3-Bromo-9H-carbazole

Product Name: 3-Bromo-9H-carbazole
CAS No.: 1592-95-6
Chemical Name: 3-Bromo-9H-carbazole
Synonyms: 2-bromo-9H-carbazole;3-BROMOCARBAZOLE;9H-Carbazole, 3-bromo-;3-broMidecarbazole;Carbazole, 3-bromo-;3- broMinecarbazole;3-Bromo-9H-carbazoL;3-Bromocarbazole >3-BROMO-9H-CARBAZOLE;3-BroMocarbazole (3BC)
CBNumber: CB2444848
Molecular Formula: C12H8BrN
Formula Weight: 246.1
MOL File: 1592-95-6.mol

More

Less

3-Bromo-9H-carbazole Property

Melting point:: 195 °C
Boiling point:: 160℃/6mm
Density: 1.617±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: 16.43±0.30(Predicted)
form: Solid
color: White
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C12H8BrN/c13-8-5-6-12-10(7-8)9-3-1-2-4-11(9)14-12/h1-7,14H
InChIKey: LTBWKAYPXIIVPC-UHFFFAOYSA-N
SMILES: N1C2=C(C=CC=C2)C2=C1C=CC(Br)=C2
EPA Substance Registry System: 3-Bromocarbazole (1592-95-6)

More

Less

Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-37/39-24/25
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29339900

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 777153
Product name: 3-Bromocarbazole
Purity: 97% (GC)
Packaging: 1g
Price: $64.6
Updated: 2023/06/20

TCI Chemical

Product number: B3458
Product name: 3-Bromocarbazole
Purity: >97.0%(GC)
Packaging: 5g
Price: $66
Updated: 2024/03/01

TCI Chemical

Product number: B3458
Product name: 3-Bromocarbazole
Purity: >97.0%(GC)
Packaging: 25g
Price: $229
Updated: 2024/03/01

Alfa Aesar

Product number: H64437
Product name: 3-Bromocarbazole, 98%
Packaging: 5g
Price: $105
Updated: 2024/03/01

Alfa Aesar

Product number: H64437
Product name: 3-Bromocarbazole, 98%
Packaging: 1g
Price: $28.6
Updated: 2023/06/20

More

Less

3-Bromo-9H-carbazole Chemical Properties,Usage,Production

Description

3-Bromo-9H-carbazole is an isomer to 2-Bromo-9H-carbazole, with the only difference being that 9H-carbazole is mono-brominated at 3-position. Blocked at 3-position, 3-Bromo-9H-carbazole derivatives reduce the chance of being oxidised to form excimers or oligomers. 3-bromo-9H-carbazole is a versatile building block that can be used to create a range of compounds, such as 9-Benzyl-3-bromo-9H-carbazole. 3-Bromo-9H-carbazole can be prepared by reacting 9H-carbzole with N-bromosuccinimide (NBS) In tetrahydrofuran at room temperature[1].

Chemical Properties

White to light yellow solid

Uses

3-Bromo-9H-carbazole is an aryl hydrocarbon receptor agonist. A standard for environmental testing and research. Substance for the bological potency study, characterization of mono to tetra-halogenated carbazoles.

Uses

3-Bromocarbazole is used as a intermediate for organic light-emitting diode(OLED) and pharmaceutical.

Preparation

3-Bromocarbazole synthesis: A solution of N-bromosuccinimide (1.1g, 5.98mmol) in dimethylformamide was added dropwise to a solution of carbazole (1, 1g, 5.96mmol) in dimethylformamide (15mL) at 0°C. The reaction mixture was then stirred at room temperature for 24h. The reaction was poured into distilled water to give a cream coloured precipitate. The precipitate was filtered off under vacuum and washed with distilled water (3 × 20mL). The precipitate was dissolved in ethyl acetate, dried with sodium sulfate and filtered. Upon concentration under reduced pressure the crude product was obtained as a brown solid. After crystallisation of the crude product with chloroform, the pure 3-Bromo-9H-carbazole(692 mg, 47%) was obtained as white crystals. Rf (ethyl acetate/hexane, 1:6 v/v): 0.43; melting point: 200–201°C.

References

[1] Peng-Mian Huang, Xiao-Chun Wang. “9-Benzyl-3-bromo-9H-carbazole.” Acta crystallographica. Section E, Structure reports online 65 Pt 8 (2009): o1763.

3-Bromo-9H-carbazole Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

3-Bromo-9H-carbazole Suppliers

Americas 1 Australia 1 Belgium 4 China 388 Europe 1 France 1 Germany 7 India 6 Japan 5 South Korea 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 13 United States 39 Global 470

Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
Advantage: 56

AbaChemScene

Tel: 732-484-9848
Fax: 888-484-5008
Email: sales@chemscene.com
Country: United States
ProdList: 3982
Advantage: 60

Alfa Chemistry

Tel
Fax: 1-516-927-0118
Email: Info@alfa-chemistry.com
Country: United States
ProdList: 24072
Advantage: 58

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

AB PharmaTech,LLC

Tel: 323-480-4688
Fax: 323-480-4688
Email: sales@acrospharmatech.com
Country: United States
ProdList: 989
Advantage: 55

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Aston Chemical

Tel: 13000000000
Email: sales@astonchem.com
Country: United States
ProdList: 1634
Advantage: 58

Alfa Chemistry

Tel
Email: info@alfa-chemistry.com
Country: United States
ProdList: 2344
Advantage: 58

Alfa Chemistry

Tel: --
Fax: --
Email: info@Alfa-Chemistry.com
Country: United States
ProdList: 6814
Advantage: 0

Crescent Chemical Company

Tel: --
Fax: --
Email: fran@creschem.com
Country: United States
ProdList: 1441
Advantage: 58

Glentham Life Sciences Ltd

Tel: --
Fax: --
Email: info@glentham.com
Country: United States
ProdList: 2026
Advantage: 58

Synblock,Inc.

Tel: --
Fax: --
Email: sales@synblock.com
Country: United States
ProdList: 228
Advantage: 58

Alichem Inc.

Tel: --
Fax: --
Email: sales@alichem.com
Country: United States
ProdList: 6167
Advantage: 58

Fluorochem Ltd.

Tel: --
Fax: --
Email: enquiries@fluorochem.co.uk
Country: United States
ProdList: 4583
Advantage: 58

TCI America, Inc. (Tokyo Chemical Industry Co., Ltd.)

Tel: --
Fax: --
Email: .Crew@tcichemicals.com
Country: United States
ProdList: 3164
Advantage: 58

Combi-Blocks, Inc.

Tel: --
Fax: --
Email: les@combi-blocks.com
Country: United States
ProdList: 2555
Advantage: 58

2A Biotech USA

Tel: --
Fax: --
Email: info@2abiotech.com
Country: United States
ProdList: 1785
Advantage: 58

Accel Pharmtech, LLC

Tel: --
Fax: --
Email: sales@accelpharmtech.com
Country: United States
ProdList: 972
Advantage: 58

SynQuest Laboratories, Inc. (Part of Central Glass Co., Ltd.)

Tel: --
Fax: --
Email: nfo@synquestlabs.com
Country: United States
ProdList: 1897
Advantage: 58

MilliporeSigma (Sigma-Aldrich Corp.)

Tel: --
Fax: --
Email: @sial.com
Country: United States
ProdList: 5414
Advantage: 58

OX CHEM

Tel: --
Fax: --
Email: sales@ox-chem.com
Country: United States
ProdList: 759
Advantage: 50

Advance Scientific & Chemical

Tel: --
Fax: --
Email: sales@advance-scientific.com
Country: United States
ProdList: 6419
Advantage: 71

AK Scientific, Inc.

Tel: --
Fax: --
Email: sales@aksci.com
Country: United States
ProdList: 6347
Advantage: 65

Accela ChemBio Inc.

Tel: --
Fax: --
Email: info@accelachem.com
Country: United States
ProdList: 1054
Advantage: 50

VWR International, LLC.

Tel: --
Fax: --
Email: @sargentwelch.com
Country: United States
ProdList: 6262
Advantage: 58

OChem Incorporation

Tel: --
Fax: --
Email: sales@ocheminc.com
Country: United States
ProdList: 6501
Advantage: 60

Spectrum Chemical Mfg. Corp.

Tel: --
Fax: --
Email: marketing@spectrumchemical.com
Country: United States
ProdList: 3113
Advantage: 60

Boron Molecular Inc.

Tel: --
Fax: --
Email: sales@boronmolecular-usa.com
Country: United States
ProdList: 996
Advantage: 65

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6962
Advantage: 56

Waterstone Technology, LLC

Tel: --
Fax: --
Email: sales@waterstonetech.com
Country: United States
ProdList: 6786
Advantage: 30

Ryan Scientific, Inc.

Tel: --
Fax: --
Email: ryan.reichlyn@ryansci.com
Country: United States
ProdList: 6439
Advantage: 60

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

More

Less

View Lastest Price from 3-Bromo-9H-carbazole manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 3-Bromo-9H-carbazole 1592-95-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-11-18

Shaanxi Dideu Medichem Co. Ltd

Product: 3-Bromo-9H-carbazole 1592-95-6
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 99%
Supply Ability: 2000tons
Release date: 2019-12-31

Hebei Xinsheng New Material Technology Co., LTD.

Product: 3-Bromo-9H-carbazole 1592-95-6
Price: US $35.00-25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 Ton
Release date: 2023-10-08

1592-95-6, 3-Bromo-9H-carbazoleRelated Search:

Carbazole POLY(N-VINYLCARBAZOLE) 3,6-Dibromo-9-ethylcarbazole 3,6-Dibromocarbazole Bromine 1-(3,6-DIBROMO-CARBAZOL-9-YL)-3-PYRROLIDIN-1-YL-PROPAN-2-OL TIMTEC-BB SBB006353 1-(3,6-DIBROMO-CARBAZOL-9-YL)-3-[4-(4-FLUORO-PHENYL)-PIPERAZIN-1-YL]-PROPAN-2-OL 1,4-Dimethyl-6-bromo-9H-carbazole 3,6-DIBROMO-9-VINYLCARBAZOLE 3,6-DIBROMO-9-(OXIRAN-2-YLMETHYL)-9H-CARBAZOLE 3,6-DIBROMO-ALPHA-(1-PIPERAZINYLMETHYL)-9H-CARBAZOLE-9-ETHANOL DIHYDROCHLORIDE 1-(3,6-DIBROMO-9H-CARBAZOL-9-YL)-3-(DIMETHYLAMINO)PROPAN-2-OL 3,6-Dibromo-9-phenyl-9H-carbazole 3-Bromo-9H-carbazole AKOS BC-1674 1-(4-[2-HYDROXY-3-(1,3,6-TRIBROMO-9H-CARBAZOL-9-YL)PROPYL]PIPERAZINO)-3-(1,3,6-TRIBROMO-9H-CARBAZOL-9-YL)PROPAN-2-OL DIHYDROCHLORIDE SALOR-INT L150053-1EA

3-BROMO-9H-CARBAZOLE

2-bromo-9H-carbazole

3-BROMOCARBAZOLE

3-broMidecarbazole

3-BroMo-9H-carbazole, 95+%

3-Bromocarbazole 97% (GC)

3-BroMocarbazole (3BC)

3- broMinecarbazole

Carbazole, 3-bromo-

9H-Carbazole, 3-bromo-

3-Bromocarbazole &gt

3-Bromo-9H-carbazoL

1592-95-6

1595-95-6

1952-95-6

C12H8BrN

Pyridines

OLED materials,pharm chemical,electronic

Carbazole Series

organic chemicals and derivatives/others

OLED

Fused Ring Systems

Halides

bc0001