3-Amino-4-methylphenol

Product Name: 3-Amino-4-methylphenol
CAS No.: 2836-00-2
Chemical Name: 3-Amino-4-methylphenol
Synonyms: 3-amino-p-cresol;Phenol, 3-amino-4-methyl-;m-Amino-p-cresol; p-Cresol, 3-amino-;5-Hydroxy-o-toluidine;3-AMINO-4-METHYLPHENOL;3-azanyl-4-methyl-phenol;2-AMINO-4-HYDROXYTOLUENE;5-Hydroxy-2-methylaniline;3-Amino-4-Methylphenol 98%
CBNumber: CB2679714
Molecular Formula: C7H9NO
Formula Weight: 123.15
MOL File: 2836-00-2.mol

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3-Amino-4-methylphenol Property

Melting point:: 156-157°C
Boiling point:: 229.26°C (rough estimate)
Density: 1.0877 (rough estimate)
refractive index: 1.5706 (estimate)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: powder to crystal
pka: 10.32±0.18(Predicted)
color: Light yellow to Brown to Dark green
CAS DataBase Reference: 2836-00-2(CAS DataBase Reference)
EPA Substance Registry System: 3-Amino-4-methylphenol (2836-00-2)

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Safety

Hazard Codes: Xi
Hazard Note: Irritant
HS Code: 2922290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: A3180
Product name: 3-Amino-4-methylphenol
Purity: >98.0%(GC)
Packaging: 1g
Price: $60
Updated: 2025/07/31

TCI Chemical

Product number: A3180
Product name: 3-Amino-4-methylphenol
Purity: >98.0%(GC)
Packaging: 5g
Price: $180
Updated: 2025/07/31

AK Scientific

Product number: J92143
Product name: 3-Amino-4-methylphenol
Packaging: 1g
Price: $20
Updated: 2021/12/16

Apolloscientific

Product number: OR7735
Product name: 2-Amino-4-hydroxytoluene
Packaging: 250mg
Price: $22
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4756-1-W2
Product name: 2-Amino-4-hydroxytoluene
Packaging: 250mg
Price: $24
Updated: 2021/12/16

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3-Amino-4-methylphenol Chemical Properties,Usage,Production

General Description

Crystals.

Air & Water Reactions

3-Amino-4-methylphenol may be sensitive to prolonged exposure to air.

Reactivity Profile

3-Amino-4-methylphenol reacts with strong oxidizing agents.

Fire Hazard

Flash point data for 3-Amino-4-methylphenol are not available. 3-Amino-4-methylphenol is probably combustible.

Synthesis

2042-14-0

2836-00-2

The general procedure for the synthesis of 3-amino-4-methylphenol from 4-methyl-3-nitrophenol was as follows: 4-methyl-3-nitrophenol (77 mg, 0.50 mmol), Fe nanoparticles (6 mg), and NaBH4 (29 mg, 0.75 mmol) were placed in 1.0 mL of 2 wt. % TPGS/H2O solution, and the reaction was carried out for 2 h at room temperature. Upon completion of the reaction, 56 mg (91% yield) of 3-amino-4-methylphenol was obtained as a white solid (hexane/ethyl acetate = 50:50). The melting point of the product was 154°C-156°C. It was analyzed by GC-MS with m/z of 123 [M], and the spectral data were consistent with those reported in the literature.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2011, vol. 21, # 1, p. 240 - 244
[2] Green Chemistry, 2017, vol. 19, # 3, p. 809 - 815
[3] Journal of Medicinal Chemistry, 2010, vol. 53, # 5, p. 1964 - 1978
[4] ACS Catalysis, 2017, vol. 7, # 4, p. 2412 - 2418
[5] Patent: WO2018/208132, 2018, A1. Location in patent: Paragraph 704-708

3-Amino-4-methylphenol Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Amino-4-methylphenol Suppliers

Americas 1 China 157 Europe 2 Germany 2 India 3 Japan 1 United Kingdom 8 United States 18 Global 192

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View Lastest Price from 3-Amino-4-methylphenol manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: p-Cresol, 3-amino- 2836-00-2
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 1000kg
Release date: 2025-09-09

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 3-Amino-4-methylphenol 2836-00-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-24

Hebei Chuanghai Biotechnology Co., Ltd

Product: 3-Amino-4-methylphenol 2836-00-2
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-12

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