Description Chemical Properties
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Lily aldehyde

Description Chemical Properties
Product Name
Lily aldehyde
CAS No.
80-54-6
Chemical Name
Lily aldehyde
Synonyms
LILIAL;BUTYLPHENYL METHYLPROPIONAL;2-(4-TERT-BUTYLBENZYL)PROPIONALDEHYDE;LYSMERAL;Lillial;synthetic convallaria aldehyde;4-(1,1-Dimethylethyl)-methylbenzenepropanal;Propanal, alpha-methyl-beta-(p-tert.-butylphenyl)-;Lilyal;lilyall
CBNumber
CB2492379
Molecular Formula
C14H20O
Formula Weight
204.31
MOL File
80-54-6.mol
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Lily aldehyde Property

Melting point:
106-109 °C
Boiling point:
150°C 10mm
Density 
0.946 g/mL at 20 °C(lit.)
vapor pressure 
0.25Pa at 20℃
refractive index 
n20/D 1.505
Flash point:
100°C
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly)
form 
Liquid
color 
Colorless to Light yellow
Odor
at 100.00 %. floral muguet watery green powdery cumin
Odor Type
floral
Water Solubility 
33mg/L at 20℃
BRN 
880140
InChIKey
SDQFDHOLCGWZPU-UHFFFAOYSA-N
LogP
4.2 at 24℃
CAS DataBase Reference
80-54-6(CAS DataBase Reference)
NIST Chemistry Reference
Lilial(80-54-6)
EPA Substance Registry System
Benzenepropanal, 4-(1,1-dimethylethyl)-.alpha.-methyl- (80-54-6)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
22-38-51/53-62-43
Safety Statements 
60-61-36/37
RIDADR 
UN 3082 9/PG 3
WGK Germany 
2
RTECS 
MW4895000
10
HS Code 
29121900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H361Suspected of damaging fertility or the unborn child

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CRM40184
Product name
Lilial solution
Purity
certified reference material, 2000?μg/mL in methanol, ampule of 1?mL
Packaging
1mL
Price
$116
Updated
2024/03/01
Sigma-Aldrich
Product number
43884
Product name
2-(4-tert-Butylbenzyl)propionaldehyde
Purity
analytical standard
Packaging
10mg
Price
$69.1
Updated
2024/03/01
TCI Chemical
Product number
B1145
Product name
3-(4-tert-Butylphenyl)isobutyraldehyde
Purity
>96.0%(GC)
Packaging
25mL
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
B1145
Product name
3-(4-tert-Butylphenyl)isobutyraldehyde
Purity
>96.0%(GC)
Packaging
100mL
Price
$73
Updated
2024/03/01
TCI Chemical
Product number
B1145
Product name
3-(4-tert-Butylphenyl)isobutyraldehyde
Purity
>96.0%(GC)
Packaging
500mL
Price
$217
Updated
2024/03/01
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Lily aldehyde Chemical Properties,Usage,Production

Description

Lily aldehyde (also known as lysmeral or Lilial) is a chemical compound commonly used as a perfume in cosmetic preparations and laundry powders1-3. It is fresh light green floral lily muguet lindenblossom aldehyde. Lilial is used in a wide variety of compositions where it confers a particularly recommended for floral notes such as muguet, linden-blossom and cyclamen2.

Chemical Properties

Lilial is a colorless to pale yellow liquid, as yet has not been found in nature. It has a higher stability than the homologous cyclamenaldehyde and therefore is used as scent in soaps.

Lilial is a widely used fragrance compound found naturally in the essential oil of chamomile and is used synthetically in a variety of beauty products, including perfumes, shampoos, deodorants, tanning lotions and hairstyling products, primarily for its Lily of the Valley aroma.

Chemical Properties

Lily aldehyde is a homolog of cyclamenaldehyde. The racemic compound is a colorless to slightly yellow liquid with a mild-floral odor, reminiscent of cyclamen and lily of the valley.
The aldehyde is prepared by the same routes as cyclamenaldehyde.
Other routes start from ??-methylcinnamaldehyde. ??-Methylcinnamaldehyde (from benzaldehyde and propionaldehyde) is hydrogenated to ??-methyldihydrocinnamic alcohol.The alcohol is alkylated with tert-butyl chloride or isobutene to 4-tert-butyl-??-methyldihydrocinnamic alcohol, which is subsequently dehydrogenated to the desired aldehyde.
4-tert-Butyl-??-methyldihydrocinnamaldehyde is more stable than cyclamenaldehyde and is a popular component of flower compositions, particularly lily of the valley and linden types, because of its mild, pleasant, blossomfragrance. It is used in a wide range of perfume types, but especially in soap and detergent perfumes.

Uses

In addition to its applications in the perfume and aroma industry, lilial is used mainly for the synthesis of substituted 3-(4-tert-butylphenyl)-2-methylpropylamines, a new class of substances with fungicidal properties. These compounds are effective against mildew in barley and wheat.

Uses

2-(4-tert-Butylbenzyl)propionaldehyde may be used as a reference standard for the determination of 2-(4-tert-butylbenzyl)propionaldehyde in:

  • Human urine samples by ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) equipped with electrospray ionization (ESI) source and multiple reaction monitoring (MRM) mode of detection.
  • Deodorants and air fresheners by sonication extraction coupled with gas chromatography-mass spectrometry (GC-MS).
  • Scented consumer products by GC-MS as well as GC in combination with olfactometry.

Production Methods

Lily aldehyde is produced industrially almost solely by aldol condensation of 4-tert-butylbenzaldehyde and propionaldehyde to give 4-tert-butyl-α-methylcinnamaldehyde, which can be hydrogenated selectively on noble metal catalysts such as Pd, Rh, Pd – Pr2O3 on Al2O3, or on modified cobalt catalysts. The aldol condensation and the hydrogenation can be carried out in one step in the presence of a hydrogenation catalyst.
The Friedel – Crafts reaction of 4-tertbutylbenzene with methacrolein or methacrolein diacetate proceeds in an analogous manner to the preparation of cyclamenaldehyde.
Further possibilities are the Rh-catalyzed hydroformylation of 1-(4-tert-butylphenyl)-1- methoxypropene and subsequent partial hydrogenation, the palladium salt catalyzed reaction of 4-tert-butylphenylhalide with methallylalcohol, and the dehydrogenation of 3-(4-tert-butylphenyl)-2-methylpropanol on silver catalysts.

General Description

2-(4-tert-Butylbenzyl)propionaldehyde is categorized under the synthetic fragrance class of compounds widely utilized in consumer products such as perfumes, after shave lotions, cosmetics, etc.

Flammability and Explosibility

Non flammable

Trade name

Lilestralis Pure (Innospec), Lysmeral® Extra (BASF).

Contact allergens

Lilial? is a synthetic compound listed as a fragrance allergen. Its presence is indicated on cosmetics within the EU.

Lily aldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Lily aldehyde manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Lily aldehyde 80-54-6
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Lily aldehyde 80-54-6
Price
US $80.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-04-25
Hebei Chuanghai Biotechnology Co,.LTD
Product
Lily aldehyde 80-54-6
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-22

80-54-6, Lily aldehydeRelated Search:


  • Lilial Lilestralis
  • Lilial solution
  • 4-(1,1-Dimethylethyl)-methylbenzenepropanal
  • synthetic convallaria aldehyde
  • 3-(4-tert-Butylphenyl)isobutyraldehyde (beta-)
  • BUTYLPHENYL METHYLPROPIONAL
  • 4-tert-butyl-alpha-methyl hydrocinnamic aldehyde
  • alpha-Methyl, beta-(p-tert-butylphenyl)propionaldehyde
  • alpha-methyl,beta-(p-tert-butylphenyl)propionaldehyde
  • alpha-Methyl-p-(tert-butyl)hydrocinnamaldehyde
  • Benzenepropanal, 4-(1,1-dimethylethyl)-alpha-methyl-
  • Benzenepropanal, 4-(tert-butyl)-a-methyl-
  • Benzenepropanal, 4-tert-butyl-alpha-methyl-
  • Benzenepropanal,4-(1,1-dimethylethyl)-.alpha.-methyl-
  • beta-(4-tert-butylphenyl)-alpha-methyl-propionaldehyd
  • Hydrocinnamaldehyde, p-tert-butyl-alpha-methyl-
  • Lilialdehyde
  • Lilyal
  • Propanal, alpha-methyl-beta-(p-tert.-butylphenyl)-
  • Propionaldehyde, beta-(4-tert-butylphenyl)-alpha-methyl-
  • p-t-Butyl-alpha-methylhydrocinnamaldehyde
  • p-tert-butyl-alpha-methyl-hydrocinnamaldehyd
  • p-tert-Butyl-alpha-methylhydrocinnamaldehyde
  • p-tert-Butyl-alpha-methylhydrocinnamic aldehyde
  • p-tert-Butyl-alpha-methyl-hydrocinnamic aldehyde (lily aldehyde)
  • p-tert-butyl-alpha-methylhydrocinnamicaldehyde
  • p-tert-Butyl-methylhydrocinnamicaldehyde
  • tert-Butyl-alpha-methylhydrocinamaldehyde
  • Lilestralis
  • p-tert-Butyl-α-methyldihydrocinnamaldehyde
  • α-Methyl-β-(p-tert-butylphenyl) propionaldehyde
  • 2-METHYL-3-(4-T-BUTYLPHENYL0PROPIONALDEHYDE
  • Convallarieae
  • 4-tert-butyl-α-methyl-benzenepropanal
  • butylphenol methylpropional
  • 2-(4-tert-Butylbenzyl)propionaldehyde (tech)
  • PARA-TERT-BUTYL-A-METHYLHYDROCINNAMALDEHYDE
  • PARA-TERT-BUTYL-ALPHA-METHYLHYDROCINNAMAL
  • PARA-TERT-BUTYL-ALPHA-METHYL-HYDROCINNAMALDEHYDE
  • LILYALDEHYDE
  • HYDROCINNAMALDEHYDE,PARA-TERT-BUTYL-ALPHA-METHYL-
  • PARA-TERT-BUTYL-ALPHA-METHYLHYDROCINNAMICALDEHYDE
  • 2-(4-tert-Butylbenzyl)propionaldehyd
  • Lillial
  • 2-(4-tert-Butylbenzyl)propionaldehyde 3-(4-tert-Butylphenyl)isobutyraldehyde 3-(4-tert-Butylphenyl)-2-methylpropionaldehyde 4-tert-Butyl-α-methylhydrocinnamaldehyde 4-tert-Butyl-α-methyl-benzenepropanal
  • 2-(4-tert-Butylbenzyl)propionaldehydeanalytical standard
  • P-TERT-BUTYL-A-METHYLHYDROCINN AMALDEHYDE
  • 2-(4-TERT-BUTYLBENZYL)PROPIONALDEHYDE
  • 4-TERT-BUTYL-ALPHA-METHYL-BENZENEPROPANAL
  • 4-TERT-BUTYL-ALPHA-METHYLHYDROCINNAMALDEHYDE
  • 3-(4-TERT-BUTYLPHENYL)-2-METHYLPROPIONALDEHYDE
  • 3-(4-TERT-BUTYLPHENYL)ISOBUTYRALDEHYDE
  • 3-(4-T-BUTYLPHENYL)-2-ISOBUTYRALDEHYDE
  • BETA-3-(4-TERT-BUTYLPHENYL)ISOBUTYRALDEHYDE
  • LILIAL
  • 3-(4-tert-Butylphenyl)-2-methylpropanal
  • 4-(1,1-dimethylethyl)-.alpha.-methyl-Benzenepropanal
  • 4-(1,1-dimethylethyl)-alpha-methyl-benzenepropana