Product name: Lithium methoxide
Purity: 98%
Packaging: 25g
Price: $86.5
Updated: 2025/07/31

Sigma-Aldrich

Product number: 344370
Product name: Lithium methoxide
Purity: 98%
Packaging: 100g
Price: $244
Updated: 2025/07/31

Strem Chemicals

Product number: 93-0335
Product name: Lithium methoxide, 10% in methanol
Packaging: 100g
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 93-0335
Product name: Lithium methoxide, 10% in methanol
Packaging: 500g
Price: $167
Updated: 2024/03/01

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LITHIUM METHOXIDE Chemical Properties,Usage,Production

Preparation

Lithium methoxide (3 cm3, 3mmol of 1.0M solution in methanol) was added to (11) (1.0 g, 2.8 mmol) in methanol (15 cm3) at 0 °C, with stirring, under an atmosphere of nitrogen. The mixture was stirred at room temperature for 67 h, then water (20 cm3) was added and the mixture extracted into dichloromethane (DCM). The DCM solution was dried (MgS04) and evaporated giving a solid ( 1.1 g) shown to consist of 4- methoxy-3,5-difluoro-2,6-dibromopyridine (22g) ( 19% ), 2,6-dibromo-4,5-dimethoxy-3- fluoropyridine (22h) (5%), (23b) (39% by comparison with authentic sample) and (23a) (36%). Neither column chromatography (eluting DCM and petrol 7: 3) nor preparative scale GLC ( 10% SE30, 140 oC) gave adequate separation of the products. However, a carbon nmr spectrum and GCMS of a mixture of (22g) and (23b) was obtained and the carbon spectra was assigned by comparison with that of (23b ).

Chemical Properties

Lithium Methoxide [865-34-9], LiOCH3, Mr 37.98, is a white solid that is soluble in methanol but virtually insoluble in aprotic organic solvents. It is commercially available as a 99 % fine crystalline solid and as 10 % solution in methanol. It can be used as base, especially as catalyst for transesterification reactions.

Uses

Lithium methoxide is used in sol-gel synthesis of lithium borophosphates. It is also useful for deprotonation reactions in organic synthesis. Further, it serves as a mild base in organic synthesis especially in transesterifications.

Uses

Employed in sol-gel synthesis of lithium borophosphates.

reaction suitability

core: lithium

Purification Methods

The most probable impurity is LiOH due to hydrolysis by moisture. It is important to keep the sample dry. It can be dried by keeping in a vacuum at 60-80o under dry N2 using an oil pump for a few hours. Store it under N2 in the cold. It should not have bands above 3000cm-1, IR has 1078, 2790, 2840 and 2930cm-1 in KBr. [Suebold J Org Chem 21 1561956, Beilstein 1 IV 1220, 1241.]

LITHIUM METHOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Cefbuperazone

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View Lastest Price from LITHIUM METHOXIDE manufacturers

BorayChem (Shanghai) New Materials Co., Ltd.

Product: Lithium Methoxide 865-34-9
Price: US $50.00/kg
Min. Order: 25kg
Purity: >99.5%
Supply Ability: 200 tons
Release date: 2025-09-09

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Lithium Methoxide 865-34-9
Price: US $79.00-38.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-11-27

Hebei Chuanghai Biotechnology Co., Ltd

Product: LITHIUM METHOXIDE 865-34-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-04

865-34-9, LITHIUM METHOXIDERelated Search:

LITHIUM SALICYLATE Lithium carbonate Lithium acetate Lithium benzoate Lithium acetoacetate LITHIUM CYCLOHEXANEBUTYRATE LITHIUM OXALATE LITHIUM ACETYLACETONATE LITHIUM PHENOXIDE Lithium stearate LITHIUM TRIFLUOROACETATE PYRUVIC ACID LITHIUM SALT LITHIUM METHOXIDE FORMALDEHYDE ETHYLENEDIAMINETETRAACETIC ACID DILITHIUM SALT Lithium BETA-HYDROXYPYRUVIC ACID LITHIUM SALT HYDRATE LITHIUM CITRATE, 99

LITHIUMMETHOXID

LITHIUM METHOXIDE

LITHIUM METHYLATE

Methanol, lithiuM salt (1:1)

LithiuM Methoxide solution ~10% in Methanol (T, ~2.2 M)

LithiuM Methoxide, 2.20 M solution in Methanol, SpcSeal

Lithium methoxide solution 1.0 M in methanol

LITHIUM METHOXIDE, 1.0M SOLUTION IN METH YL ALCOHOL

LITHIUM METHYLATE SOLUTION, ~4.6 % IN ME THANOL

LITHIUM METHYLATE SOLUTION, ~10% IN METH ANOL

Lithium methoxide, 10% in methanol

Lithiummethoxide;96.8%;

Lithium methoxide, pure, 99%

Lithium methoxide, 10% Solution in Methanol

methanol,lithiumsalt

Lithiummethoxide,min.95%

lithium methoxide solution

Lithium Methoxide pure 10% solution in Methanol

Lithium methoxide, 98+%

LITHIUM METHOXIDE (9-10% in methanol)

lithium methanolate

Lithium metoxide 10% in methanole

LITHIUM METHOXIDE, 2.25M in methanol (9-10 wt %)

ithium methoxide

Lithium methoxide, min. 95%

Lithium methoxide10% solution in methanolAcroSeal§3pure

Methoxylithium

Lithium methoxide, 99%, pure

Lithium methoxide, 10% solution in methanol, pure

Lithium methoxide,pure,2.2M (10 wt%) solutionin methanol

Lithium methoxide, 2.2M (10 wt%) solution in methanol, AcroSeal, pure

LithiuM Methoxide, pure, 2.2M (10 wt%) solution in Methanol, AcroSeal

LithiuM Methoxide, 2.2 M solution in MeOH, J&KSeal

LithiuM Methoxide, 2.2 M solution in MeOH

LITHIUM METHOXIDE, 2.25M in Methanol (9-10 wgt %)

Lithium metoxide

LITHIUM METHOXIDE ISO 9001：2015 REACH

LITHIUMMETHOXIDE 11.0% IN METHANOL

Lithium methoxide 1m in methanol

865-34-9 LITHIUM METHOXIDE

lithium(1+) methanolate

cadmium(2+),dithiocyanate

Lithium methoxide (6CI, 7CI)

Lithiummethoxide 1. M in THF

Lithium methanol solution

LITHIUM METHOXIDE(2.2Minhexane)

Lithium Methoxide Solution in Methanol, 10%

Lithium Methoxide (1.0 M in THF)

0.1M Lithium methoxide

lithium(1+) ion methanolate

865-34-9

71977-96-2

CH4OLi

CH3LiO

LiOCH3

CH3OLi

Organic Bases

Synthetic Reagents