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4-Methyl-2-benzothiazolehydrazine

Uses
Product Name
4-Methyl-2-benzothiazolehydrazine
CAS No.
20174-68-9
Chemical Name
4-Methyl-2-benzothiazolehydrazine
Synonyms
4-METHYL-2-HYDRAZINO BENZOTHIAZOLE;2-Hydrazine-4-Methyl Benzo Thiazole;2-Hydrazine-4-Methyl;2-hydrazin-4-methylbenzothiazole;2-hydrazyl-4-methylbenzothiazole;4-Methyl-2-benzothiazolehydrazine;4-methyl-2-hydrazyl benzothiazole;4-methyl-2-hydrazinylbenzothiazole;(4-Methylbenzothiazol-2-yl)hydrazine;Benzothiazole,2-hydrazinyl-4-Methyl-
CBNumber
CB2511953
Molecular Formula
C8H9N3S
Formula Weight
179.24
MOL File
20174-68-9.mol
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4-Methyl-2-benzothiazolehydrazine Property

Melting point:
167-169 °C
Boiling point:
351.5±35.0 °C(Predicted)
Density 
1.44±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Store in freezer, under -20°C
pka
2.62±0.20(Predicted)
Appearance
Light brown to yellow Solid
CAS DataBase Reference
20174-68-9(CAS DataBase Reference)
EPA Substance Registry System
2(3H)-Benzothiazolone, 4-methyl-, hydrazone (20174-68-9)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
J53004
Product name
4-Methyl-2-benzothiazolehydrazine
Packaging
1g
Price
$15
Updated
2021/12/16
Matrix Scientific
Product number
136143
Product name
(4-Methyl-benzothiazol-2-yl)-hydrazine
Purity
95%+
Packaging
1g
Price
$350
Updated
2021/12/16
Matrix Scientific
Product number
136143
Product name
(4-Methyl-benzothiazol-2-yl)-hydrazine
Purity
95%+
Packaging
2.500g
Price
$762
Updated
2021/12/16
Matrix Scientific
Product number
136143
Product name
(4-Methyl-benzothiazol-2-yl)-hydrazine
Purity
95%+
Packaging
5g
Price
$1154
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0011975
Product name
4-METHYL-2-HYDRAZINO BENZOTHIAZOL
Purity
95.00%
Packaging
5G
Price
$1674.75
Updated
2021/12/16
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4-Methyl-2-benzothiazolehydrazine Chemical Properties,Usage,Production

Uses

2-Hydrazino-4-methylbenzothiazole is used in the synthesis of pesticides.

Uses

2-Hydrazino-4-methylbenzothiazole is used in the synthesis of pesticides.

Synthesis

1477-42-5

2644-70-4

20174-68-9

Example 16: Synthesis of 4-methyl-2-hydrazinylbenzothiazole 4-Methyl-2-aminobenzothiazole (8.21 g, 0.05 mol), hydrazine monohydrochloride (1.14 g, 0.017 mol), 85% hydrazine hydrate (1.96 g, 0.033 mol) and ethylene glycol (41 ml) were mixed under nitrogen protection. The reaction mixture was heated to 140°C and kept at this temperature for 15 hours. Upon completion of the reaction, the mixture was allowed to cool slowly to room temperature and allowed to stand overnight under nitrogen atmosphere. The following morning, water (45 mL) was added to the reaction mixture to promote crystallization. Subsequently, the mixture was filtered and the target product 4-methyl-2-hydrazinylbenzothiazole was isolated. The product was dried under vacuum at 60°C overnight to give a final 8.00 g in 89% yield with a melting point of 143°-151°C. The purity of the product was 85.8% as determined by non-aqueous titration.

References

[1] Patent: US3937714, 1976, A

4-Methyl-2-benzothiazolehydrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Methyl-2-benzothiazolehydrazine Suppliers

Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16075
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768836
Email
1791901229@qq.com
Country
China
ProdList
6950
Advantage
52
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
6387
Advantage
52
TaiZhou ZhiCheng Chemicals & Technology Co., LTD.
Tel
0523-82837785 13914525028
Fax
0523-87913272
Email
info@jszchg.com
Country
China
ProdList
246
Advantage
60
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View Lastest Price from 4-Methyl-2-benzothiazolehydrazine manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
4-Methyl-2-benzothiazolehydrazine 20174-68-9
Price
US $60.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-06-04
Hebei Yanxi Chemical Co., Ltd.
Product
4-Methyl-2-hydrazino benzothiazole 20174-68-9
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
20tons
Release date
2023-09-13
airuikechemical co., ltd.
Product
4-Methyl-2-benzothiazolehydrazine 20174-68-9
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.99%
Supply Ability
20 tons
Release date
2024-04-10

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