cyclamen aldehyde
- Product Name
- cyclamen aldehyde
- CAS No.
- 103-95-7
- Chemical Name
- cyclamen aldehyde
- Synonyms
- 3-(4-Isopropylphenyl)-2-methylpropanal;Cyclamal;2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE;3-p-cumenyl-2-methylpropionaldehyde;3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE;3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE;(R,S)-p-Isopropyl-α-methylhydro-cinnamaldehyde;3-p-;FEMA 2743;aldehydeb
- CBNumber
- CB9246702
- Molecular Formula
- C13H18O
- Formula Weight
- 190.28
- MOL File
- 103-95-7.mol
cyclamen aldehyde Property
- Boiling point:
- 270 °C(lit.)
- Density
- 0.95 g/mL at 25 °C(lit.)
- vapor pressure
- 0.3Pa at 20℃
- refractive index
- n20/D 1.505(lit.)
- FEMA
- 2743 | 2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE
- Flash point:
- 228 °F
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Chloroform (Slightly), Ethyl Acetate, Methanol (Slightly)
- form
- Oil
- color
- Colourless liquid.
- Odor
- Powerful floral-green with a characteristic cucumber-melon note used in floral types.
- Odor Type
- floral
- Water Solubility
- 66mg/L at 20℃
- JECFA Number
- 1465
- Stability:
- Hygroscopic
- LogP
- 3.4 at 35℃
- CAS DataBase Reference
- 103-95-7(CAS DataBase Reference)
- EPA Substance Registry System
- Benzenepropanal, .alpha.-methyl-4-(1-methylethyl)- (103-95-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- W274305
- Product name
- 2-Methyl-3-(p-isopropylphenyl)propionaldehyde
- Purity
- ≥95%, FCC, FG
- Packaging
- sample-k
- Price
- $54.6
- Updated
- 2024/03/01
- Product number
- W274305
- Product name
- 2-Methyl-3-(p-isopropylphenyl)propionaldehyde
- Purity
- ≥95%, FCC, FG
- Packaging
- 1kg
- Price
- $139
- Updated
- 2024/03/01
- Product number
- W274305
- Product name
- 2-Methyl-3-(p-isopropylphenyl)propionaldehyde
- Purity
- ≥95%, FCC, FG
- Packaging
- 5kg
- Price
- $511
- Updated
- 2024/03/01
- Product number
- S405361
- Product name
- 3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE
- Purity
- Aldrich
- Packaging
- 1g
- Price
- $179
- Updated
- 2024/03/01
- Product number
- I0377
- Product name
- 3-(4-Isopropylphenyl)isobutyraldehyde
- Purity
- >92.0%(GC)
- Packaging
- 25mL
- Price
- $78
- Updated
- 2024/03/01
cyclamen aldehyde Chemical Properties,Usage,Production
Description
2-Methyl-3-(p-isopropylphenyl) propionaldehyde has a strong, flowery odor. May be prepared by condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst.
Chemical Properties
The commercially available racemate is a colorless to yellowish liquid with an intense floral odor reminiscent of Cyclamen europaeum (cyclamen, sowbread).
Production. Two main processes are used for the industrial synthesis of cyclamen aldehyde:
1) Alkaline condensation of 4-isopropylbenzaldehyde and propanal results, via the aldol, in the formation of 2-methyl-3-(4-isopropylphenyl)-2-propenal. The unsaturated aldehyde is hydrogenated selectively to the saturated aldehyde in the presence of potassium acetate and a suitable catalyst, such as palladium–alumina:
2) Friedel–Crafts reaction of isopropylbenzene and 2-methylpropenal diacetate (methacrolein diacetate) in the presence of titanium tetrachloride/boron trifluoride etherate gives cyclamen aldehyde enolacetate, which is hydrolyzed to aldehyde:
Uses. Cyclamen aldehyde is an important component for obtaining special blossomnotes in perfume compositions, particularly the cyclamen type. Because of its fresh, floral aspect, it is also used as the top note in many other blossomfragrances.
Chemical Properties
2-Methyl-3-(p-isopropylphenyl)-propionaldehyde has a strong, flowery odor
Occurrence
Reported found in nutmeg and starfruit.
Uses
Cyclamal, is an ingredient in perfume. It can also be used in the synthesis of Cyclamen Alcohol (C987655).
Uses
Cyclamen Aldehyde is a very powerful, floral, green note used in many perfumery applications to blend into fresh, floral, green or ozonic/marine accords. It is an ingredient with growing use and importance in helping to build replacement accords for materials disappearing from the Perfumers’ palette. Cyclamen has good overall stability except in extremes of pH. It has good tenacity and substantivity and represents very good value for money in new creations.In addition to its use in numerous perfume compositions, cyclamen aldehyde is an intermediate for the preparation of fungicides and fungistatic substances.
Definition
ChEBI: Xi-3-(4-Isopropylphenyl)-2-methylpropanal is a monoterpenoid.
Preparation
By condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst
Safety Profile
Moderately toxic by ingestion. A human skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
cyclamen aldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from cyclamen aldehyde manufacturers
- Product
- cyclamen aldehyde 103-95-7
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-09-22
- Product
- cyclamen aldehyde 103-95-7
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2023-04-03
- Product
- cyclamen aldehyde 103-95-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 50000kg
- Release date
- 2023-08-14