ChemicalBook > CAS DataBase List > BUTTPARK 80\07-66

BUTTPARK 80\07-66

Product Name
BUTTPARK 80\07-66
CAS No.
50419-88-0
Chemical Name
BUTTPARK 80\07-66
Synonyms
BUTTPARK 80\07-66;4-Chloro-5-bromoanthranilic acid;2-AMINO-5-BROMO-4-CHLOROBENZOIC ACID;BENZOIC ACID, 2-AMINO-5-BROMO-4-CHLORO-;2-amino-5-bromo-4-chlorobenzene carboxylic acid
CBNumber
CB2712246
Molecular Formula
C7H5BrClNO2
Formula Weight
250.48
MOL File
50419-88-0.mol
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BUTTPARK 80\07-66 Property

Boiling point:
385.0±42.0 °C(Predicted)
Density 
1.892
storage temp. 
2-8°C, protect from light
pka
4.32±0.10(Predicted)
Appearance
Off-white to light brown Solid
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
A602063
Product name
2-Amino-5-bromo-4-chlorobenzoicAcid
Packaging
50mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB45152
Product name
5-Bromo-4-chloroanthranilic acid
Packaging
250mg
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB45152
Product name
5-Bromo-4-chloroanthranilic acid
Packaging
500mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB45152
Product name
5-Bromo-4-chloroanthranilic acid
Packaging
1g
Price
$120
Updated
2021/12/16
AK Scientific
Product number
V6257
Product name
2-Amino-5-bromo-4-chlorobenzoicacid
Packaging
1g
Price
$132
Updated
2021/12/16
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BUTTPARK 80\07-66 Chemical Properties,Usage,Production

Synthesis

89-77-0

50419-88-0

2-Amino-4-chlorobenzoic acid (I; 20.00 g, 116.6 mmol) and acetonitrile (300 mL) were added to a 500 mL single-necked round-bottomed flask with rapid stirring to form a beige-colored suspension. At room temperature, N-bromosuccinimide (NBS; 20.75 g, 116.6 mmol) was added slowly in batches. After addition, the reaction mixture was continued to be stirred for 1 hour. Subsequently, the reaction mixture was placed in a 45 °C water bath and the solvent was removed by rotary evaporation. Water was added to the residue, stirred and the filter cake was washed by filtration. Finally, the product was dried under vacuum at 60 °C to afford 2-amino-5-bromo-4-chlorobenzoic acid (II; 28.62 g, 98% yield).

References

[1] Patent: CN106986809, 2017, A. Location in patent: Paragraph 0024; 0025; 0026; 0027; 0028; 0029; 0030
[2] Patent: CN106966914, 2017, A. Location in patent: Paragraph 0019; 0020; 0028; 0029; 0036; 0037
[3] Patent: US2015/119405, 2015, A1. Location in patent: Paragraph 0407; 0408; 0409
[4] Patent: WO2005/54238, 2005, A1. Location in patent: Page/Page column 70
[5] Organic and Biomolecular Chemistry, 2014, vol. 12, # 27, p. 5031 - 5037

BUTTPARK 80\07-66 Preparation Products And Raw materials

Raw materials

Preparation Products

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50419-88-0, BUTTPARK 80\07-66Related Search:


  • BUTTPARK 80\07-66
  • 4-Chloro-5-bromoanthranilic acid
  • 2-amino-5-bromo-4-chlorobenzene carboxylic acid
  • BENZOIC ACID, 2-AMINO-5-BROMO-4-CHLORO-
  • 2-AMINO-5-BROMO-4-CHLOROBENZOIC ACID
  • 50419-88-0