CALCIUM NITRIDE

Product Name: CALCIUM NITRIDE
CAS No.: 12013-82-0
Chemical Name: CALCIUM NITRIDE
Synonyms: metalsbasis);CALCIUM NITRIDE;tricalcium dinitride;calciumnitride(ca3n2);CalciuM nitride (99%-Ca);Calciumnitride,(metals basis);CALCIUM NITRIDE, -200 MESH, 99%;Calcium nitride, 99% (metals basis);CalciuM nitride powder, -200 Mesh, 99% trace Metals basis (contains <0.5% Mg);CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%
CBNumber: CB2672982
Molecular Formula: Ca3N2
Formula Weight: 148.25
MOL File: 12013-82-0.mol

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CALCIUM NITRIDE Property

Melting point:: 1195°C
Boiling point:: 1195 °C
Density: 2.63 g/mL at 25 °C(lit.)
solubility: soluble in H2O, acid solutions; insoluble in ethanol
form: Pieces
Specific Gravity: 2.63
color: Brown
Water Solubility: Insoluble in water.
Sensitive: Moisture Sensitive
InChIKey: DVJMVZQXJNJSJR-UHFFFAOYSA-N
CAS DataBase Reference: 12013-82-0(CAS DataBase Reference)
EPA Substance Registry System: Calcium nitride (Ca3N2) (12013-82-0)

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Safety

Hazard Codes: F,C
Risk Statements: 11-29-34
Safety Statements: 16-22-26-36/37/39-45
RIDADR: UN 3208 4.3/PG 1
WGK Germany: 3
TSCA: Yes
HazardClass: 4.1
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H260In contact with water releases flammable gases which may ignite spontaneously

H314Causes severe skin burns and eye damage

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 415103
Product name: Calcium nitride
Purity: 200 mesh, 95%
Packaging: 25g
Price: $485
Updated: 2023/06/20

Sigma-Aldrich

Product number: 415103
Product name: Calcium nitride
Purity: 200 mesh, 95%
Packaging: 100g
Price: $1490
Updated: 2023/06/20

Alfa Aesar

Product number: 013124
Product name: Calcium nitride, 99% (metals basis)
Packaging: 50g
Price: $429
Updated: 2024/03/01

Alfa Aesar

Product number: 013124
Product name: Calcium nitride, 99% (metals basis)
Packaging: 5g
Price: $53.8
Updated: 2023/06/20

Strem Chemicals

Product number: 20-2025
Product name: Calcium nitride (99%-Ca)
Packaging: 5g
Price: $85
Updated: 2024/03/01

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CALCIUM NITRIDE Chemical Properties,Usage,Production

Description

Calcium nitride has the formula of Ca3N2 and the molecular weight of grams per mole. It can be prepared by the reactionofCametal inapure streamof nitrogen gas:
3Ca + 2N2 ? Ca3N2
A second method is the decomposition of an amide:
3Ca(NH2)2 + heat ? Ca3N2 + 4NH3
This must be accomplished in an inert atmosphere (not nitrogen gas). It is a reddish-brown powder. Its CAS number is 12013-82-0 and its density is 2.76 g/ cm³. It melts at 1195 °C (2183 F).α-Calcium nitride is the commonly encountered form. It has an antibixbyite structure similar to Mn2O3, except that the positions of the ions are reversed: calcium (Ca²⁺) ions take the oxide (O^2-) positions and nitride ions (N^3-) that of the manganese (Mn³⁺). If Ca metal is burned in air, it forms the oxide, CaO, and the nitride, Ca3N2. The latter reacts with atmospheric moisture to produce the hydroxide of calcium and ammonia:
Ca3N2 + 6H2O ? 3Ca(OH)2 + 2NH3

Chemical Properties

12mm pieces and smaller, -200 mesh 99% pure; brown crystal(s); hex: a=0.3533nm, c=0.411 nm; cub: a=1.138 nm [CIC73] [CER91]

Uses

Recent advances in the utilization of single crystals for a wide variety of purposes, especially in various electronic surveillance and detection applications, has generated considerable research in the development of improved techniques for growing single crystalline materials. A problem has arisen, however, in that many of the methods relied upon heretofore fail to growcrystals having a reproducibly high quality. Calcium nitride as a high temperature solvent has been used in the recrystallization of refractory aluminum nitride, that is growing single crystals of aluminum nitride from a molten solution containing the refractory material as the solute, and calcium nitride as the solvent. Crystallization is accomplished by the precipitation or crystallization of the solute, the solute being the desired crystal, from the molten solution.

Uses

Calcium nitride is used in the production of light-emitting diode (LED) phosphors.

Uses

Calcium nitride is used as a nitride source in metathesis reactions to produce complex nitrides as well as SiAlON-related optical materials.

CALCIUM NITRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CALCIUM NITRIDE Suppliers

China 56 Germany 1 India 1 Japan 1 Switzerland 1 United Kingdom 4 United States 16 Global 80

J & K SCIENTIFIC LTD.

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Sigma-Aldrich

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12013-82-0, CALCIUM NITRIDERelated Search:

PRASEODYMIUM(III) NITRIDE YTTRIUM NITRIDE cerium nitride YTTERBIUM NITRIDE GALLIUM NITRIDE LANTHANUM(III) NITRIDE EUROPIUM NITRIDE STRONTIUM NITRIDE NEODYMIUM(III) NITRIDE CHROMIUM NITRIDE TITANIUM NITRIDE LITHIUM NITRIDE Magnesium nitride DYSPROSIUM NITRIDE Aluminum nitride triberyllium nitride ERBIUM NITRIDE CALCIUM NITRIDE

Calciumnitride,(metals basis)

CalciuM nitride (99%-Ca)

CalciuM nitride powder, -200 Mesh, 99% trace Metals basis (contains <0.5% Mg)

CALCIUM NITRIDE

CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%

calciumnitride(ca3n2)

Calcium nitride, 99% (metals basis)

tricalcium dinitride

CALCIUM NITRIDE, -200 MESH, 99%

metalsbasis)

12013-82-0

Ca3N2

Ceramics

Metal and Ceramic Science

Nitrides