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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)

Product Name
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
CAS No.
108695-90-5
Chemical Name
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
Synonyms
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V);Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium;(OC-6-21)-Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
CBNumber
CB2410018
Molecular Formula
C20H22Cl3O2PReS
Formula Weight
649.98
MOL File
108695-90-5.mol
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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Property

form 
powder
InChI
1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChIKey
GIBDGLAUIKUJJX-UHFFFAOYSA-K
SMILES
CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
665096
Product name
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
Purity
97%
Packaging
250mg
Price
$58.94
Updated
2025/07/31
Sigma-Aldrich
Product number
665096
Product name
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
Purity
97%
Packaging
1g
Price
$214.2
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
HCH0067426
Product name
OXOTRICHLORO[(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE]RHENIUM(V)
Purity
95.00%
Packaging
250MG
Price
$605.89
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0067426
Product name
OXOTRICHLORO[(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE]RHENIUM(V)
Purity
95.00%
Packaging
1G
Price
$808.91
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0067426
Product name
OXOTRICHLORO[(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE]RHENIUM(V)
Purity
95.00%
Packaging
5G
Price
$1629.94
Updated
2021/12/16
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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Chemical Properties,Usage,Production

Uses

Catalyst for:

  • Enantioselective reduction of ketones and imines
  • Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
  • Synthesis of 2-deoxy-α glycosides
  • Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis

reaction suitability

core: rhenium
reagent type: catalyst

OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Preparation Products And Raw materials

Raw materials

Preparation Products

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OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Suppliers

Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80
Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing1@energy-chemical.com
Country
China
ProdList
44894
Advantage
58
Shanghai Maclean Biochemical Technology Co., LTD
Tel
021-021-50706066 15221275939
Email
shenlinxing@macklin.cn
Country
China
ProdList
29784
Advantage
58
Merck KGaA
Tel
21-20338288
Email
ordercn@merckgroup.com
Country
China
ProdList
6394
Advantage
58
Santa Cruz Biotechnology Inc
Tel
021-60936350
Email
scbt@scbt.com
Country
China
ProdList
6594
Advantage
58
Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
52923
Advantage
58

108695-90-5, OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)Related Search:


  • OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
  • Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
  • (OC-6-21)-Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
  • 108695-90-5
  • C20H21Cl3O2PReS
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhenium