ChemicalBook > CAS DataBase List > (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)

(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)

Product Name
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
CAS No.
132098-59-0
Chemical Name
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
Synonyms
SF140057;2,2'-METHYLENEBIS[(4S)-4-PHENYL-2-OXAZOLINE];(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE);(S,S)-2,2'-methyleneBis(4-phenyl-2-oxazoline);4(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE);Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane;Bis((4S)-4,5-dihydro-4-phenyloxazol-2-yl)methane;(S,S)-2,2''-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) 97+%;2,2'-Methylenebis[(4S)-4-phenyl-4,5-dihydro-2-oxazole];(4S,4'S)-2,2'-methylenebis[4,5-dihydro-4-phenyl-Oxazole
CBNumber
CB2324005
Molecular Formula
C19H18N2O2
Formula Weight
306.36
MOL File
132098-59-0.mol
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(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Property

Boiling point:
131-134 °C0.01 mm Hg(lit.)
Density 
1.28 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.587
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
4.54±0.70(Predicted)
optical activity
[α]20/D ~ 90°, c = 1 in ethanol
BRN 
4202633
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
416428
Product name
2,2′-Methylenebis[(4S)-4-phenyl-2-oxazoline]
Purity
97%
Packaging
250mg
Price
$84
Updated
2024/03/01
Sigma-Aldrich
Product number
416428
Product name
2,2′-Methylenebis[(4S)-4-phenyl-2-oxazoline]
Purity
97%
Packaging
1g
Price
$432
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0005185
Product name
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
Purity
95.00%
Packaging
250MG
Price
$644.57
Updated
2021/12/16
Ambeed
Product number
A681147
Product name
Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane
Purity
97%99%ee
Packaging
50mg
Price
$55
Updated
2021/12/16
Ambeed
Product number
A681147
Product name
Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane
Purity
97%99%ee
Packaging
100mg
Price
$85
Updated
2021/12/16
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(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Chemical Properties,Usage,Production

Uses

C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Suppliers

China 48 France 1 Germany 1 Switzerland 2 United States 4 Global 56

132098-59-0, (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)Related Search:

2,2'-METHYLENEBIS[(4R,5S)-4,5-DIPHENYL-2-OXAZOLINE] Bis((S)-4-isobutyl-4,5-dihydrooxazol-2-yl)methane 2,2'-methylenebis[(4S)-4-tert-butyl-2-oxazoline] (4R,4'R)-2,2'-methylenebis[4,5-dihydro-4-(phenylmethyl)-Oxazole Oxazole, 2,2'-methylenebis[4,5-dihydro-4-methyl-, (4S,4'S)- (4S,4'S,5R,5'R)-2,2'-methylenebis[4,5-dihydro-4,5-diphenyl-Oxazole Bis((6-bromopyridin-3-yl)methyl)amine INDEX NAME NOT YET ASSIGNED (4S,4'S)-2,2'-methylenebis[4,5-dihydro-4-(phenylmethyl)-Oxazole (S,S)-2,2'-METHYLENEBIS(4-TERT-BUTYL-2-OXAZOLINE) (R,R)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) 2-[1-METHYL-1-(4-PHENYL-4,5-DIHYDRO-1,3-OXAZOL-2-YL)ETHYL]-4-PHENYL-4,5-DIHYDRO-1,3-OXAZOLE (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] 4-PHENYL-2-[(4-PHENYL-4,5-DIHYDRO-1,3-OXAZOL-2-YL)METHYL]-4,5-DIHYDRO-1,3-OXAZOLE

  • 2,2'-METHYLENEBIS[(4S)-4-PHENYL-2-OXAZOLINE]
  • (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
  • (S,S)-2,2''-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) 97+%
  • 4(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
  • 2,2'-Methylenebis[(4S)-4-phenyl-4,5-dihydro-2-oxazole]
  • Bis((4S)-4,5-dihydro-4-phenyloxazol-2-yl)methane
  • 2,2′-Methylenebis[(4S)-4-phenyl-2-oxazoline],(S,S)-2,2′-Methylenebis(4-phenyl-2-oxazoline)
  • Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane
  • (4S,4'S)-2,2'-methylenebis[4,5-dihydro-4-phenyl-Oxazole
  • SF140057
  • Oxazole, 2,2'-methylenebis[4,5-dihydro-4-phenyl-, (4S,4'S)-
  • (S,S)-2,2'-methyleneBis(4-phenyl-2-oxazoline)
  • 132098-59-0
  • Privileged Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • BOX
  • Chiral Reagent