OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Property

form 

powder

Safety

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Chemical Properties,Usage,Production

Uses

Catalyst for:

• Enantioselective reduction of ketones and imines
• Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
• Synthesis of 2-deoxy-α glycosides
• Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis