Indole-6-boronic acid pinacol ester

Product Name: Indole-6-boronic acid pinacol ester
CAS No.: 642494-36-8
Chemical Name: Indole-6-boronic acid pinacol ester
Synonyms: 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole;INDOLE-6-BORONIC ACID PINACOLATE;INDOLE-6-BORONIC ACID PINACOL ESTER;Indole-6-yl-boronic acid pinacol ester;1H-Indol-6-ylboronic acid, pinacol ester;Indole-6-boronic acid, pinacol ester 95+%;Indole-6-boronic acid pinacol ester - [I12491];(1H-INDOL-6-YL)BORONIC ACID PINACOL ESTER 97%;6-(tetraMethyl-1,3,2-dioxaborolan-2-yl)-1H-indole;1H-Indole, 6-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-
CBNumber: CB2690636
Molecular Formula: C14H18BNO2
Formula Weight: 243.11
MOL File: 642494-36-8.mol

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Indole-6-boronic acid pinacol ester Property

Melting point:: 167-172 °C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Light brown to brown Solid
InChI: InChI=1S/C14H18BNO2/c1-13(2)14(3,4)18-15(17-13)11-6-5-10-7-8-16-12(10)9-11/h5-9,16H,1-4H3
InChIKey: VNDFXJNIKZCQRY-UHFFFAOYSA-N
SMILES: B1(C2C=CC3C=CNC=3C=2)OC(C)(C)C(C)(C)O1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: I577783
Product name: Indole-6-boronicacid,pinacolester
Packaging: 250mg
Price: $55
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H60-1-10
Product name: 1H-Indol-6-ylboronic acid, pinacol ester
Purity: 98%
Packaging: 250mg
Price: $25
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H60-1-10
Product name: 1H-Indol-6-ylboronic acid, pinacol ester
Purity: 98%
Packaging: 1g
Price: $85
Updated: 2021/12/16

Synthonix

Product number: I12491
Product name: Indole-6-boronicacidpinacolester
Purity: 95+%
Packaging: 1g
Price: $110
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0003711
Product name: INDOLE-6-BORONIC ACID PINACOL ESTER
Purity: 95.00%
Packaging: 1G
Price: $315
Updated: 2021/12/16

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Indole-6-boronic acid pinacol ester Chemical Properties,Usage,Production

Uses

Indole-6-boronic acid, pinacol ester

Synthesis

52415-29-9

73183-34-3

642494-36-8

Under nitrogen protection, 6-bromo-1H-indole (25 g, 0.128 mol), pinacol ester of bisboronic acid (48.58 g, 0.191 mol), Pd(dppf)Cl2 (5.2 g, 5 mol%) and KOAc (37.55 g, 0.383 mol) were dissolved in DMF (500 ml). The reaction mixture was stirred at 120°C for several hours. After completion of the reaction, extraction was carried out with ethyl acetate and the organic phase was dried with magnesium sulfate. Purification by column chromatography (eluent: hexane/ethyl acetate=10:1, v/v) afforded 6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole (20.15 g, 65% yield).

References

[1] Journal of the American Chemical Society, 2017, vol. 139, # 24, p. 8267 - 8276
[2] Synlett, 2003, # 8, p. 1204 - 1206
[3] Patent: JP2015/531758, 2015, A. Location in patent: Paragraph 0045-0046
[4] Patent: US2007/112005, 2007, A1. Location in patent: Page/Page column 82
[5] Patent: US2007/280928, 2007, A1. Location in patent: Page/Page column 80

Indole-6-boronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

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Indole-6-boronic acid pinacol ester Suppliers

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SynAsst Chemical.

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View Lastest Price from Indole-6-boronic acid pinacol ester manufacturers

Career Henan Chemical Co

Product: Indole-6-boronic acid pinacol ester 642494-36-8
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%min
Supply Ability: 300kg
Release date: 2020-03-06

Career Henan Chemical Co

Product: Indole-6-boronic acid pinacol ester 642494-36-8
Price: US $6.60/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg -1000kg
Release date: 2020-01-02

642494-36-8, Indole-6-boronic acid pinacol esterRelated Search:

Indole-3-butyric acid Methyl acrylate Indometacin Tris(trimethylsilyl)phosphate Indole-3-acetic acid Bis(pinacolato)diboron Indole-6-boronic acid 1H-Indole-7-boronic acid, pinacol ester,INDOLE-7-BORONIC ACID PINACOL ESTER 2-(Pinacolateboryl)indole INDOLE-7-METHANOL INDOLE-7-BORONIC ACID Ethyl 1H-indole-6-carboxylate INDOLE-2,5-DICARBOXYLIC ACID 2-ETHYL ESTER 5-METHYL ESTER Indole-5-carboxylic acid Methyl indole-5-carboxylate Indole-4-carboxylic acid 3-Indolepropionic acid 3-Indoleacetonitrile

INDOLE-6-BORONIC ACID PINACOLATE

INDOLE-6-BORONIC ACID PINACOL ESTER

6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole

6-(tetraMethyl-1,3,2-dioxaborolan-2-yl)-1H-indole

1H-Indole, 6-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-

3-hydroxy-2,3-dimethylbutan-2-yl hydrogen 1H-indol-6-ylboronate

Indole-6-yl-boronic acid pinacol ester

Indole-6-boronic acid, pinacol ester 95+%

1H-Indol-6-ylboronic acid, pinacol ester

(1H-INDOL-6-YL)BORONIC ACID PINACOL ESTER 97%

Indole-6-boronic acid pinacol ester - [I12491]

642494-36-8

Indole/indoline/oxindole