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5-METHYLBENZOXAZOLE

Product Name
5-METHYLBENZOXAZOLE
CAS No.
10531-78-9
Chemical Name
5-METHYLBENZOXAZOLE
Synonyms
5-METHYLBENZOXAZOLE;5-Methyl-benzooxazole;Benzoxazole, 5-methyl-;5-Methylbenzoxazole>5-Methylbenzoxazole 97%;5-Methylbenzo[d]oxazole;5-METHYL-1,3-BENZOXAZOLE;5-Methylbenzoxazole, 99.5+%
CBNumber
CB2397300
Molecular Formula
C8H7NO
Formula Weight
133.15
MOL File
10531-78-9.mol
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5-METHYLBENZOXAZOLE Property

Melting point:
41-44 °C
Boiling point:
96 °C / 15mmHg
Density 
1.1475 (rough estimate)
refractive index 
1.5320 (estimate)
Flash point:
87℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
pka
2.66±0.10(Predicted)
color 
White to Green to Brown
CAS DataBase Reference
10531-78-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,C,Xn
Risk Statements 
36/37/38-37/38-36-34-20/21/22-41-22
Safety Statements 
37/39-26-45-36/37/39-27-39-36
WGK Germany 
1
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
722243
Product name
5-Methylbenzoxazole
Purity
97%
Packaging
25g
Price
$64.4
Updated
2025/07/31
TCI Chemical
Product number
M1688
Product name
5-Methylbenzoxazole
Purity
>98.0%(GC)
Packaging
5g
Price
$165
Updated
2025/07/31
TCI Chemical
Product number
M1688
Product name
5-Methylbenzoxazole
Purity
>98.0%(GC)
Packaging
25g
Price
$657
Updated
2025/07/31
TRC
Product number
M332050
Product name
5-Methylbenzoxazole
Packaging
100mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
J96986
Product name
5-Methylbenzo[d]oxazole
Packaging
1g
Price
$13
Updated
2021/12/16
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5-METHYLBENZOXAZOLE Chemical Properties,Usage,Production

Chemical Properties

YELLOW TO BROWN CRYSTALLINE SOLID

Synthesis

122-51-0

95-84-1

10531-78-9

GENERAL METHOD: Triethyl orthoformate (1.1 mmol) and o-amino-p-toluol (1 mmol) were mixed and p-toluenesulfonic acid (TSA, 1 mol%) was added as a catalyst. The reaction mixture was stirred at 80-90 °C for an appropriate time depending on the course of the reaction (cf. Table 4). After completion of the reaction (monitored by TLC), the reaction mixture was diluted with chloroform (10 mL) and the catalyst was removed by filtration. The final product 5-methylbenzazole was purified by column chromatography.

References

[1] Monatshefte fur Chemie, 2011, vol. 142, # 1, p. 87 - 91
[2] Combinatorial Chemistry and High Throughput Screening, 2013, vol. 16, # 8, p. 618 - 627
[3] Chemical Communications, 2014, vol. 50, # 73, p. 10661 - 10664
[4] Monatshefte fur Chemie, 2007, vol. 138, # 7, p. 663 - 667
[5] Comptes Rendus Chimie, 2013, vol. 16, # 11, p. 1029 - 1034

5-METHYLBENZOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-METHYLBENZOXAZOLE Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from 5-METHYLBENZOXAZOLE manufacturers

Honest Joy Holdings Limited
Product
5-Methylbenzoxazole 10531-78-9
Price
US $0.00/KG
Min. Order
1KG
Purity
97.5%
Supply Ability
100 tons
Release date
2022-01-14
Career Henan Chemical Co
Product
5-METHYLBENZOXAZOLE 10531-78-9
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08