ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE

Product Name: ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE
CAS No.: 1564-49-4
Chemical Name: ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE
Synonyms: AKOS 92999;ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE;Ethyl 1-Methyl-5-nitro-1H-iMidazole-2-carboxylate;ethyl 1-methyl-5-nitro-imidazole-2-carboxylate - [E83254];1H-Imidazole-2-carboxylic acid, 1-methyl-5-nitro-, ethyl ester
CBNumber: CB2325330
Molecular Formula: C7H9N3O4
Formula Weight: 199.16
MOL File: Mol file

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ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE Property

Melting point:: 81-83°C
Boiling point:: 350.7±34.0 °C(Predicted)
Density: 1.42±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
pka: -0.95±0.25(Predicted)
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: E946000
Product name: Ethyl1-methyl-5-nitro-1H-imidazole-2-carboxylate
Packaging: 100mg
Price: $265
Updated: 2021/12/16

AK Scientific

Product number: 7841AA
Product name: Ethyl1-methyl-5-nitro-1H-imidazole-2-carboxylate
Packaging: 1g
Price: $485
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0303033
Product name: ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE
Purity: 95.00%
Packaging: 5MG
Price: $501.01
Updated: 2021/12/16

Chemenu

Product number: CM122459
Product name: ethyl1-methyl-5-nitro-1H-imidazole-2-carboxylate
Purity: 95+%
Packaging: 1g
Price: $546
Updated: 2021/12/16

Chemenu

Product number: CM122459
Product name: ethyl1-methyl-5-nitro-1H-imidazole-2-carboxylate
Purity: 95+%
Packaging: 5g
Price: $1547
Updated: 2021/12/16

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ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

30148-21-1

1564-49-4

Step 6a. ethyl 1-methyl-1H-imidazole-2-carboxylate (2.0 g, 13 mmol) was dissolved in 8 mL of concentrated H2SO4, followed by the slow addition of 8 mL of concentrated HNO3. The reaction mixture was stirred at 70 °C for 3 h. The reaction mixture was then extracted with dichloromethane (DCM). After completion of the reaction, the solution was diluted with H2O and the pH was adjusted to 7-8 with aqueous Na2CO3. The reaction mixture was extracted with dichloromethane (DCM) and the organic layers were combined and concentrated. Purification by silica gel column chromatography (eluent: ethyl acetate/petroleum ether) afforded the target compound 1-methyl-5-nitro-1H-imidazole-2-carboxylic acid ethyl ester as a yellow solid (0.9 g, 34.7% yield).ESI-MS m/z = 200.20 [M + H]+.

References

[1] Patent: WO2016/183266, 2016, A1. Location in patent: Page/Page column 50

ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE Suppliers

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1564-49-4, ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATERelated Search:

ETHYL 1-METHYL-5-NITROIMIDAZOLE-2-CARBOXYLATE

AKOS 92999

Ethyl 1-Methyl-5-nitro-1H-iMidazole-2-carboxylate

1H-Imidazole-2-carboxylic acid, 1-methyl-5-nitro-, ethyl ester

ethyl 1-methyl-5-nitro-imidazole-2-carboxylate - [E83254]

1564-49-4