(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE

ChemicalBook > CAS DataBase List > (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE

(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE

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Product Name: (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE
CAS No.: 851308-40-2
Chemical Name: (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE
Synonyms: r-np-xyl;(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]eth;(R)-1-[(R)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine;(R)-1-[(S)-2-(Di-1-naphtylphosphino)ferrocenyl]-ethyl-di-3,5-xylylphosphine;(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine;(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine >=97%;(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine,Min.97%;(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino) ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%;(2R)-1-[(1R)-1-[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE;(r,r)-1-{1-[bis(3,5-dimethylphenyl)phosphino]ethyl}-2-[di(1-naphthyl)phosphino]ferrocene (acc to cas)
CBNumber: CB2501536
Molecular Formula: C43H39P2.C5H5.Fe
Formula Weight: 738.669
MOL File: 851308-40-2.mol

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(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE Property

alpha: -163° ±10° (c 0.5, CHCl3)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: orange
CAS DataBase Reference: 851308-40-2

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Safety

WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 26-1175
Product name: (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%
Packaging: 100mg
Price: $107
Updated: 2024/03/01

Strem Chemicals

Product number: 26-1175
Product name: (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%
Packaging: 500mg
Price: $375
Updated: 2024/03/01

Strem Chemicals

Product number: 26-1175
Product name: (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%
Packaging: 2g
Price: $1031
Updated: 2024/03/01

Strem Chemicals

Product number: 26-1175
Product name: (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%
Packaging: 10g
Price: $4379
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CCH0004828
Product name: (R)-1-((SP)-2-(DI(1-NAPHTHYL)PHOSPHINO)FERROCENYL)ETHYLDI(3,5-XYLYL)PHOSPHINE
Purity: 95.00%
Packaging: 1G
Price: $1269.75
Updated: 2021/12/16

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(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE Chemical Properties,Usage,Production

Reactions

Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain.4 These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
Asymmetric hydrogenation of ketones and phosphinylketimines.
Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
Boration of α,α-unsaturated esters and nitriles.
Reaction of aryl halides with ammonia.
Cu-catalyzed reduction of activated C=C bonds with PMHS.
Regio- and enantioselective hydroboration of vinyl arenes.
Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE Suppliers

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View Lastest Price from (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE manufacturers

Career Henan Chemical Co

Product: r-np-xyl 851308-40-2
Price: US $3.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2020-03-13

851308-40-2, (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINERelated Search:

(S)-1-{(R)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLBIS(2-METHYLPHENYL)PHOSPHINE (R)-1-{(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}-ETHYLDI(3,5 (R)-1-[(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT (R)-1-[(S)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE (R)-1-{(S)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLBIS(2-METHYLPHENYL)PHOSPHINE (S)-1-[(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}-ETHYLDI(3,5 (AS,AS)-1,1#-BIS[<ALPHA>-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2#-BIS(DIPHENYLPHOSPHINO (S)-1-{(R)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE (S)-1-{(R)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE (S)-1-[(R)-2-(DI-TERT.-BUTYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE (R)-1-[(S)-2-(DI-TERT.-BUTYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE 1,3-Bis(diphenylphosphino)propane 1,6-Bis(diphenylphosphino)hexane 1,3-BIS(PHENYLPHOSPHINO)PROPANE (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE

r-np-xyl

1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1S)-1-[bis(3,5-dim ethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3 ,4,5-cyclopentanepentayl, iron salt (1:1:1)

(r,r)-1-{1-[bis(3,5-dimethylphenyl)phosphino]ethyl}-2-[di(1-naphthyl)phosphino]ferrocene (acc to cas)

(2R)-1-[(1R)-1-[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE

(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino) ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%

(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]eth

(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine,Min.97%

(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine

(R)-1-[(S)-2-(Di-1-naphtylphosphino)ferrocenyl]-ethyl-di-3,5-xylylphosphine

(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine >=97%

(R)-1-[(R)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine

851308-40-2

C48H44FeP2

Josiphos Series

Chiral Phosphine

Ferrocene Series

organometallic complex