ChemicalBook > CAS DataBase List > (S)-Equol

(S)-Equol

Product Name
(S)-Equol
CAS No.
531-95-3
Chemical Name
(S)-Equol
Synonyms
Equol;(S)-EQUOL;R,S-EQUOL;S,R-equol;(3S)-Equol;(-)-(S)-EQUOL;Equol USP/EP/BP;S-Equol S Equol;EQUOL, (+/-)-(SH);(S)-Equol,99%e.e.
CBNumber
CB2317528
Molecular Formula
C15H14O3
Formula Weight
242.27
MOL File
531-95-3.mol
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(S)-Equol Property

Melting point:
189-190°C
alpha 
D -21.5°
Boiling point:
312.25°C (rough estimate)
Density 
1.1914 (rough estimate)
refractive index 
1.5557 (estimate)
storage temp. 
Inert atmosphere,2-8°C
solubility 
DMSO (Soluble), Ethanol (Slightly), Methanol (Slightly)
pka
9.94±0.40(Predicted)
form 
Solid
color 
White to Pale Yellow
InChI
InChI=1S/C15H14O3/c16-13-4-1-10(2-5-13)12-7-11-3-6-14(17)8-15(11)18-9-12/h1-6,8,12,16-17H,7,9H2/t12-/m1/s1
InChIKey
ADFCQWZHKCXPAJ-GFCCVEGCSA-N
SMILES
C1OC2=CC(O)=CC=C2C[C@H]1C1=CC=C(O)C=C1
CAS DataBase Reference
531-95-3(CAS DataBase Reference)
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Safety

WGK Germany 
3
3-10
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Cayman Chemical
Product number
10010173
Product name
(S)-Equol
Purity
≥98%
Packaging
1mg
Price
$21
Updated
2024/03/01
Cayman Chemical
Product number
10010173
Product name
(S)-Equol
Purity
≥98%
Packaging
5mg
Price
$89
Updated
2024/03/01
Cayman Chemical
Product number
10010173
Product name
(S)-Equol
Purity
≥98%
Packaging
10mg
Price
$157
Updated
2024/03/01
Cayman Chemical
Product number
10010173
Product name
(S)-Equol
Purity
≥98%
Packaging
25mg
Price
$341
Updated
2024/03/01
Tocris
Product number
6158
Product name
(S)-Equol
Purity
≥98%(HPLC)
Packaging
10
Price
$122
Updated
2021/12/16
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(S)-Equol Chemical Properties,Usage,Production

Description

S-equol is a metabolite of dietary soy isoflavone daidzein by gut microbiome and possesses the most anti-atherogenic properties among all isoflavones.

Chemical Properties

White to Off-White Solid

Uses

Receptor; binding activity

Uses

A human urinary metabolite of Daidzein. It is also a natural estrogenic metabolite from soy isoflavones

Uses

(S)-Equol and R-Equol are metabolites of the soy isoflavones Daidzein (D103500) and Genistein. Both have significant biological actions.

Definition

ChEBI: Equol is a member of hydroxyisoflavans.

benefits

S-equol(EQUOL) is a selective estrogen receptor β (ERβ) agonist with lower binding activity for ERα, the predominant estrogen receptor in the breast and uterus. ERβ is highly expressed in hippocampal neurons . The hippocampus plays a major role in the brain for memory and spatial orientation. Thus, a selective ERβ agonist, such as S-equol, could offer a safe therapeutic or dietary supplement for cognitive improvement.

Biological Activity

(S)-Equol is an isoflavan produced by intestinal bacteria in response to soy isoflavone intake in human. it shows a wide range of activities including antioxidant activity, anti-inflammation activity and anticancer activity. it is reported that equol specifically binds to 5α-dht and has a modest affinity for recombinant estrogen receptor erβ, which may be responsible for most of equol’s biological properties. [1]

Side effects

(S)-Equol(EQUOL) can cause some mild side effects such as constipation and bloating.

Synthesis

3722-56-3

531-95-3

Dimethoxybenzodihydropyran (S)-23 (18 g, 66.7 mmol) was dissolved in pyridine hydrochloride (192 g, 148 mL, 1.67 mol), and the reaction mixture was heated at 150 °C overnight and then cooled to room temperature. The reaction solution was neutralized with excess aqueous NaHCO3 and subsequently extracted with dichloromethane (3 x 100 mL). The organic phases were combined and the crude product was purified by column chromatography (eluent: hexane/diethyl ether mixed solvent) to afford (S)-3-(4-hydroxyphenyl)benzodihydropyran-7-ol as a white solid in 88% yield (14.2 g, 58.7 mmol). The product characterization data were as follows: [α]25D = -19.5 (c = 1.05, MeOH), literature value [α]25D = -13 (c = 0.21, ethanol); 1H NMR (400 MHz, CD3OD) δ 7.09 (d, J = 8.5 Hz, 2H), 6.88 (d, J = 8.2 Hz, 1H), 6.76 (d, J = 8.5 Hz, 2H), 6.33 (dd, J = 8.2, 2.5 Hz, 1H), 6.25 (d, J = 2.5 Hz, 1H), 4.20 (tdd, J = 10.5, 3.6, 1.8 Hz, 1H), 3.91 (t, J = 10.5 Hz, 1H), 3.05 (tdd, J = 10.2, 6.0, 3.6 Hz, 1H). 2.93-2.77 (m, 2H); 13C NMR (100 MHz, CD3OD) δ 157.6, 157.3, 156.3, 133.8, 131.2, 129.3 (2C), 116.4 (2C), 114.6, 109.1, 103.8, 72.2, 39.4, 33.0.

Physiological effects

(S)-Equol is a selective estrogen receptor β (ERβ) agonist with lower binding activity for ERα, the predominant estrogen receptor in the breast and uterus. ERβ is highly expressed in hippocampal neurons.

in vitro

in vitro studies were conducted to measure both the binding affinity of equol for 5alpha-dihydrotestosterone (5alpha-dht) and the effects of equol treatment in human prostate cancer (lncap) cells. it was found that equol bound to 5alpha-dht with maximum and half maxim concentrations of 100 nm and 4.8 nm, respectively. in addition, equol significantly offset the increases in psa levels from lncap cells. [1]

in vivo

an in vivo study was performed to investigate effects of equol on rat prostate weight and circulating levels of sex steroid hormones. 1.0 mg/kg of equol was injected to long-evans rats fed with a low isoflavone diet for 25 days. findings from this study suggested that equol significantly decreased rat prostate weights and down-regulated serum levels of 5alpha-dht. however, this agent did not alter levels of lh, testosterone and estradiol. [1]

References

[1]lund td, blake c, bu l, hamaker an, lephart ed. iequol an isoflavonoid: potential for improved prostate health, in vitro and in vivo evidence. reprod biol endocrin. 2011; 9(4): doi: 10.1186/1477-7827-9-4.
[2]setchell dr and clerici c. equol: pharmacokinetics and biological actions. j nutr. 2010 jul; 140(7): 1363s–8s.

(S)-Equol Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-Equol Suppliers

Nanjing EnMing Pharmaceutical Technology Co., Ltd.
Tel
025-58894663 13305188663
Fax
025-58894661
Email
njempt@163.com
Country
China
ProdList
16
Advantage
58
Kono Chem Co., Ltd
Tel
029-86107037-8014 18292830413
Email
info@konochemical.com
Country
China
ProdList
473
Advantage
58
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7471
Advantage
65
Wuxi Jingyao Bio-Technology Co., Ltd.
Tel
0510-88770633 13961738808
Email
jingyaobiotech@126.com
Country
China
ProdList
346
Advantage
55
Bonerge(Hunan) Lifescience Co., Ltd.
Tel
0731 82791134 17673648049
Email
Alav.w@bonerge.com
Country
China
ProdList
10
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
Chembest Research Laboratories Limited
Tel
+86-21-20908456
Fax
021-58180499
Email
sales@BioChemBest.com
Country
China
ProdList
6003
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
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View Lastest Price from (S)-Equol manufacturers

Changsha Staherb Natural Ingredients Co., Ltd.
Product
Equol; Soybean extract 531-95-3
Price
US $0.00/KG
Min. Order
1KG
Purity
>99% HPLC
Supply Ability
1000KG
Release date
2022-09-16
Sinoway Industrial co., ltd.
Product
Equol 531-95-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20tons
Release date
2024-07-16
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Equol 531-95-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-06-03

531-95-3, (S)-EquolRelated Search:


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  • Food Residue Analysis
  • Analytical Standards
  • Analytical Chromatography Product Catalog
  • Food & Beverage Standards
  • Chromatography
  • Inhibitors
  • Iso-Flavones
  • Chiral Reagents
  • Heterocycles
  • Metabolites & Impurities
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