METHYL ALPHA-BROMOPHENYL ACETATE

Product Name: METHYL ALPHA-BROMOPHENYL ACETATE
CAS No.: 704-65-4
Chemical Name: METHYL ALPHA-BROMOPHENYL ACETATE
Synonyms: 2-Acetoxybenzyl bromide;2-(Bromomethyl)phenyl acetate;2-Acetoxyphenylmethyl bromide;Phenol, 2-(bromomethyl)-, 1-acetate
CBNumber: CB2506566
Molecular Formula: C9H9BrO2
Formula Weight: 229.07
MOL File: 704-65-4.mol

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METHYL ALPHA-BROMOPHENYL ACETATE Property

storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: fused solid
color: White

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Safety

HS Code: 2915390090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B847225
Product name: 2-(Bromomethyl)phenylAcetate
Packaging: 100mg
Price: $200
Updated: 2021/12/16

Apolloscientific

Product number: OR400175
Product name: 2-(Bromomethyl)phenylacetate
Packaging: 500mg
Price: $203
Updated: 2021/12/16

Apolloscientific

Product number: OR400175
Product name: 2-(Bromomethyl)phenylacetate
Packaging: 1g
Price: $319
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-18
Product name: 2-(Bromomethyl)phenyl acetate
Packaging: 1g
Price: $352
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-18
Product name: 2-(Bromomethyl)phenyl acetate
Packaging: 500mg
Price: $224
Updated: 2021/12/16

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METHYL ALPHA-BROMOPHENYL ACETATE Chemical Properties,Usage,Production

Synthesis

533-18-6

704-65-4

General method: o-tolyl acetate (3.18 g, 15 mmol) and N-bromosuccinimide (2.67 g, 15 mmol) were dissolved in dry carbon tetrachloride (60 ml), and the reaction mixture was stirred for 1 hr under the irradiation of 150 W tungsten lamp. After completion of the reaction, the mixture was cooled to room temperature and the precipitated succinimide was removed by filtration. The filtrate was concentrated under reduced pressure to remove the solvent and the resulting crude product was purified by silica gel column chromatography using a solvent mixture of ethyl acetate with petroleum ether (60-80 °C boiling range, 10% v/v) as eluent to give phenyl 2-(bromomethyl)acetate (3a). It was further recrystallized from a mixed solvent of ethyl ether and petroleum ether (60-80 °C boiling range) to obtain colorless shiny granular crystals.

References

[1] Organic Letters, 2009, vol. 11, # 16, p. 3670 - 3673
[2] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993, # 12, p. 1359 - 1366
[3] Tetrahedron Letters, 2011, vol. 52, # 18, p. 2423 - 2423
[4] Inorganic Chemistry, 2017, vol. 56, # 1, p. 470 - 479
[5] Acta Chemica Scandinavica, 1997, vol. 51, # 12, p. 1162 - 1168

METHYL ALPHA-BROMOPHENYL ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL ALPHA-BROMOPHENYL ACETATE Suppliers

China 29 Germany 1 India 1 United Kingdom 1 United States 4 Global 36

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704-65-4, METHYL ALPHA-BROMOPHENYL ACETATERelated Search:

Vinyl acetate Zinc hydroxide

2-Acetoxybenzyl bromide

2-(Bromomethyl)phenyl acetate

Phenol, 2-(bromomethyl)-, 1-acetate

2-Acetoxyphenylmethyl bromide

704-65-4