ChemicalBook > CAS DataBase List > 5-IODO-2-METHOXYTOLUENE

5-IODO-2-METHOXYTOLUENE

Product Name
5-IODO-2-METHOXYTOLUENE
CAS No.
75581-11-2
Chemical Name
5-IODO-2-METHOXYTOLUENE
Synonyms
5-IODO-2-METHYLANISOLE;4-IODO-2-METHYLANISOLE;5-IODO-2-METHOXYTOLUENE;4-Iodo-1-Methoxy-2-Methylbenzene;Benzene, 4-iodo-1-methoxy-2-methyl-
CBNumber
CB2370299
Molecular Formula
C8H9IO
Formula Weight
248.06
MOL File
75581-11-2.mol
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5-IODO-2-METHOXYTOLUENE Property

Melting point:
75-76 °C(Solv: acetic acid (64-19-7))
Boiling point:
247.7±28.0 °C(Predicted)
Density 
1.634±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
Appearance
Off-white to gray Solid
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Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
I737063
Product name
4-Iodo-2-methylanisole
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
I737063
Product name
4-Iodo-2-methylanisole
Packaging
500mg
Price
$75
Updated
2021/12/16
Activate Scientific
Product number
AS145178
Product name
5-Iodo-2-methylanisole
Purity
98%
Packaging
250mg
Price
$140
Updated
2021/12/16
Matrix Scientific
Product number
007383
Product name
4-Iodo-2-methylanisole
Purity
97%
Packaging
25g
Price
$205
Updated
2021/12/16
Activate Scientific
Product number
AS145178
Product name
5-Iodo-2-methylanisole
Purity
98%
Packaging
1g
Price
$269
Updated
2021/12/16
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5-IODO-2-METHOXYTOLUENE Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 4081, 1996 DOI: 10.1016/0040-4039(96)00738-1

Synthesis

578-58-5

75581-11-2

The general procedure for the synthesis of 4-iodo-2-methylanisole from 2-methylanisole is as follows: to a stirred solution of 2-methylanisole (1 mmol) in dichloromethane (CH2Cl2) or 1,2-dichloroethane ((CH2Cl)2) (0.1 M), triphenylphosphorane-gold bis(trifluoromethylsulfonyl)imide (Ph3PAuNTf2) (0.025 mmol , 19 mg; if toluene-coordinated Ph3PAuNTf2 complex was used, the ratio was 2:1), followed by the addition of N-iodosuccinimide (NIS) (1.1 mmol, 248 mg). The reaction mixture was stirred at room temperature or reacted under reflux conditions until complete conversion of the feedstock was confirmed by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was evaporated under reduced pressure and the resulting crude product was purified by fast column chromatography using different ratios of hexane and ethyl acetate (EtOAc) as eluents to finally obtain pure 4-iodo-2-methylanisole.

References

[1] Synthetic Communications, 2003, vol. 33, # 8, p. 1319 - 1323
[2] Chemistry Letters, 1988, # 5, p. 795 - 798
[3] Synlett, 2014, vol. 25, # 3, p. 399 - 402
[4] Tetrahedron Letters, 1996, vol. 37, # 23, p. 4081 - 4084
[5] Journal of Organic Chemistry, 2006, vol. 71, # 11, p. 4349 - 4352

5-IODO-2-METHOXYTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 5-IODO-2-METHOXYTOLUENE manufacturers

Career Henan Chemical Co
Product
5-IODO-2-METHOXYTOLUENE 75581-11-2
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

75581-11-2, 5-IODO-2-METHOXYTOLUENERelated Search:

clioxanide ROSE BENGAL 5-IODO-2,3-DIHYDROBENZO[B]FURAN ERYTHROSIN B ROSE BENGAL ERYTHROSIN B 5-AMINOERYTHROSIN ERYTHROSIN B ISOTHIOCYANATE, ISOMER II BENZAMIDE, N-[(1-ETHYL-2-PYRROLIDINYL)METHYL]-2-HYDROXY-3-IODO-6-METHOXY- ETHYL 6-IODO-4-OXO-4H-CHROMENE-2-CARBOXYLATE ROSE BENGAL LACTONE epidepride TRIIODOFLUORESCEIN 3-IODO-4-METHOXYTOLUENE 4-IODO-2-METHOXYTOLUENE Hydroxy[(3',6'-dihydroxy-2',7'-diiodospiro[3H-2,1-benzoxathiole-3,9'-[9H]xanthene]-1,1-dioxide)-4'-yl]mercury(II) salt METHYL 5-IODO-2-[(4-METHYLBENZOYL)OXY]BENZENECARBOXYLATE 2,3-DIMETHOXY-5-IODOBENZALDEHYDE

  • 5-IODO-2-METHOXYTOLUENE
  • 4-IODO-2-METHYLANISOLE
  • 5-IODO-2-METHYLANISOLE
  • 4-Iodo-1-Methoxy-2-Methylbenzene
  • Benzene, 4-iodo-1-methoxy-2-methyl-
  • 75581-11-2
  • C8H9OI
  • Aromatic Ethers
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Iodine Compounds