ChemicalBook > CAS DataBase List > SODIUM ACETYLIDE

SODIUM ACETYLIDE

Product Name
SODIUM ACETYLIDE
CAS No.
1066-26-8
Chemical Name
SODIUM ACETYLIDE
Synonyms
Sodioethyne;ETHYNYLSODIUM;ethyne:sodium;Sodium acetyL;Sodium acetylid;SODIUM ACETYLIDE;Sodium acetylenide;Monosodium acetyide;Monosodium acetylide;SodiuM acetylide suspensi
CBNumber
CB2455464
Molecular Formula
C2HNa
Formula Weight
48.02
MOL File
1066-26-8.mol
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SODIUM ACETYLIDE Property

Boiling point:
-22.2°C
Density 
0,865 g/cm3
Flash point:
85 °F
storage temp. 
Refrigerator (+4°C) + Flammables area
form 
Low Melting Solid or Crystalline Powder
color 
White to pale yellow
Water Solubility 
Reacts with water.
Sensitive 
Air & Moisture Sensitive
BRN 
3587232
CAS DataBase Reference
1066-26-8(CAS DataBase Reference)
EPA Substance Registry System
Sodium acetylide (1066-26-8)
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Safety

Hazard Codes 
F,Xn,C
Risk Statements 
10-15-20/21-38-34-14/15
Safety Statements 
36/37-43-45-36/37/39-26
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
3
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
II
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H261In contact with water releases flammable gas

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
249572
Product name
Sodium acetylide suspension
Purity
18 wt. % slurry in xylene: light mineral oil, 95% (Purity of contained acetylide)
Packaging
100g
Price
$83.1
Updated
2024/03/01
Sigma-Aldrich
Product number
249572
Product name
Sodium acetylide suspension
Purity
18 wt. % slurry in xylene: light mineral oil, 95% (Purity of contained acetylide)
Packaging
500g
Price
$251
Updated
2024/03/01
Strem Chemicals
Product number
93-1021
Product name
Sodium acetylide (18% suspension in xylene)
Packaging
50g
Price
$48
Updated
2021/12/16
Strem Chemicals
Product number
93-1021
Product name
Sodium acetylide (18% suspension in xylene)
Packaging
250g
Price
$187
Updated
2021/12/16
TRC
Product number
S960228
Product name
SodiumAcetylideSuspension(18wt.%slurryinxylene)
Packaging
50g
Price
$115
Updated
2021/12/16
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SODIUM ACETYLIDE Chemical Properties,Usage,Production

Description

Sodium acetylide is an unstable powder, a salt of acetylene. It is a severe explosion risk when shocked or heated. It is used in the manufacture of detonators.

Chemical Properties

brown slurry

Uses

Sodium Acetylide Suspension is a reagent used in the synthesis of rhodium(I) amidinate complexes.

Uses

Sodium acetylide suspension has been used in the preparation of: 2-ethynyladamantan-2-ol1 apical-equatorial (ae) isomer of (Et4N)3[1-(2′-B10H9)-2-NH3B10H8]2 trimethylsilylacetylene3

Definition

ChEBI: The salt formed from the acetylide monoanion and a single sodium cation.

Purification Methods

It sometimes contains diluents, e.g. xylene, butyl ether or dioxane which can be removed by filtration followed by a vacuum at 65-60o/5mm. Alternatively the acetylide is purged with HCCH at 100-125o to remove diluent. NaC2H adsorbs 2.2x, 2.0x and 1.6x its wt of xylene, butyl ether and dioxane, respectively. Powdered NaC2H is yellow or yellow-gray in colour and is relatively stable. It can be heated to ca 300o in the absence of air. Although no explosion or evolution of gas occurs, it turns brown due to disproportionation. At 170-190o in air it ignites slowly and burns smoothly. At 215-235o in air it “flash-ignites” and burns quickly. It can be dropped into a slight excess of H2O without flashing or burning, but vigorous evolution of HC CH (HIGHLY FLAMMABLE IN AIR) occurs. The sample had been stored in the absence of air for one year without deterioration. Due to the high flammability of HCCH, the salt should be stored dry and should be treated with care. After long storage, NaCCH can be redissolved in liquid NH3 and used for the same purposes as the fresh material. However it may be slightly turbid due to the presence of moisture. [Rutledge J Org Chem 22 649 1957, Greenlee & Henne J Am Chem Soc 77 5013 1955, Campbell & Campbell Inorg Synth II 76, 81 1946, Org Synth 30 15 1950, Beilstein 1 H 238.] It is available commercially under N2 in Sure/Seal bottles as an 18 wt% solution in xylene/mineral oil. See “Aliphatic Compounds”, Chapter 4, for its prepartion.

SODIUM ACETYLIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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SODIUM ACETYLIDE Suppliers

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View Lastest Price from SODIUM ACETYLIDE manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
SODIUM ACETYLIDE 1066-26-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-03-01

1066-26-8, SODIUM ACETYLIDERelated Search:


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