ChemicalBook > CAS DataBase List > CALCIUM NITRIDE

CALCIUM NITRIDE

Product Name
CALCIUM NITRIDE
CAS No.
12013-82-0
Chemical Name
CALCIUM NITRIDE
Synonyms
metalsbasis);CALCIUM NITRIDE;tricalcium dinitride;calciumnitride(ca3n2);CalciuM nitride (99%-Ca);Calciumnitride,(metals basis);CALCIUM NITRIDE, -200 MESH, 99%;Calcium nitride, 99% (metals basis);CalciuM nitride powder, -200 Mesh, 99% trace Metals basis (contains <0.5% Mg);CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%
CBNumber
CB2672982
Molecular Formula
Ca3N2
Formula Weight
148.25
MOL File
12013-82-0.mol
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CALCIUM NITRIDE Property

Melting point:
1195°C
Boiling point:
1195 °C
Density 
2.63 g/mL at 25 °C(lit.)
solubility 
soluble in H2O, acid solutions; insoluble in ethanol
form 
Pieces
Specific Gravity
2.63
color 
Brown
Water Solubility 
Insoluble in water.
Sensitive 
Moisture Sensitive
InChIKey
DVJMVZQXJNJSJR-UHFFFAOYSA-N
CAS DataBase Reference
12013-82-0(CAS DataBase Reference)
EPA Substance Registry System
Calcium nitride (Ca3N2) (12013-82-0)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-29-34
Safety Statements 
16-22-26-36/37/39-45
RIDADR 
UN 3208 4.3/PG 1
WGK Germany 
3
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H260In contact with water releases flammable gases which may ignite spontaneously

H314Causes severe skin burns and eye damage

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
415103
Product name
Calcium nitride
Purity
200 mesh, 95%
Packaging
25g
Price
$485
Updated
2023/06/20
Sigma-Aldrich
Product number
415103
Product name
Calcium nitride
Purity
200 mesh, 95%
Packaging
100g
Price
$1490
Updated
2023/06/20
Alfa Aesar
Product number
013124
Product name
Calcium nitride, 99% (metals basis)
Packaging
50g
Price
$429
Updated
2024/03/01
Alfa Aesar
Product number
013124
Product name
Calcium nitride, 99% (metals basis)
Packaging
5g
Price
$53.8
Updated
2023/06/20
Strem Chemicals
Product number
20-2025
Product name
Calcium nitride (99%-Ca)
Packaging
5g
Price
$85
Updated
2024/03/01
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CALCIUM NITRIDE Chemical Properties,Usage,Production

Description

Calcium nitride has the formula of Ca3N2 and the molecular weight of grams per mole. It can be prepared by the reactionofCametal inapure streamof nitrogen gas:
3Ca + 2N2 ? Ca3N2
A second method is the decomposition of an amide:
3Ca(NH2)2 + heat ? Ca3N2 + 4NH3
This must be accomplished in an inert atmosphere (not nitrogen gas). It is a reddish-brown powder. Its CAS number is 12013-82-0 and its density is 2.76 g/ cm3. It melts at 1195 °C (2183 F).α-Calcium nitride is the commonly encountered form. It has an antibixbyite structure similar to Mn2O3, except that the positions of the ions are reversed: calcium (Ca2+) ions take the oxide (O2-) positions and nitride ions (N3-) that of the manganese (Mn3+). If Ca metal is burned in air, it forms the oxide, CaO, and the nitride, Ca3N2. The latter reacts with atmospheric moisture to produce the hydroxide of calcium and ammonia:
Ca3N2 + 6H2O ? 3Ca(OH)2 + 2NH3

Chemical Properties

12mm pieces and smaller, -200 mesh 99% pure; brown crystal(s); hex: a=0.3533nm, c=0.411 nm; cub: a=1.138 nm [CIC73] [CER91]

Uses

Recent advances in the utilization of single crystals for a wide variety of purposes, especially in various electronic surveillance and detection applications, has generated considerable research in the development of improved techniques for growing single crystalline materials. A problem has arisen, however, in that many of the methods relied upon heretofore fail to growcrystals having a reproducibly high quality. Calcium nitride as a high temperature solvent has been used in the recrystallization of refractory aluminum nitride, that is growing single crystals of aluminum nitride from a molten solution containing the refractory material as the solute, and calcium nitride as the solvent. Crystallization is accomplished by the precipitation or crystallization of the solute, the solute being the desired crystal, from the molten solution.

Uses

Calcium nitride is used in the production of light-emitting diode (LED) phosphors.

Uses

Calcium nitride is used as a nitride source in metathesis reactions to produce complex nitrides as well as SiAlON-related optical materials.

CALCIUM NITRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CALCIUM NITRIDE Suppliers

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12013-82-0, CALCIUM NITRIDERelated Search:


  • Calciumnitride,(metals basis)
  • CalciuM nitride (99%-Ca)
  • CalciuM nitride powder, -200 Mesh, 99% trace Metals basis (contains <0.5% Mg)
  • CALCIUM NITRIDE
  • CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%CALCIUM NITRIDE, 99%
  • calciumnitride(ca3n2)
  • Calcium nitride, 99% (metals basis)
  • tricalcium dinitride
  • CALCIUM NITRIDE, -200 MESH, 99%
  • metalsbasis)
  • 12013-82-0
  • Ca3N2
  • Ceramics
  • Metal and Ceramic Science
  • Nitrides