ChemicalBook > CAS DataBase List > SODIUM COBALTINITRITE

SODIUM COBALTINITRITE

Product Name
SODIUM COBALTINITRITE
CAS No.
13600-98-1
Chemical Name
SODIUM COBALTINITRITE
Synonyms
SODIUM CLORIDE;SODIUM HEXANITROCOBALTATE(III);SODIUM COBALTNITRITE;SODIUM HEXANITROCOBALTATE;SODIUM HEXANITRITOCOBALTATE(III);Sodium hexanitrocoba;SODIUM COBALTINITRITE;COBALT SODIUM NITRITE;Cobaltnitrite, Sodium;SodiumCobaltinitriteGr
CBNumber
CB2664428
Molecular Formula
CoN6NaO12(-2)
Formula Weight
357.95
MOL File
13600-98-1.mol
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SODIUM COBALTINITRITE Property

Melting point:
220 °C (dec.)(lit.)
storage temp. 
Store below +30°C.
solubility 
720g/l
form 
Solid
color 
Orange to orange-brown
Odor
Odorless
PH
5 (100g/l, H2O, 20℃)
Water Solubility 
Soluble in water
Merck 
13,8677
Stability:
Stable. Contact with conbustible material may cause fire. Incompatible with strong acids, organic materials, amines.
CAS DataBase Reference
13600-98-1(CAS DataBase Reference)
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Safety

Hazard Codes 
O,Xn
Risk Statements 
8-36/37/38-42/43-40
Safety Statements 
17-26-36/37
RIDADR 
UN 1479 5.1/PG 2
WGK Germany 
3
RTECS 
GF9480000
HazardClass 
5.1
PackingGroup 
II
HS Code 
28429090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
233722
Product name
Sodium hexanitrocobaltate(III)
Purity
ACS reagent
Packaging
100g
Price
$187
Updated
2024/03/01
Sigma-Aldrich
Product number
233722
Product name
Sodium hexanitrocobaltate(III)
Purity
ACS reagent
Packaging
500g
Price
$636
Updated
2024/03/01
Sigma-Aldrich
Product number
1.02521
Product name
Sodium hexanitrocobaltate(III)
Purity
[sodium cobalt(III)nitrite] for analysis EMSURE? ACS,Reag. Ph Eur
Packaging
25g
Price
$128
Updated
2024/03/01
Sigma-Aldrich
Product number
1.02521
Product name
Sodium hexanitrocobaltate(III)
Purity
[sodium cobalt(III)nitrite] for analysis EMSURE? ACS,Reag. Ph Eur
Packaging
100g
Price
$257
Updated
2024/03/01
Strem Chemicals
Product number
93-1056
Product name
Sodium hexanitritocobaltate(III), (ACS)
Packaging
50g
Price
$123
Updated
2024/03/01
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SODIUM COBALTINITRITE Chemical Properties,Usage,Production

Chemical Properties

SODIUM COBALTINITRITE is deep yellow to brown crystalline powder

Uses

SODIUM COBALTINITRITE is used in the detection Potassium.

Uses

For the detection of potassium with which it forms a slightly soluble compound.

Uses

Nitrosation reagent for the conversion of aromatic amines to 1,3-diaryltriazenes with excellent yield.1

Preparation

Sodiumhexanitrocobaltate(III) ("sodiumcobaltinitrite") Na3Co(N02)6 is a well-known orange solid which precipitates potassium ions from aqueous solution as K3Co(NO2)6. It is prepared by blowing air through a mixture of cobalt(II) nitrate and sodium nitrite solutions in the presence of acetic acid:
2[Co(H20)6]2+ +12NO2- +2CH3COOH + 1/2O2 → 2[Co(NO)2)6]3- +2CH3COO-+ 13H2O
after filtration of any precipitated potassium or ammonium salts, the sodium salt is precipitated by the addition of ethanol.

Purification Methods

Dissolve the salt (ca 60g) in H2O (300mL), filter to obtain a clear solution, add 96% EtOH (250mL) with vigorous stirring. Allow the precipitate to settle for 2hours, filter it off, wash it with EtOH (4 x 25mL), twice with Et2O and dry it in air [Glemser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1541 1965]. It forms yellow to brown crystals which are very soluble in H2O, are decomposed by acid and form an insoluble K salt. Used for estimating potassium.

SODIUM COBALTINITRITE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from SODIUM COBALTINITRITE manufacturers

Career Henan Chemical Co
Product
SODIUM COBALTINITRITE 13600-98-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons
Release date
2020-02-01

13600-98-1, SODIUM COBALTINITRITERelated Search:


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  • CoN6Na3O12