Cinmethylin

Product Name: Cinmethylin
CAS No.: 87818-31-3
Chemical Name: Cinmethylin
Synonyms: cinch;argold;SKH 301;sd95481;WL 95481;CINMETHYLIN;exo-(+-)-xy);(2.2.1)heptane;Caswell No. 731G;Cinmethylin [iso]
CBNumber: CB2407074
Molecular Formula: C18H26O2
Formula Weight: 274.4
MOL File: 87818-31-3.mol

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Cinmethylin Property

Melting point:: 25°C
Boiling point:: 313°C
Density: d20 1015 kg/m3
refractive index: 1.4800 (estimate)
Flash point:: 147 °C
storage temp.: 0-6°C
CAS DataBase Reference: 87818-31-3(CAS DataBase Reference)
EPA Substance Registry System: Cinmethylin (87818-31-3)

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Safety

Hazard Codes: Xn,N
Risk Statements: 20-51/53
Safety Statements: 23-61-22
RIDADR: UN3082 9/PG 3
WGK Germany: 3
RTECS: RN8762000
HS Code: 29321900
Toxicity: LD50 orally in rats: 4.5 g/kg; LD50 dermally in rabbits: >2 g/kg (Lee)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H332Harmful if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 34237
Product name: Cinmethylin
Purity: mixture of isomers
Packaging: 50mg
Price: $240
Updated: 2024/03/01

TRC

Product number: C475400
Product name: Cinmethylin
Packaging: 500mg
Price: $1320
Updated: 2021/12/16

AK Scientific

Product number: O991
Product name: Cinmethylin
Packaging: 50mg
Price: $292
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC20446
Product name: Cinmethylin
Packaging: 50mg
Price: $300
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC20446
Product name: Cinmethylin
Packaging: 5mg
Price: $65
Updated: 2021/12/16

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Cinmethylin Chemical Properties,Usage,Production

Description

Cinmethylinwas developed by Shell Chemical Company in the early 1980s as a weed control agent for monocotyledonous species. This herbicide controls important grasses such as green foxtail (Setaria viridis) and barnyardgrass (Echinochloa crus-galli) and suppresses the growth of several broadleaf weeds such as prickly sida (Sida spinosa) and velvetleaf (Abutilon theophrasti).

Uses

Cinmethylin is used as pre-emergence grass herbicide. Cinmethylin is member of the cineole eucalyptol family.

Definition

ChEBI: Exo-(+)-cinmethylin is a 1-methyl-2-[(2-methylbenzyl)oxy]-4-(propan-2-yl)-7-oxabicyclo[2.2.1]heptane that is the exo-(+)-isomer of cinmethylin. It is an enantiomer of an exo-(-)-cinmethylin.

Pharmacology

Cinmethylin is active on several important grasses in rice (Echinochloa spp., Cyperus spp., and Monochoria vaginalis) at rates from 25 to 100 g ai/ha (5). Its chemical and toxicological features (low persistence in environment and low mammalian toxicity) generated a significant level of interest in its use as a rice herbicide.

Metabolic pathway

When rats are administered 14C-cinmethylin orally, the major route of its elimination is via urinary excretion. A complex degradation pattern of cinmethylin is observed and the metabolic pathways involve hydroxylation, oxidation at the benzyl and cineol portions, conjugation with glucuronic acid and glycine, and cleavage of the ether linkage. When rats are administered 14C-cinmethylin by stomach incubation, two minor metabolites are identified as o- (acetoxymethyl)benzoic acid and 9-(acetoxymethyl)-a- carboxycinmethylin.

Cinmethylin Preparation Products And Raw materials

Raw materials

Tert-butyric acid Sodium acetate p-Toluenesulfonic acid Nitrogen 1,8-Cineole 1-Heptyne tert-Butyl hydroperoxide Terpin ETHYLENE GLYCOL Double ring 1,3-Diaminopropane Glutaric acid Lithium

Preparation Products

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Cinmethylin Suppliers

Canada 1 China 65 Europe 1 Germany 2 India 2 Japan 3 Switzerland 1 United Kingdom 2 United States 11 Global 88

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
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Chemsky (shanghai) International Co.,Ltd

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 15421
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BEST-REAGENT

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Nanjing Sunlida Biological Technology Co., Ltd.

Tel: 025-57798810
Fax: 025-57019371
Email: sales@sunlidabio.com
Country: China
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TianJin Alta Scientific Co., Ltd.

Tel: 022-65378550-8551
Fax: +86-022-2532-9655
Email: contact@altascientific.com
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Suzhou Lakestar Pharmatech Co., Ltd.

Tel: 0512-63970158-603 18018108880
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Alta Scientific Co., Ltd.

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Fax: 022-2532-9655
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Chengdu RunZeBenTu Chemical Co., Ltd

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Shanghai Xilong Biochemical Technology Co., Ltd.

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Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20810
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View Lastest Price from Cinmethylin manufacturers

Hebei Duling International Trade Co. LTD

Product: Cinmethylin 87818-31-3
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100 tons
Release date: 2023-05-24

Hebei Fengqiang Trading Co., LTD

Product: Cinmethylin 87818-31-3
Price: US $100.00/bag
Min. Order: 1bag
Purity: 99
Supply Ability: 5000
Release date: 2023-08-25

87818-31-3, CinmethylinRelated Search:

4-Methoxyphenylacetone Methoxydiethylborane CYCLOHEPTANE Basic Violet 1 Methyl acrylate Kresoxim-methyl p-(2-Methoxyethyl) phenol 2-Methoxyethanol Acetonitrile Methylparaben Chlorodimethylphenylsilane Methanol Methyl 2-Butanone 2,2,5,5-TETRAMETHYLTETRAHYDROFURAN 1,4-Cineole Cinmethylin Methoxy

1-Methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-7-oxabicyclo[2.2.1]heptane

(+-)-exo-1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-7-oxabicyclo

(2.2.1)heptane

1-methyl-4-(1-methylethyl)-2-[(2-methylphenyl)methoxy]-exo-(±)-7-Oxabicyclo[2.2.1]heptane

7-oxabicyclo(2.2.1)heptane,1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)metho

exo-(±)-1-methyl-4-(1-methyl ethyl)-2-((2-methyl phenyl)methoxy)-7-oxabicyclo(2,2,1)heptane

CINMETHYLIN

Cinmethylin mixture of isomers PESTANAL

cinmethylin (bsi, draft e-iso, ansi, wssa)

Caswell No. 731G

argold

cinch

cinch(cinmethylin)

(1RS,2RS,4RS)-1,4-Epoxy-p-menth-2-yl-2-methyl benzyl ether

exo-(+/-)-1-methyl-2-(2-methylbenzyloxy)-4-isopropyl-7-oxabicyclo(2.2.1)heptane

（1RS， 2SR， 4SR）-1-，4-epoxy-p-menth-2-yl-2-methyl benzyl ehter

SKH 301

WL 95481

(1RS,2SR,4SR)-1,4-EPOXY-P-MENTHA-2-YL2-METHYLBENZYLETHER

7-Oxabicyclo(2.2.1)heptane, 1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-, (1R,2S,4S)-rel-

7-Oxabicyclo(2.2.1)heptane, 1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-, exo-(+-)-

7-Oxabicyclo(2.2.1)heptene exo-(+-)-1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-

Cinmethylin [iso]

(1R,2S,4S)-rel-1-Methyl-4-(1-Methylethyl)-2-[(2-Methylphenyl)Methoxy]-7-oxabicyclo[2.2.1]heptane

exo-(+-)-7-oxabicyclo(2.2.1)heptan

exo-(+-)-xy)

sd95481

(1RS,2RS,4RS)-1,4-epoxy-p-menth-2-yl-2-metnyl-benzyl ether

(1R,2R,4S)-1-methyl-2-[(2-methylphenyl)methoxy]-4-propan-2-yl-7-oxabicyclo[2.2.1]heptane

Cinmethylin solution

Cinmethylin@1000 μg/mL in Acetonitrile

Cinmethylin Standard

Cinmethylin@100 μg/mL in Acetonitrile

Chlorzoxazone Impurity 28

87818-31-3

Agro-Products

Aromatics

Heterocycles

Herbicide