ChemicalBook > CAS DataBase List > OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
- Product Name
- OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
- CAS No.
- 108695-90-5
- Chemical Name
- OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
- Synonyms
- OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V);Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium;(OC-6-21)-Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
- CBNumber
- CB2410018
- Molecular Formula
- C20H22Cl3O2PReS
- Formula Weight
- 649.98
- MOL File
- 108695-90-5.mol
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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Property
- form
- powder
- InChI
- 1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
- InChIKey
- GIBDGLAUIKUJJX-UHFFFAOYSA-K
- SMILES
- CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 665096
- Product name
- Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
- Purity
- 97%
- Packaging
- 250mg
- Price
- $58.94
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 665096
- Product name
- Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
- Purity
- 97%
- Packaging
- 1g
- Price
- $214.2
- Updated
- 2025/07/31
American Custom Chemicals Corporation
- Product number
- HCH0067426
- Product name
- OXOTRICHLORO[(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE]RHENIUM(V)
- Purity
- 95.00%
- Packaging
- 250MG
- Price
- $605.89
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0067426
- Product name
- OXOTRICHLORO[(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE]RHENIUM(V)
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $808.91
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0067426
- Product name
- OXOTRICHLORO[(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE]RHENIUM(V)
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1629.94
- Updated
- 2021/12/16
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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Chemical Properties,Usage,Production
Uses
Catalyst for:
- Enantioselective reduction of ketones and imines
- Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
- Synthesis of 2-deoxy-α glycosides
- Sulfurization of phosphorous(III) compounds with thiiranes
Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis
reaction suitability
core: rhenium
reagent type: catalyst
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Preparation Products And Raw materials
Raw materials
Preparation Products
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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Suppliers
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