Reaction
ChemicalBook > CAS DataBase List > (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

Reaction
Product Name
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
CAS No.
494227-35-9
Chemical Name
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
Synonyms
MANDYPHOS SL-M002-1;(R)-(S)-NMe2-Pcy2-Mandyphos;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA;(R,R)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc;(R,R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(SP,SμP)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(SP,S′P)-1,1′-Bis(dicyclohexylphosphino)-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis(dicyclohexylphosphino)ferrocene;(1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene;(SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene
CBNumber
CB2677457
Molecular Formula
C52H72FeN2P2
Formula Weight
842.95
MOL File
494227-35-9.mol
More
Less

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Property

alpha 
+54.6° (c 1.0, CHCl3)
form 
solid
color 
orange-red
Stability:
store cold
CAS DataBase Reference
494227-35-9
More
Less

Safety

WGK Germany 
3
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Strem Chemicals
Product number
26-0240
Product name
(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
26-0240
Product name
(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
26-0240
Product name
(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging
2g
Price
$1207
Updated
2024/03/01
Strem Chemicals
Product number
26-0240
Product name
(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging
10g
Price
$4824
Updated
2024/03/01
AK Scientific
Product number
7420AJ
Product name
(alphaR,alphaR)-2,2'-Bis(alpha-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(dicyclohexylphosphino)ferrocene
Packaging
10g
Price
$4902
Updated
2021/12/16
More
Less

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Chemical Properties,Usage,Production

Reaction

Ligand for a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ketones. Ligand for gold catalyzed Phenol synthesis from furyldialkyne
Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [(η6-benzylamine)Cr(CO)3]

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
Zhengzhou HQ Material Co., Ltd.
Tel
0371-67759225 13526468238
Fax
+86-37155919558
Email
sales@hqmat.com
Country
China
ProdList
525
Advantage
60
Sinocompound Catalysts Co., Ltd.
Tel
0512-67216630 18962121273
Fax
0512-56316689
Email
sales@sinocompound.com
Country
China
ProdList
278
Advantage
64
Shaanxi Rock New Materials Co., Ltd.
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Country
China
ProdList
310
Advantage
62
Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
351
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Zhengzhou HQ Material Co., Ltd.
Tel
0371-67759225 13526468238
Fax
0371-55919558
Email
sales@hqmat.com
Country
China
ProdList
471
Advantage
55
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
953
Advantage
55
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2654
Advantage
58
More
Less

View Lastest Price from (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE manufacturers

Career Henan Chemical Co
Product
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 494227-35-9
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kgs
Release date
2020-01-10

494227-35-9, (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENERelated Search:


  • MANDYPHOS SL-M002-1
  • (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
  • (R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA
  • (S,S)-(+)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
  • (R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
  • (<alpha>R,<alpha>R)-1,1#-Bis[<alpha>-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc
  • (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,min.97%
  • (r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis(dicyclohexylphosphino)ferrocene (acc to cas)
  • (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis(dicyclohexylphosphino)ferrocene
  • (SP,SμP)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene
  • Mandyphos SL-M002-1, (1R,1μRμ)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)
  • (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene, min. 97%
  • (1R,1′R′)-1,1′-Bis(dicyclohexylphosphino)-2,2′-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)
  • (R)-(S)-NMe2-Pcy2-Mandyphos
  • (αR,αR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1′-bis(dicyclohexyphosphino)ferrocene
  • (aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(dicyclohexylphosphino)ferrocene
  • (aR,aR)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(dicyclohexylphosphino)-ferrocene
  • (1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
  • (SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene >=97%
  • (S,S)Fc-1,1’-Bis(dicyclohexylphosphino)-2,2’-bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]ferrocene
  • (SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene
  • (SP,S′P)-1,1′-Bis(dicyclohexylphosphino)-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene
  • (1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
  • (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene
  • (R,R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene
  • 494227-35-9
  • C54H74FeN2P2
  • C52H74FeN2P2
  • Privileged Ligands
  • Solvias Ligands
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Chiral Phosphine
  • Ferrocene Series
  • Mandyphos Series