ChemicalBook > CAS DataBase List > 4-Methylbenzyl alcohol

4-Methylbenzyl alcohol

Product Name
4-Methylbenzyl alcohol
CAS No.
589-18-4
Chemical Name
4-Methylbenzyl alcohol
Synonyms
Benzenemethanol, 4-methyl-;METHYLBENZYL ALCOHOL;p-methyl-benzylalcoho;p-Toluyl alcohol;PMAL;p-Tolymethanol;p-methylbenzyl;P-TOLYLCARBINOL;p-Tolyl-methanol;4-TOLYL CARBINOL
CBNumber
CB2694649
Molecular Formula
C8H10O
Formula Weight
122.16
MOL File
589-18-4.mol
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4-Methylbenzyl alcohol Property

Melting point:
59-61 °C(lit.)
Boiling point:
217 °C(lit.)
Density 
0,98 g/cm3
vapor pressure 
1.6Pa at 25℃
refractive index 
1.5265 (estimate)
FEMA 
4624 | 4-METHYLBENZYL ALCOHOL
Flash point:
116-118°C/20mm
storage temp. 
Sealed in dry,Room Temperature
form 
Crystalline Mass, Needles, or Crystals
pka
14.49±0.10(Predicted)
color 
White
Odor
mild floral
Odor Type
floral
Water Solubility 
Soluble in methanol, ether and ethanol. Slightly soluble in water.
JECFA Number
2065
BRN 
1856550
LogP
1.67 at 20℃
CAS DataBase Reference
589-18-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanol, 4-methyl-(589-18-4)
EPA Substance Registry System
4-Methylbenzenemethanol (589-18-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
2
RTECS 
DO9370000
TSCA 
Yes
HS Code 
29062990
Hazardous Substances Data
589-18-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
127809
Product name
4-Methylbenzyl alcohol
Purity
98%
Packaging
5g
Price
$29.3
Updated
2024/03/01
Sigma-Aldrich
Product number
127809
Product name
4-Methylbenzyl alcohol
Purity
98%
Packaging
25g
Price
$66.7
Updated
2024/03/01
TCI Chemical
Product number
M0162
Product name
4-Methylbenzyl Alcohol
Purity
>99.0%(GC)
Packaging
25g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
M0162
Product name
4-Methylbenzyl Alcohol
Purity
>99.0%(GC)
Packaging
100g
Price
$123
Updated
2024/03/01
Alfa Aesar
Product number
A15315
Product name
4-Methylbenzyl alcohol, 99%
Packaging
25g
Price
$43.65
Updated
2024/03/01
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4-Methylbenzyl alcohol Chemical Properties,Usage,Production

Chemical Properties

white crystalline mass, needles or crystals

Uses

Perfumery, flavoring dyes, laboratory reagent.

Uses

4-Methylbenzyl alcohol is used in fragrances, flavoring and as a laboratory reagent. It is also used as a raw material for the preparation of polycarbonates and 4-methyl-benzaldehyde.

Production Methods

p-Tolyl alcohol is commercially prepared by reducing p-tolyl aldehyde. It is used mainly in fragrances, and the major route of exposure is likely to be dermal contact.

Definition

ChEBI: A methylbenzyl alcohol in which the methyl substituent is para to the hydroxymethyl group.

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 946, 1987 DOI: 10.1021/jo00381a047

General Description

Needles or off-white crystalline powder.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

4-Methylbenzyl alcohol can react with acids, acid chlorides, acid anhydrides and oxidizing agents.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition 4-Methylbenzyl alcohol emits acrid smoke and toxic fumes of carbon monoxide and carbon dioxide.

Fire Hazard

Flash point data for 4-Methylbenzyl alcohol are not available. 4-Methylbenzyl alcohol is probably combustible.

Flammability and Explosibility

Not classified

Purification Methods

Crystallise the alcohol from pet ether (b 80-100o, 1g/mL), Et2O, pentane or H2O (m 61-62.1o). It can also be distilled in a vacuum. [Beilstein 6 H 498, 6 I 248, 6 II 469, 6 III 1779.]

4-Methylbenzyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Methylbenzyl alcohol Suppliers

Americas 1 Belgium 4 Canada 1 China 269 Europe 2 France 1 Germany 6 India 15 Japan 6 Slovakia 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 10 United States 45 Global 365
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View Lastest Price from 4-Methylbenzyl alcohol manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
4-Methylbenzyl Alcohol 589-18-4
Price
US $180.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-30
Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
p-tolylmethanol 589-18-4
Price
US $15.00/kg
Min. Order
1kg
Purity
99.912%
Supply Ability
10ton
Release date
2024-04-24
Hebei Mojin Biotechnology Co., Ltd
Product
4-Methylbenzyl alcohol 589-18-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-03

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