ChemicalBook > CAS DataBase List > 4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE

4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE

Product Name
4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE
CAS No.
320-43-4
Chemical Name
4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE
Synonyms
4-Chloro-2-(trifluoromethyl)benzald;2-TRIFLUOROMETHYL-4-CHLOROBENZALDEHYDE;4-Chloro-2-fluoro-7-methoxyacetophenone;2-(Trifluoromthyl)-4-Chlorobenzaldehyde;4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE;Benzaldehyde, 4-chloro-2-(trifluoromethyl)-;4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE, 97%+
CBNumber
CB2418832
Molecular Formula
C8H4ClF3O
Formula Weight
208.57
MOL File
320-43-4.mol
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4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Property

Boiling point:
218.5±40.0 °C(Predicted)
Density 
1.423±0.06 g/cm3(Predicted)
refractive index 
1.4960
storage temp. 
2-8°C, stored under nitrogen
form 
liquid
color 
Clear, colourless
Sensitive 
Air Sensitive
CAS DataBase Reference
320-43-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22-36-43
Safety Statements 
26-36/37
Hazard Note 
Irritant
HS Code 
2913000090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
C432915
Product name
4-Chloro-2-(trifluoromethyl)benzaldehyde
Packaging
250mg
Price
$55
Updated
2021/12/16
TRC
Product number
C432915
Product name
4-Chloro-2-(trifluoromethyl)benzaldehyde
Packaging
100mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
2815-7-24
Product name
4-Chloro-2-(trifluoromethyl)benzaldehyde
Purity
97%
Packaging
5G
Price
$23
Updated
2021/12/16
SynQuest Laboratories
Product number
2815-7-24
Product name
4-Chloro-2-(trifluoromethyl)benzaldehyde
Purity
97%
Packaging
25g
Price
$93
Updated
2021/12/16
AK Scientific
Product number
J94823
Product name
4-Chloro-2-(trifluoromethyl)benzaldehyde
Packaging
100g
Price
$240
Updated
2021/12/16
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4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

320-41-2

320-43-4

The general procedure for the synthesis of 4-chloro-2-trifluoromethylbenzaldehyde using 2-trifluoromethyl-4-chlorobenzonitrile as a starting material was as follows: 2-trifluoromethyl-4-chlorobenzonitrile (appropriate amount) was added to a mixed solution of formic acid (96%, 15 mL) and water (3 mL). Nickel-aluminum alloy (1260 mg) was then added. The reaction mixture was heated and reacted at 100 °C overnight. Upon completion of the reaction, the reaction mixture was diluted with ethyl acetate and filtered through diatomaceous earth to remove solid impurities. The filtrate was sequentially extracted with 1N sodium hydroxide solution and saturated aqueous sodium chloride solution. The organic phase was dried with anhydrous sodium sulfate, filtered and concentrated to give 4-chloro-2-trifluoromethylbenzaldehyde (555 mg, 87% yield). The product was characterized by 1HNMR (400 MHz, MeOH-d4): δ 10.29 (m, 1H), 8.10 (d, 1H, J = 8.4 Hz), 7.91 (d, 1H, J = 1.6 Hz), 7.85 (dd, 1H, J = 8.4,1.6 Hz).

References

[1] Patent: WO2006/44454, 2006, A1. Location in patent: Page/Page column 63

4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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Alfa Aesar
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400-6106006
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021-67582001/03/05
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saleschina@alfa-asia.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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Capot Chemical Co., Ltd
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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China
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JinYan Chemicals(ShangHai) Co.,Ltd.
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13817811078
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86-021-50426522,50426273
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sales@jingyan-chemical.com
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China
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Pure Chemistry Scientific Inc.
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001-857-928-2050 or 1-888-588-9418
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001-617-206-9595
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sales@chemreagents.com
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United States
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Shanghai Longsheng chemical Co.,Ltd.
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bin.wu@shlschem.com
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China
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Shanghai Harvest Chemical Industrial Co., Ltd.
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021-31038972,31038973 17321035817
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+86-21-51385350
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sales@harvest-chem.com
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China
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Beijing Eternalchem Co,. Ltd.
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010-59484199 18611897322
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sales@eternalchem.com
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China
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Hangzhou Yuhao Chemical Technology Co., Ltd
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0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
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6387
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View Lastest Price from 4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE 320-43-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-25
Career Henan Chemical Co
Product
4-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE 320-43-4
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-01-31