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cyclamen aldehyde

Product Name
cyclamen aldehyde
CAS No.
103-95-7
Chemical Name
cyclamen aldehyde
Synonyms
3-(4-Isopropylphenyl)-2-methylpropanal;Cyclamal;2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE;3-p-cumenyl-2-methylpropionaldehyde;3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE;3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE;(R,S)-p-Isopropyl-α-methylhydro-cinnamaldehyde;3-p-;FEMA 2743;aldehydeb
CBNumber
CB9246702
Molecular Formula
C13H18O
Formula Weight
190.28
MOL File
103-95-7.mol
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cyclamen aldehyde Property

Boiling point:
270 °C(lit.)
Density 
0.95 g/mL at 25 °C(lit.)
vapor pressure 
0.3Pa at 20℃
refractive index 
n20/D 1.505(lit.)
FEMA 
2743 | 2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE
Flash point:
228 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate, Methanol (Slightly)
form 
Oil
color 
Colourless liquid.
Odor
Powerful floral-green with a characteristic cucumber-melon note used in floral types.
Odor Type
floral
biological source
synthetic
Water Solubility 
66mg/L at 20℃
JECFA Number
1465
Stability:
Hygroscopic
LogP
3.4 at 35℃
CAS DataBase Reference
103-95-7(CAS DataBase Reference)
EPA Substance Registry System
Benzenepropanal, .alpha.-methyl-4-(1-methylethyl)- (103-95-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
MW4900000
HS Code 
29122990
Toxicity
The acute oral LD50 value in rats was reported as 3*81 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W274305
Product name
2-Methyl-3-(p-isopropylphenyl)propionaldehyde
Purity
≥95%, FCC, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W274305
Product name
2-Methyl-3-(p-isopropylphenyl)propionaldehyde
Purity
≥95%, FCC, FG
Packaging
1kg
Price
$139
Updated
2024/03/01
Sigma-Aldrich
Product number
W274305
Product name
2-Methyl-3-(p-isopropylphenyl)propionaldehyde
Purity
≥95%, FCC, FG
Packaging
5kg
Price
$511
Updated
2024/03/01
Sigma-Aldrich
Product number
S405361
Product name
3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE
Purity
Aldrich
Packaging
1g
Price
$179
Updated
2024/03/01
TCI Chemical
Product number
I0377
Product name
3-(4-Isopropylphenyl)isobutyraldehyde
Purity
>92.0%(GC)
Packaging
25mL
Price
$78
Updated
2024/03/01
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cyclamen aldehyde Chemical Properties,Usage,Production

Description

2-Methyl-3-(p-isopropylphenyl) propionaldehyde has a strong, flowery odor. May be prepared by condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst.

Chemical Properties

The commercially available racemate is a colorless to yellowish liquid with an intense floral odor reminiscent of Cyclamen europaeum (cyclamen, sowbread).
Production. Two main processes are used for the industrial synthesis of cyclamen aldehyde:
1) Alkaline condensation of 4-isopropylbenzaldehyde and propanal results, via the aldol, in the formation of 2-methyl-3-(4-isopropylphenyl)-2-propenal. The unsaturated aldehyde is hydrogenated selectively to the saturated aldehyde in the presence of potassium acetate and a suitable catalyst, such as palladium–alumina:
2) Friedel–Crafts reaction of isopropylbenzene and 2-methylpropenal diacetate (methacrolein diacetate) in the presence of titanium tetrachloride/boron trifluoride etherate gives cyclamen aldehyde enolacetate, which is hydrolyzed to aldehyde:
Uses. Cyclamen aldehyde is an important component for obtaining special blossomnotes in perfume compositions, particularly the cyclamen type. Because of its fresh, floral aspect, it is also used as the top note in many other blossomfragrances.

Chemical Properties

2-Methyl-3-(p-isopropylphenyl)-propionaldehyde has a strong, flowery odor

Occurrence

Reported found in nutmeg and starfruit.

Uses

Cyclamal, is an ingredient in perfume. It can also be used in the synthesis of Cyclamen Alcohol (C987655).

Uses

Cyclamen Aldehyde is a very powerful, floral, green note used in many perfumery applications to blend into fresh, floral, green or ozonic/marine accords. It is an ingredient with growing use and importance in helping to build replacement accords for materials disappearing from the Perfumers’ palette. Cyclamen has good overall stability except in extremes of pH. It has good tenacity and substantivity and represents very good value for money in new creations.In addition to its use in numerous perfume compositions, cyclamen aldehyde is an intermediate for the preparation of fungicides and fungistatic substances.

Definition

ChEBI: Xi-3-(4-Isopropylphenyl)-2-methylpropanal is a monoterpenoid.

Preparation

By condensation of cuminic aldehyde and propionaldehyde followed by hydrogenation in the presence of a catalyst

Safety Profile

Moderately toxic by ingestion. A human skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthesis

Cyclamen aldehyde is synthesized from Cuminaldehyde plus Ropionaldehyde by condensation followed by selective hydrogenation and finally dehydrogenation of the Cyclamen alcohol to aldehyde.

cyclamen aldehyde Preparation Products And Raw materials

Raw materials

Tropine Lily aldehyde Potassium hydroxide 2-Methylpropanedioic acid Sodium ethoxide tert-Butylbenzene PUMICE STONE trans-Cinnamic acid Titanium tetrachloride Isobutyraldehyde Diethyl malonate Cuminaldehyde trans-Cinnamaldehyde

Preparation Products

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View Lastest Price from cyclamen aldehyde manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
cyclamen aldehyde 103-95-7
Price
US $60.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-25
Hebei Mujin Biotechnology Co.,Ltd
Product
cyclamen aldehyde 103-95-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-22
Hebei Weibang Biotechnology Co., Ltd
Product
cyclamen aldehyde 103-95-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-05

103-95-7, cyclamen aldehydeRelated Search:

Loxoprofen Loxoprofen sodium cyclamen aldehyde Lily aldehyde Isobutyraldehyde Phenylpropyl aldehyde Propionaldehyde batridene 2-(4-TERT-BUTYL-PHENYL)-CYCLOPROPANECARBOXYLIC ACID RARECHEM AQ BC 9085 1-[6-HYDROXY-4-(4-ISOPROPYLPHENYL)-3,6-DIMETHYL-4,5,6,7-TETRAHYDRO-2,1-BENZISOXAZOL-5-YL]ETHANONE 2-(4-TERT-BUTYL-PHENYL)-CYCLOPROPANECARBOXYLIC ACID ETHYL ESTER RARECHEM AL BI 0264 AKOS B029667 AKOS B000951 1-[2-(4-ISOPROPYLPHENYL)CYCLOPROPYL]-1-ETHANONE RARECHEM DK HD C009 ETHYL 2-(2-(4-TERT-BUTYLPHENYL)CYCLOPROPANECARBOXAMIDO)-4,5,6,7-TETRAHYDROBENZO[B]THIOPHENE-3-CARBOXYLATE

  • (R,S)-p-Isopropyl-α-methylhydro-cinnamaldehyde
  • P-ISOPROPYL-A-METHYLHYDROCINNAMALDEHYDE
  • CYCLAMEN ALDEHYDE
  • FEMA 2743
  • 2-METHYL-3-(P-ISOPROPYLPHENYL)PROPION- &
  • 3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE
  • 4-ISOPROPYL-ALPHA-METHYLHYDROCINNAMALDEHYDE
  • A-METHYL-P-ISOPROPYLHYDROCINNAMIC ALDEHYDE
  • ALPHA-METHYL-P-ISOPROPYLHYDROCINNAMIC ALDEHYDE
  • 1-(4-ISOPROPYLPHENYL)-2-PROPANAL
  • 2-METHYL-3-(P-ISOPROPYLPHENYL)PROPIONALDEHYDE
  • 2-Methyl-3-(para-isopropyl phenyl)propionaldehyde
  • Alpha-methyl-p-isopropylphenylpropanaldehyde
  • Benzenepropanal, a-methyl-4-(1-methylethyl)-
  • .alpha.-methyl-4-(1-methylethyl)-Benzenepropanal
  • 3-(4-iso-Propylphenyl)-2-methylpropanal
  • 3-(4-Isopropylphenyl)-2-methylpropanal
  • 3-(p-Isopropylphenyl)isobutyraldehyde
  • 3-p-
  • 3-p-cumenyl-2
  • 3-p-cumenyl-2-
  • 3-p-cumenyl-2-methylpropionaldehyde
  • Aldehyde B
  • aldehydeb
  • alpha-methyl-4-(1-methylethyl)-benzenepropana
  • alpha-methyl-4-(1-methylethyl)benzenepropanal
  • alpha-Methyl-p-isopropylhydrocinnamaldehyde
  • Benzenepropanal, alpha-methyl-4-(1-methylethyl)-
  • Benzenepropanal,.alpha.-methyl-4-(1-methylethyl)-
  • beta-Methyl-p-iso-propyl phenyl propionaldehyde
  • Cyclamal
  • Hydrocinnamaldehyde, p-isopropyl-alpha-methyl-
  • -Methyl-4-(1-methylethyl)benzenepropanal
  • p-isopropyl-alpha-methyl-hydrocinnamaldehyd
  • p-Isopropyl-alpha-methylhydrocinnamaldehyde
  • p-Isopropyl-alpha-methylhydrocinnamic aldehyde
  • p-isopropyl-alpha-methylhydrocinnamicaldehyde
  • p-Isopropyl-alpha-methylphenylpropyl aldehyde
  • p-isopropyl-alpha-methylphenylpropylaldehyde
  • p-isopropyl-alpha-methylpropiophenaldehyde
  • p-iso-Propyl-methylhyrocinnamaldehyde
  • CYCLAMON ALDEHYDE EXTRA
  • Rabbit ears grass aldehyde
  • PARA-ISOPROPYL-ALPHA-METHYL-HYDROCINNAMALDEHYDE
  • 4-PROPYL-ALPHA-METHYLHYDROCINNAMALDEHYDE
  • 3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE 90+%
  • p-Isopropyl-α-methylpropiophenaldehyde
  • p-Isopropyl-α-methylhydrocinnamaldehyde
  • p-Isopropyl-α-methylphenylpropyl aldehyde
  • 4-Isopropyl-α-methylbenzenepropanal
  • 4-Isopropyl-α-methylhydrocinnamaldehyde
  • p-Isopropyl-α-methylbenzenepropionaldehyde
  • 2-methvl-3-(P-isopropylphenyl)-propionaldehyde
  • 3-(4-isopropylphenyl)butyraldehyde
  • 3-(4-propan-2-ylphenyl)butanal
  • 3-(4-ISOPROPYLPHENYL)-2-METHYLPROPIONALDEHYDE
  • Benzenepropanal, α-methyl-4-(1-methylethyl)-
  • 3-(4-ISOPROPYLPHENYL)ISOBUTYRALDEHYDE USP/EP/BP