1,2-Diaminopropane
- Product Name
- 1,2-Diaminopropane
- CAS No.
- 78-90-0
- Chemical Name
- 1,2-Diaminopropane
- Synonyms
- 1,2-PROPANEDIAMINE;DIAMINOPROPANE;propane-1,2-diamine;PROPANEDIAMINE;PROPYLENEDIAMINE;1,2-PROPYLENEDIAMINE;2,3-diaminopropane;12AP;NSC 175731;1,2-C twoaMine
- CBNumber
- CB2426189
- Molecular Formula
- C3H10N2
- Formula Weight
- 74.12
- MOL File
- 78-90-0.mol
1,2-Diaminopropane Property
- Melting point:
- -37 °C
- Boiling point:
- 120-122 °C(lit.)
- Density
- 0.87 g/mL at 25 °C(lit.)
- vapor density
- 2.6 (vs air)
- vapor pressure
- 14 mm Hg ( 20 °C)
- refractive index
- n20/D 1.446
- Flash point:
- 92 °F
- storage temp.
- Flammables area
- solubility
- H2O: very soluble
- form
- clear liquid
- pka
- 9.82(at 25℃)
- color
- Colorless to Almost colorless
- PH
- 12 (100g/l, H2O, 20℃)
- explosive limit
- 2.2-11.1%(V)
- Water Solubility
- SOLUBLE
- Sensitive
- Air Sensitive & Hygroscopic
- Merck
- 14,7852
- BRN
- 605274
- Dielectric constant
- 10.2（Ambient）
- Stability:
- Stable. Flammable. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides.
- InChIKey
- AOHJOMMDDJHIJH-UHFFFAOYSA-N
- LogP
- -1.2 at 20℃
- CAS DataBase Reference
- 78-90-0(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,2-Propanediamine(78-90-0)
- EPA Substance Registry System
- 1,2-Diaminopropane (78-90-0)
Safety
- Hazard Codes
- C
- Risk Statements
- 10-21/22-35-42/43
- Safety Statements
- 26-37/39-45-36/37/39-23
- RIDADR
- UN 2258 8/PG 2
- WGK Germany
- 1
- RTECS
- TX6650000
- F
- 3-10-23
- Autoignition Temperature
- 680 °F
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29212900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H302Harmful if swallowed
H311Toxic in contact with skin
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 117498
- Product name
- 1,2-Diaminopropane
- Purity
- 99%
- Packaging
- 100g
- Price
- $29
- Updated
- 2024/03/01
- Product number
- 117498
- Product name
- 1,2-Diaminopropane
- Purity
- 99%
- Packaging
- 2kg
- Price
- $212.8
- Updated
- 2024/03/01
- Product number
- D0113
- Product name
- 1,2-Diaminopropane
- Purity
- >98.0%(GC)(T)
- Packaging
- 25mL
- Price
- $22
- Updated
- 2024/03/01
- Product number
- D0113
- Product name
- 1,2-Diaminopropane
- Purity
- >98.0%(GC)(T)
- Packaging
- 500mL
- Price
- $73
- Updated
- 2024/03/01
- Product number
- B24489
- Product name
- 1,2-Diaminopropane, 99%
- Packaging
- 100ml
- Price
- $21.65
- Updated
- 2024/03/01
1,2-Diaminopropane Chemical Properties,Usage,Production
Description
1,2-Diaminopropane is a colorless liquid that is very hygroscopic and miscible with water and most organic solvents. It forms azeotropes with butanol, 2-methylpropanol, and toluene and has a strong ammoniacal odor.
Chemical Properties
clear liquid
Uses
1,2-Diaminopropane was used as model precursor in the electron induced deposition of amorphous carbon nitride films.
Uses
In conjunction with cupric sulfate it is a very sensitive reagent for mercury.
Production Methods
Because 1,2-dichloropropane does not react smoothly with ammonia, 1,2-diaminopropane is usually prepared by aminating a mixture of 2-amino-1-propanol and 1-amino-2-propanol, which is obtained from propylene oxide and ammonia. The process differs from corresponding processes for the production of diaminoethane in that the temperature in the catalytic amination is higher (190 – 230 ℃).
Application
1,2-Diaminopropane is used as an intermediate for crop-protection agents, e.g., Basfungin (BASF). Analogous to the ethylenediamine derivatives, the zinc dithiocarbamate propineb acts as a fungicide. Especially in the United States, derivatives of the amine are used as fuel and lubricant additives.
Definition
ChEBI: A diamine that is propane substituted by amino groups at positions 1 and 2. Propylenediamine is commonly used as a bidentate ligand in the formation of coordination complexes.
General Description
A colorless liquid with an ammonia-like odor. Flash point 160°F. Density 0.87 g / cm3. Boiling point 243°F. Strongly irritates skin and tissue.
Air & Water Reactions
Very hygroscopic. Very soluble in water.
Reactivity Profile
1,2-Diaminopropane neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
Health Hazard
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and Explosibility
Flammable
Safety Profile
Moderately toxic by ingestion, sktn contact, and subcutaneous routes. A corrosive irritant to eyes, skin, and mucous membranes. Dangerous fire hazard when exposed to heat, flames, oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. Used as an intermedate in production of petroleum and polymer additives, and surfactants. See also AMINES.
Purification Methods
Purify the diamine by azeotropic distillation with toluene. Then distil it. Store it in a CO2 free atmosphere. [Horton et al. Anal Chem 27 269 1955, Beilstein 4 IV 1255.]
1,2-Diaminopropane Preparation Products And Raw materials
Raw materials
Preparation Products
1,2-Diaminopropane Suppliers
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View Lastest Price from 1,2-Diaminopropane manufacturers
- Product
- 1,2-Diaminopropane 78-90-0
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2022-10-14
- Product
- 1,2-Diaminopropane 78-90-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-09-08
- Product
- 1,2-Diaminopropane 99% 78-90-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27