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4-ETHOXYMETHYL-BENZOIC ACID

Product Name
4-ETHOXYMETHYL-BENZOIC ACID
CAS No.
146781-28-4
Chemical Name
4-ETHOXYMETHYL-BENZOIC ACID
Synonyms
4-(Ethoxymethyl);Benzoic acid, 4-(ethoxymethyl)-
CBNumber
CB2511423
Molecular Formula
C10H12O3
Formula Weight
180.2
MOL File
146781-28-4.mol
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4-ETHOXYMETHYL-BENZOIC ACID Property

Boiling point:
296.3±23.0 °C(Predicted)
Density 
1.143±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
4.22±0.10(Predicted)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S283428
Product name
4-ETHOXYMETHYL-BENZOIC ACID
Purity
AldrichCPR
Packaging
25MG
Price
$28.6
Updated
2023/06/20
TRC
Product number
E937508
Product name
4-ETHOXYMETHYL-BENZOIC ACID
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
E937508
Product name
4-ETHOXYMETHYL-BENZOIC ACID
Packaging
500mg
Price
$110
Updated
2021/12/16
Matrix Scientific
Product number
019003
Product name
4-Ethoxymethyl-benzoic acid
Packaging
500mg
Price
$79
Updated
2021/12/16
Matrix Scientific
Product number
019003
Product name
4-Ethoxymethyl-benzoic acid
Packaging
1g
Price
$129
Updated
2021/12/16
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4-ETHOXYMETHYL-BENZOIC ACID Chemical Properties,Usage,Production

Synthesis

2031-62-1

1571-08-0

146781-28-4

GENERAL STEPS: A dichloromethane solution (15 mL) of substrate (2 mmol, 1 eq.), pre-catalyst (0.04 mmol, 0.02 eq.), and methyl diethoxysilane (3 mmol, 1.5 eq.) was added to the Schlenk tube under argon protection (1 atm). The reaction mixture was allowed to react under light conditions for 4 hours. After completion of the reaction, the solvent was removed under reduced pressure and methanol (5 mL) and aqueous NaOH solution (2.5 M, 5 mL) were added to the residue and the resulting suspension was stirred overnight. Subsequently, the reaction mixture was neutralized with aqueous HCl (2 M, 30 mL) and brine (20 mL) and subjected to standard post-treatment to afford 4-ethoxymethylbenzoic acid as a yellow oil.

References

[1] Tetrahedron Letters, 2012, vol. 53, # 37, p. 5015 - 5018

4-ETHOXYMETHYL-BENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-ETHOXYMETHYL-BENZOIC ACID Suppliers

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