DIETHYLALUMINUM CYANIDE SOLUTION

Product Name: DIETHYLALUMINUM CYANIDE SOLUTION
CAS No.: 5804-85-3
Chemical Name: DIETHYLALUMINUM CYANIDE SOLUTION
Synonyms: Einecs 227-359-8;(Cyano-C)diethyL;Cyanodiethylalane;Diethylcyanoaluminum;Cyanodiethylaluminum;(cyano-C)diethylaluminium;Aluminum, (cyano-kC)diethyl-;DIETHYLALUMINUM CYANIDE SOLUTION;Aluminum, (cyano-.kappa.C)diethyl-;Diethyl Aluminium Cyanide (1.0 M in Toluene)
CBNumber: CB2502593
Molecular Formula: C5H10AlN
Formula Weight: 111.121138
MOL File: 5804-85-3.mol

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DIETHYLALUMINUM CYANIDE SOLUTION Property

Boiling point:: 150 °C(Press: 0.07 Torr)
Density: 0.87 g/mL at 20 °C
Flash point:: 45 °F
solubility: solution in benzene, toluene, diisopropyl ether.
form: syrup
color: colorless
BRN: 3587410

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Safety

Hazard Codes: F,T+,N
Risk Statements: 11-26/27/28-32-38-48/20-50/53-63-65-67
Safety Statements: 36/37-45-60-61-62-28-16
RIDADR: UN 3123 6.1/PG 1
WGK Germany: 2
F: 10

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H311Toxic in contact with skin

H315Causes skin irritation

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 276863
Product name: Diethylaluminum cyanide solution
Purity: 1.0M in toluene
Packaging: 100ml
Price: $296
Updated: 2024/03/01

Sigma-Aldrich

Product number: 276863
Product name: Diethylaluminum cyanide solution
Purity: 1.0M in toluene
Packaging: 800ml
Price: $1570
Updated: 2024/03/01

Sigma-Aldrich

Product number: 276863
Product name: Diethylaluminum cyanide solution
Purity: 1.0 M in toluene
Packaging: 4x25ml
Price: $111.6
Updated: 2024/03/01

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DIETHYLALUMINUM CYANIDE SOLUTION Chemical Properties,Usage,Production

Uses

DIETHYLALUMINUM CYANIDE SOLUTION Reagents used to hydrocyanate side chain ketones directed by aryl sulfinyl groups.1

Application

Diethylaluminum Cyanide is used for hydrocyanation of α,β-unsaturated ketones;^[1] preparation of α-cyanohydrins from carbonyl compounds.^[2]

Preparation

Diethylaluminum Cyanide is prepared by reaction of Triethylaluminum with a slight excess of Hydrogen Cyanide below rt^[3].

storage

Diethylaluminum Cyanide is highly toxic. It can be stored as 1-2 M solutions in benzene, toluene, or diisopropyl ether. Use in a fume hood.

References

1. Nagata, W.; Yoshioka, M.; Hirai, S. JACS 1972, 94, 4635.
2. Agosta, W. C.; Lowrance, W. W., Jr. JOC 1970, 35, 3851.
3. Nagata, W.; Yoshioka, M. OR 1977, 25, 255.

DIETHYLALUMINUM CYANIDE SOLUTION Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYLALUMINUM CYANIDE SOLUTION Suppliers

China 21 India 1 Switzerland 1 United States 2 Global 25

Beijing HwrkChemical Technology Co., Ltd

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5804-85-3, DIETHYLALUMINUM CYANIDE SOLUTIONRelated Search:

Lithium Aluminum Hydride COPPER(II) SULFIDE Tetrapotassium hexacyanoferrate trihydrate Potassium cyanate ALUMINUM CARBIDE Cupric cyanide Triethylaluminum Aluminon BTS-CATALYST Dimethylaluminum hydride HYDROGEN CYANIDE Aluminium hydride Trimethylaluminium DIETHYLALUMINUM CYANIDE SOLUTION

D**Diethylaluminum cyanide solution, 1 M in toluene

Cyanodiethylalane

Aluminum, (cyano-kC)diethyl-

DIETHYLALUMINUM CYANIDE SOLUTION

(cyano-C)diethylaluminium

DIETHYLALUMINUM CYANIDE SOLUTION, ~1 M I N TOLUENE

DIETHYLALUMINUM CYANIDE, 1.0M SOLUTION I N TOLUENE

Aluminum, (cyano-.kappa.C)diethyl-

Cyanodiethylaluminum

Diethylcyanoaluminum

Einecs 227-359-8

Diethylaluminum cyanide solution technical, ~1 in tolu

Diethylaluminum cyanide solution 1.0 in toluene

(Cyano-C)diethyL

Diethylaluminum cyanide solution 1.0 M in toluene

Diethyl Aluminium Cyanide (1.0 M in Toluene)

5804-85-3

C5H10AlN

C2H52AlCN

Chemical Synthesis

Organometallic Reagents

Chemical Synthesis

Organoaluminum

Organometallic Reagents